{"id":1768,"date":"2018-01-10T13:58:43","date_gmt":"2018-01-10T10:58:43","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1768"},"modified":"2018-02-14T15:22:48","modified_gmt":"2018-02-14T12:22:48","slug":"2016-2-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2016-2-5\/","title":{"rendered":"2016 (2) 5"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.38.02.141\">https:\/\/doi.org\/10.15407\/polymerj.38.02.141<\/a><\/p>\n<p><strong>Influence of acyl radicals and their ratio in the structure of the device containing titanium on the properties of filled polypropylene<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>P.I. Bashtanyk<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, M.Ya. Kuzmenko<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, S.M. Kuzmenko<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, N.M. Laskovenko<\/em><\/strong><strong><em>2<\/em><\/strong><strong><em>, A.G. Golovan<\/em><\/strong><strong><em>1<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1State University of Chemical Technologyst<\/p>\n<p>7, Yu. Gagarin str., Dnipropetrovs\u2019k, 49005, Ukraine<\/p>\n<p>2Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2016, <strong>38<\/strong>, no. 2: 141-147.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The results of investigations of the properties of polypropylene thermoplastics filled hydroxide aluminum, pretreated products pereetyryfikatsiyi tetrabutoxytitanium mixture of acrylic acid and stearic acid in different molar ratio. This dressing has a number usable in the structure around titanium atom simultaneously reaction capable butoxygroup and akrylat- and stearatatsylni- radicals possible to obtain less combustible composite materials with increased magnitude of durability at expansion (to 50,0 MPa), with impact viscosity according to Sharpy (up to 60,2 KJ\/m<\/em><em>2<\/em><em>)<\/em><\/p>\n<p><em>Increasing strength characteristics of composite materials is caused both cemical interaction of acrylate acyloxy groups at appret titanium atom with radicals which appear in a polypropylene molecule and incrasid of the part of physical interactions between titanium(an appret) and electronegatsve oxyden the products of polypropylene destruction, a filler and an- bond of acrylacyloxyl radikals and a polarized bond (<\/em>\u00ba<em>TiO\u2013C\u2013) of neighbor appret molecules.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords:<\/strong> polypropylene, hydroxide aluminium, impregnation, properties, composite.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u041c\u0438\u043a\u0443\u043b\u0435\u043d\u043e\u043a \u0418.\u041e. \u041a\u043b\u0430\u0441\u0441\u0438\u0444\u0438\u043a\u0430\u0446\u0438\u044f \u0442\u0435\u0440\u043c\u043e\u043f\u043b\u0430\u0441\u0442\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u043e\u043d\u043d\u044b\u0445 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u043e\u0432 \u0438 \u0438\u0445 \u043d\u0430\u043f\u043e\u043b\u043d\u0438\u0442\u0435\u043b\u0435\u0439 \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b. \u2013 2012. &#8211; \u21169. \u2013 \u0421. 29-37.<br \/>\n2. \u0411\u0435\u0440\u043b\u0438\u043d, \u0410.\u0410., \u0412\u043e\u043b\u044c\u0444\u0441\u043e\u043d \u0421.\u0410., \u041e\u0448\u043c\u044f\u043d \u0412.\u0413. \u041f\u0440\u0438\u043d\u0446\u0438\u043f \u0441\u043e\u0437\u0434\u0430\u043d\u0438\u044f \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u043e\u043d\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u043e\u0432. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1990. \u2013 \u0421. 57-58.<br \/>\n3. \u0414\u0430\u043d\u0438\u043b\u0438\u043d\u0430 \u041b.\u0418., \u041c\u0438\u0448\u0438\u043d\u0430 \u0415.