{"id":1777,"date":"2018-01-10T14:12:47","date_gmt":"2018-01-10T11:12:47","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1777"},"modified":"2018-02-14T15:27:41","modified_gmt":"2018-02-14T12:27:41","slug":"2016-2-8","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2016-2-8\/","title":{"rendered":"2016 (2) 8"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.38.02.158\">https:\/\/doi.org\/10.15407\/polymerj.38.02.158<\/a><\/p>\n<p><strong>The kinetics of the formation of organic-inorganic interpenetrating polymer networks in the presence of poly(titanium oxide) was obtained by sol-gel method<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>T.V. Tsebrienko, <\/em><\/strong><strong><em>\u0422<\/em><\/strong><strong><em>.<\/em><\/strong><strong><em>\u0422<\/em><\/strong><strong><em>. Alekseeva<\/em><\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2016, <strong>38<\/strong>, no. 2: 158-167.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Synthesis polymers.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Russian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The features of the kinetics of the formation of organic-inorganic interpenetrating polymer network (OI IPNs) based on crosslinked polyurethane (PU) and polyhydroxyethylmethacrylate (PHEMA) in the presence of poly(titanium oxide) (\u2013TiO<\/em><em>2<\/em><em>\u2013)<\/em><em>n<\/em><em>, was obtained by sol-gel method with variation content of (\u2013TiO<\/em><em>2<\/em><em>\u2013)<\/em><em>n<\/em><em>\u00a0and the molar ratio of titanium isopropoxide (Ti(OPr<\/em><em>i<\/em><em>)<\/em><em>4<\/em><em>) to the water was 1:2 have been studied by calorimetric method. Organic-inorganic interpenetrating polymer networks were obtained with a ratio PU\/PHEMA 30\/70 % wt. It was shown that the rate of the formation of PHEMA-component decrease when content of poly(titanium oxide) in OI IPNs increased. It is associated with appearance of the \u201ccell\u201d effect due to the grafting poly(titanium oxide) to hydroxyethylmethacrylate (HEMA). It was found that the rate of polymerization of HEMA in the presence of poly(titanium oxide) which was obtained in the medium of polypropylene glycol (POPG) significantly higher then the rate of the formation PHEMA when poly(titanium oxide) was obtained in HEMA. The rate of the formation of PHEMA depends on the features of incorporation (\u2013TiO<\/em><em>2<\/em><em>\u2013)<\/em><em>n<\/em><em>\u00a0in the organic matrix. <\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words: <\/strong>hybrid materials, kinetics, radical polymerization, \u201ccell\u201d effect, conversion degree.<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0438\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Yet J.-M., Weng C.-J., Huang K.-Y. Thermal and Optical Properties of PMMA\u2013Titania Hybrid Materials Prepared by Sol-Gel Approach with HEMA as Coupling Agent \/\/ J. Appl. Polym. Sci. \u2013 2004. &#8211; 94. \u2013P. 400\u2013405.<br \/>\n2. Nussbaumer R. J., Caseri W. R., Smith P. Polymer-TiO2 Nanocomposites: A Route Towards Visually Transparent Broadband UV Filters and High Refractive Index Materials \/\/ Macromol. Mater. Eng. \u2013 2003. \u2013 288. \u2013 P. 44-49.<br \/>\n3. Chiu W.-M., Yang C.-F., Chao Y.-H. Synthesis and Characterization of Titanium Dioxide Optical Film by Sol-Gel Process \/\/ J. Appl. Polym. Sci. \u2013 2007. \u2013 103. \u2013 P. 2271-2280.<br \/>\n4. Douce J., Boilot J.