\u0418., \u0422\u0440\u043e\u0441\u0442\u044f\u043d\u0435\u0446\u043a\u0430\u044f \u0412.\u041b., \u0421\u043a\u0440\u0438\u043f\u043a\u043e \u041b.\u0410., \u041d\u043e\u0432\u0438\u043a\u043e\u0432 \u0421.\u0418. \u041f\u0440\u0438\u043c\u0435\u043d\u0435\u043d\u0438\u0435 \u0442\u0438\u0442\u0430\u043d\u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0441\u043e\u0435\u0434\u0435\u043d\u0435\u043d\u0438\u0439 \u0432 \u043a\u0430\u0447\u0435\u0441\u0442\u0432\u0435 \u0430\u043f\u043f\u0440\u0435\u0442\u043e\u0432 \u0434\u043b\u044f \u0442\u0440\u0438\u0433\u0438\u0434\u0440\u0430\u0442\u0430 \u043e\u043a\u0441\u0438\u0434\u0430 \u0430\u043b\u044e\u043c\u0438\u043d\u0438\u044f \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b. \u2013 1987. &#8211; \u211612. \u2013 \u0421. 39-40.<br \/>\n4. \u0411\u0430\u0448\u0442\u0430\u043d\u0438\u043a \u041f.\u0406., \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u041c.\u042f., \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u0421.\u041c., \u0413\u043e\u043b\u043e\u0432\u0430\u043d\u044c \u0410.\u0413. \u0414\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043d\u044f \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0435\u0439 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0439\u043d\u0438\u0445 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0456\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u043f\u043e\u043b\u0456\u043f\u0440\u043e\u043f\u0456\u043b\u0435\u043d\u0443, \u043d\u0430\u043f\u043e\u0432\u043d\u0435\u043d\u043e\u0433\u043e \u0433\u0456\u0434\u0440\u043e\u043a\u0441\u0438\u0434\u043e\u043c \u0430\u043b\u044e\u043c\u0456\u043d\u0456\u044e \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c.\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. \u2013 2015. &#8211; \u21166. \u2013 \u0421. ?<br \/>\n5. \u0411\u0430\u0448\u0442\u0430\u043d\u0438\u043a \u041f.\u0418., \u041e\u0432\u0447\u0430\u0440\u0435\u043d\u043a\u043e \u0412.\u0413. \u0411\u0430\u0437\u0430\u043b\u044c\u0442\u043e\u043f\u043b\u0430\u0441\u0442\u0438\u043a\u0438 \u0430\u043d\u0442\u0438\u0444\u0440\u0438\u043a\u0446\u0438\u043e\u043d\u043d\u043e\u0433\u043e \u043d\u0430\u0437\u043d\u0430\u0447\u0435\u043d\u0438\u044f \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u043f\u043e\u043b\u0438\u043f\u0440\u043e\u043f\u0438\u043b\u0435\u043d\u0430 \/\/ \u041c\u0435\u0445\u0430\u043d\u0438\u043a\u0430 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u043d\u044b\u0445 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u043e\u0432. \u2013 1997. \u2013 33, \u2116 3. \u2013 \u0421. 417-421.<br \/>\n6. \u0411\u0430\u0448\u0442\u0430\u043d\u0438\u043a \u041f.\u0406., \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u041c.\u042f., \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u0421.\u041c., \u0406\u0433\u043e\u043d\u0456\u043d\u0430 \u0413.\u041c., \u0404\u0432\u0442\u0443\u0448\u0435\u043d\u043a\u043e \u042f.\u0406., \u0428\u043f\u0430\u0442\u0430\u043a\u043e\u0432\u0430 \u0413.\u0412. \u041a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0439\u043d\u0456 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0438 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u043f\u043e\u043b\u0456\u043f\u0440\u043e\u043f\u0456\u043b\u0435\u043d\u0443, \u0430\u0440\u043c\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u0430\u043f\u0440\u0435\u0442\u043e\u0432\u0430\u043d\u0438\u043c \u0431\u0430\u0437\u0430\u043b\u044c\u0442\u043e\u0432\u0438\u043c \u0432\u043e\u043b\u043e\u043a\u043d\u043e\u043c \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c. \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. \u2013 2014. &#8211; \u21161. \u2013 \u0421. 57-61.