-P., Biteau J. Effect of filler size and surface condition of nano- sized silica particles in polysiloxane coatings \/\/ Thin Solid Films. \u2013 2004. \u2013 466. \u2013 P. 114-122.<br \/>\n5. Ke Z., Yongping B. Improve the gas barrier property of PET film with montmorillonite by in situ interlayer polymerization \/\/ Materials Letters. \u2013 2005. \u2013 59. \u2013 P. 3348\u20133351.<br \/>\n6. Wang Z.F., Wang B., Qi N., Zhang H.F. Influence of fillers on free volume and gas barrier properties in styrene-butadiene rubber studied by positrons \/\/ Polymer. &#8211; 2005. \u2013 46. \u2013 P. 719\u2013724.<br \/>\n7. Deng J., Ding X., Zhang W., Peng Y. Carbon nanotube\u2013polyaniline hybrid materials \/\/ Europ. Polymer J. \u2013 2002. \u2013 38. \u2013 P. 2497\u20132501.<br \/>\n8. \u041f\u043e\u043c\u043e\u0433\u0430\u0439\u043b\u043e \u0410.\u0414. \u0413\u0438\u0431\u0440\u0438\u0434\u043d\u044b\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440-\u043d\u0435\u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u044b \/\/ \u0423\u0441\u043f\u0435\u0445\u0438 \u0445\u0438\u043c\u0438\u0438. \u2013 2000. \u2013 69. \u2013 \u0420. 60 \u2013 89.<br \/>\n9. Wang J., Ni X. Interfacial Structure of Poly(methyl methacrylate)\/TiO2 Nanocomposites Prepared Through Photocatalytic Polymerization \/\/ J. Appl. Polym. Sci. \u2013 2007. \u2013 108. \u2013 P. 3552\u20133558.<br \/>\n10. Bach L.G., Islam Md. R., Seo S.Y., Lim K.T. A Novel Route for the Synthesis of Poly(2-hydroxyethyl methacrylate) Grafted TiO2 Nanoparticles via Surface Thiol-Lactam Initiated Radical Polymerization \/\/ J. Appl. Polym. Sci. \u2013 2012. \u2013P. 1 \u2013 9.<br \/>\n11. Kuznetsova A. I., Kameneva O., Rozes L., Sanchez C., Bityurin N. Extinction of photo-induced Ti3+ centres in titanium oxide gels and gel-based oxo-PHEMA hybrids \/\/ Chemical Physics Letters. \u2013 2006. \u2013 429. \u2013 P. 523 \u2013 527.<br \/>\n12. \u041a\u0430\u043c\u0435\u043d\u0435\u0432\u0430 \u041e.\u0412., \u041a\u0443\u0437\u043d\u0435\u0446\u043e\u0432 \u0410. \u0418., \u0421\u043c\u0438\u0440\u043d\u043e\u0432\u0430 \u041b. \u0410., \u0420\u043e\u0437\u0435\u0441 \u041b. \u041d\u043e\u0432\u044b\u0435 \u0433\u0438\u0431\u0440\u0438\u0434\u043d\u044b\u0435 \u043e\u0440\u0433\u0430\u043d\u043e-\u043d\u0435\u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u043f\u043e\u043b\u0438\u0442\u0438\u0442\u0430\u043d\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0433\u043e \u0433\u0435\u043b\u044f \u0441 \u044d\u0444\u0444\u0435\u043a\u0442\u0438\u0432\u043d\u044b\u043c \u0423\u0424-\u0438\u043d\u0434\u0443\u0446\u0438\u0440\u043e\u0432\u0430\u043d\u043d\u044b\u043c \u0440\u0430\u0437\u0434\u0435\u043b\u0435\u043d\u0438\u0435\u043c \u0437\u0430\u0440\u044f\u0434\u0430 \/\/ \u0414\u041e\u041a\u041b. \u0410\u041d \u0420\u0424. \u2013 2006. \u2013 407. \u2013 \u0421. 29-31.<br \/>\n13. Su H.-W., Chen W.-C. High refractive index polyimide-nanocrystalline-titania hybrid optical materials \/\/ J. Mater. Chem. C. \u2013 2008. &#8211; 18. &#8211; P. 1139\u20131145.<br \/>\n14. Ravirajan P., Bradley D.D.C., Nelson J., Haque S.A., Durrant J.R. Efficient charge collection in hybrid polymer\/TiO2 solar cells using poly(ethylenedioxythiophene)\/polystyrene sulphonate as hole collector \/\/ Appl. Phys. Lett. &#8211; 2005. \u2013 86. \u2013 P. 1-3.<br \/>\n15. Gaya U.I., Abdullah A.H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems \/\/ J. Photochem. Photobiol. C. \u2013 2008. \u2013 9. \u2013 P. 1 -12.