<br \/>\n7. \u0413\u041e\u0421\u0422 28157-89. \u041c\u0435\u0442\u043e\u0434 \u043e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u0441\u0442\u043e\u0439\u043a\u043e\u0441\u0442\u0438 \u043a \u0433\u043e\u0440\u0435\u043d\u0438\u044e. &#8211; \u0412\u0432\u0435\u0434. 1990-01-07.- \u041c.: \u0413\u043e\u0441. \u043a\u043e\u043c\u0438\u0442\u0435\u0442 \u0421\u0421\u0421\u0420 \u043f\u043e \u0441\u0442\u0430\u043d\u0434\u0430\u0440\u0442\u0430\u043c, 1989.-10 \u0441.<br \/>\n8. \u0410\u043c\u0431\u0440\u043e\u0436 \u0418. \u041f\u043e\u043b\u0438\u043f\u0440\u043e\u043f\u043b\u0435\u043d: \u043f\u0435\u0440. \u0441\u043e \u0441\u043b\u043e\u0432\u0430\u0446\u043a\u043e\u0433\u043e \u0412.\u0410. \u0415\u0433\u043e\u0440\u043e\u0432\u0430. \/ \u041f\u043e\u0434 \u0440\u0435\u0434. \u041f\u0438\u043b\u0438\u043f\u043e\u0432\u0441\u043a\u043e\u0433\u043e \u0412.\u0418., \u042f\u0440\u0446\u0435\u0432\u0430 \u0418.\u041a. \u2013 \u041b.: \u0425\u0438\u043c\u0438\u044f, 1967. &#8211; 316 \u0441.<br \/>\n9. \u041b\u0438\u043f\u0430\u0442\u043e\u0432 \u042e.\u0421. \u0424\u0438\u0437\u0438\u043a\u043e-\u0445\u0438\u043c\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043e\u0441\u043d\u043e\u0432\u044b \u043d\u0430\u043f\u043e\u043b\u043d\u0435\u043d\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1991. \u2013 259 \u0441.<br \/>\n10. \u042d\u043d\u0446\u0438\u043a\u043b\u043e\u043f\u0435\u0434\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041c.: \u0421\u043e\u0432\u0440. \u042d\u043d\u0446\u0438\u043a\u043b\u043e\u043f\u0435\u0434\u0438\u044f, 1972. &#8211; \u21161.- 1224 \u0441.<br \/>\n11. \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u0421.\u041d, \u0411\u0443\u0440\u043c\u0438\u0441\u0442\u0440 \u041c.\u0412., \u041a\u0443\u0437\u044c\u043c\u0435\u043d\u043a\u043e \u041d.\u042f. \u0421\u0438\u043d\u0442\u0435\u0437 \u0438 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u043f\u0440\u043e\u0434\u0443\u043a\u0442\u043e\u0432 \u0433\u0438\u0434\u0440\u043e\u043b\u0438\u0442\u0438\u0447\u0435\u0441\u043a\u043e\u0439 \u043a\u043e\u043d\u0434\u0435\u043d\u0441\u0430\u0446\u0438\u0438 \u0442\u0435\u0442\u0440\u0430\u0431\u0443\u0442\u043e\u043a\u0441\u0438\u0442\u0438\u0442\u0430\u043d\u0430 \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c. \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. \u2013 2007. &#8211; \u21161. \u2013 \u0421. 67-70.<br \/>\n12. \u0410\u043d\u0434\u0440\u0438\u0430\u043d\u043e\u0432 \u041a.\u0410., \u0425\u0430\u043d\u0430\u043d\u0430\u0448\u0432\u0438\u043b\u0438 \u041b.\u041c. \u0422\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u044f \u044d\u043b\u0435\u043c\u0435\u043d\u0442\u043e\u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043c\u043e\u043d\u043e\u043c\u0435\u0440\u043e\u0432 \u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1973. &#8211; 400 \u0441.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.38.02.141 Influence of acyl radicals and their ratio in the structure of the device containing titanium on the properties of filled polypropylene \u00a0 P.I. Bashtanyk1, M.Ya. Kuzmenko1, S.M. Kuzmenko1, N.M. Laskovenko2, A.G. Golovan1 &nbsp; 1State University of Chemical Technologyst 7, Yu. Gagarin str., Dnipropetrovs\u2019k, 49005, Ukraine 2Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1768"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1768"}],"version-history":[{"count":3,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1768\/revisions"}],"predecessor-version":[{"id":2170,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1768\/revisions\/2170"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1768"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}