<br \/>\n16. Moradi S. Azar P.A., Farshid S.R., Khorrami S.A. Effect of Additives on Characterization and Photocatalic Activity of TiO2\/ZnO Nanocomposite Prepared via Sol-Gel Process \/\/ Intern. J. Chem. Eng. \u2013 2012. \u2013 2012. \u2013 P. 1 \u2013 5.<br \/>\n17. Bityurin N., Znaidi L., Kanaev A. Laser-induced absorption in titanium oxide based gels \/\/ Chem. Physics Letters. \u2013 2003. \u2013 374.- P. 95 -99.<br \/>\n18. Kameneva O., Kuznestov A. I., Smirnova L. A., Ro- zes L., Sanchez C. New photoactive hybrid organic\u2013inorganic materials based on titanium-oxo-PHEMA nanocomposites exhibiting mixed valence properties \/\/ J. Mater. Chem. C. \u2013 2005. &#8211; 15. &#8211; P. 3380 \u20133383.<br \/>\n19. Salomatina E.V., Biturin N.M., Gulenova M.V., Gracheva T.A. Synthesis, structure, and properties of organic-inorganic nanocomposites containing poly(titanium oxide) \/\/ J. Mater. Chem. C. \u2013 2013. &#8211; 1, \u2116 39. &#8211; P. 6375-6385.<br \/>\n20. \u0426\u0435\u0431\u0440\u0438\u0435\u043d\u043a\u043e \u0422.\u0412., \u0410\u043b\u0435\u043a\u0441\u0435\u0435\u0432\u0430 \u0422.\u0422. \u041e\u0441\u043e\u0431\u0435\u043d\u043d\u043e\u0441\u0442\u0438 \u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0438 \u0444\u043e\u0440\u043c\u0438\u0440\u043e\u0432\u0430\u043d\u0438\u044f \u0432\u0437\u0430\u0438\u043c\u043e\u043f\u0440\u043e\u043d\u0438\u043a\u0430\u044e\u0449\u0438\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u0441\u0435\u0442\u043e\u043a \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u0430, \u043f\u043e\u043b\u0438\u0433\u0438\u0434\u0440\u043e\u043a\u0441\u0438\u044d\u0442\u0438\u043b\u043c\u0435\u0442\u0430\u043a\u0440\u0438\u043b\u0430\u0442\u0430 \u0438 \u043f\u043e\u043b\u0438\u0442\u0438\u0442\u0430\u043d\u043e\u043a\u0441\u0438\u0434\u0430, \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u043d\u043e\u0433\u043e \u0437\u043e\u043b\u044c-\u0433\u0435\u043b\u044c \u043c\u0435\u0442\u043e\u0434\u043e\u043c \/\/ \u041f\u043e\u043b\u0438\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2016. \u201338, \u2116 1. \u2013 \u0421. 47-55.<br \/>\n21. Brinker C.J., Scherer G.W. Sol-Gel Science. \u2013 New York: Academic Press, 1990. &#8211; P. 908.<br \/>\n22. \u041c\u0430\u0440\u0442\u044b\u043d\u044e\u043a \u0418.\u0421., \u0410\u043b\u0435\u043a\u0441\u0435\u0435\u0432\u0430 \u0422.\u0422. \u041a\u0438\u043d\u0435\u0442\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0437\u0430\u043a\u043e\u043d\u043e\u043c\u0435\u0440\u043d\u043e\u0441\u0442\u0438 \u043e\u0431\u0440\u0430\u0437\u043e\u0432\u0430\u043d\u0438\u044f \u043e\u0440\u0433\u0430\u043d\u043e-\u043d\u0435\u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0412\u041f\u0421 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u0441\u0435\u0442\u0447\u0430\u0442\u043e\u0433\u043e \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u0430 \u0438 Ti-\u0441\u043e\u0434\u0435\u0440\u0436\u0430\u0449\u0435\u0433\u043e \u0441\u043e\u043f\u043e\u043b\u0438\u043c\u0435\u0440\u0430 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2013. \u2013 35, \u2116 2 \u2013 \u0421. 171-178.<br \/>\n23. \u0420\u043e\u0437\u0435\u043d\u0431\u0435\u0440\u0433 \u0411.\u0410., \u0411\u043e\u0439\u043a\u043e \u0413.\u041d., \u0411\u043e\u0433\u0434\u0430\u043d\u043e\u0432\u0430 \u041b.\u041c. \u0420\u0435\u0430\u043a\u0446\u0438\u0438 \u043c\u0435\u0436\u0446\u0435\u043f\u043d\u043e\u0433\u043e \u043e\u0431\u043c\u0435\u043d\u0430 \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0410. \u2013 2003. \u2013 45. \u2013 \u0421. 1454-1461.<br \/>\n24. 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Fourier transform infrared study of poly (2-hydroxyethyl methacrylate) PHEMA \/\/ Colloid &amp; Polymer Sci. \u2013 1997. \u2013 275. \u2013 P. 323-332.<br \/>\n25. \u0410\u043b\u0435\u043a\u0441\u0454\u0454\u0432\u0430 \u0422.\u0422., \u041c\u0435\u043d\u0436\u0435\u0440\u0435\u0441 \u0413.\u042f., \u041c\u0430\u0440\u0442\u0438\u043d\u044e\u043a \u0406.\u0421. \u0421\u043f\u0435\u043a\u0442\u0440\u0430\u043b\u044c\u043d\u0456 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043d\u044f \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u0432\u0437\u0430\u0454\u043c\u043e\u043f\u0440\u043e\u043d\u0438\u043a\u043d\u0438\u0445 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u0441\u0456\u0442\u043e\u043a \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u0441\u0456\u0442\u0447\u0430\u0441\u0442\u043e\u0433\u043e \u043f\u043e\u043b\u0456\u0443\u0440\u0435\u0442\u0430\u043d\u0443 \u0442\u0430 \u043e\u0440\u0433\u0430\u043d\u043e-\u043d\u0435\u043e\u0440\u0433\u0430\u043d\u0456\u0447\u043d\u043e\u0433\u043e \u043a\u043e\u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0443 \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c. \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. \u2013 2012. \u2013 3. \u2013 \u0421. 54-55.<br \/>\n26. Chatterjee A. Properties Improvement of PMMA Using Nano TiO2 \/\/ J. Appl. Polym. Sci. \u2013 2010. \u2013 118.\u2013 P. 2890-2897.<br \/>\n27. Zhon H., Chen Y. Fan H. Water vapor permeability of the polyurethane\/TiO2 nanohybrid membrane with temperature sensitivity \/\/ J. Appl. Polym. Sci. \u2013 2008. &#8211; 109. \u2013 P. 3002-3007.<br \/>\n28. Kaddami H., Gerard J.F., Hajjl P. Silica-filled poly(HEMA) from HEMA\/grafted SiO2 nanoparticles: polymerization kinetics and rheological changes \/\/ J. Appl. Polym. Sci. \u2013 1999. \u2013 73. \u2013 P. 2701-2713.<br \/>\n29. Kaddami H., Pascault J.P., Gerard J.F. Influence of the initiation rate on the polymerization kinetics of hydroxyl ethyl methacrylate (HEMA) filled with HEMA-grafted silica preformed nanoparticles \/\/ Polym. Eng. Sci. \u2013 2004. \u2013 44<br \/>\n30. \u0413\u043b\u0430\u0434\u044b\u0448\u0435\u0432 \u0413.\u041f., \u041f\u043e\u043f\u043e\u0432 \u0412.\u0410. \u0420\u0430\u0434\u0438\u043a\u0430\u043b\u044c\u043d\u0430\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u0438\u0437\u0430\u0446\u0438\u044f \u043f\u0440\u0438 \u0433\u043b\u0443\u0431\u043e\u043a\u0438\u0445 \u0441\u0442\u0435\u043f\u0435\u043d\u044f\u0445 \u043f\u0440\u0435\u0432\u0440\u0430\u0449\u0435\u043d\u0438\u044f. \u2013 \u041c.: \u041d\u0430\u0443\u043a\u0430, 1974. \u2013 242 \u0441.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.38.02.158 The kinetics of the formation of organic-inorganic interpenetrating polymer networks in the presence of poly(titanium oxide) was obtained by sol-gel method \u00a0 T.V. Tsebrienko, \u0422.\u0422. Alekseeva \u00a0 Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2016, 38, no. 2: 158-167. &nbsp; Section: Synthesis polymers. &nbsp; Language: [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1777"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1777"}],"version-history":[{"count":3,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1777\/revisions"}],"predecessor-version":[{"id":2173,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1777\/revisions\/2173"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1777"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}