{"id":1781,"date":"2018-01-10T14:25:15","date_gmt":"2018-01-10T11:25:15","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1781"},"modified":"2018-02-14T15:40:19","modified_gmt":"2018-02-14T12:40:19","slug":"2016-1-1","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2016-1-1\/","title":{"rendered":"2016 (1) 1"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.38.01.003<\/a><\/p>\n

Thermal and electrical conductivity of the polymer-metal composites with 1D structure of filler formed in a magnetic field<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

Ye.P Mamunya V.V. Levchenko, I.M. Parashchenko, E.V. Lebedev<\/em><\/strong><\/p>\n

 <\/p>\n

Institute of Macromolecular Chemistry of NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

 <\/p>\n

Polym. J., 2016, 38<\/strong>, no. 1: 3-17.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

The electrical and thermal properties of the metal-filled composites with a statistical three-dimensional 3D and an oriented one-dimensional 1D structure of the filler, which is formed in a magnetic field, have been studied. Composites based on thermosetting resin (silicone) and the thermoplastic polymer LDPE comprising metal fillers Fe and Ni with a particle size of 3 and 10 microns, respectively, were prepared. A significant increase in electrical conductivity and reduced percolation threshold from 25 to 4 % vol., as well as 1.5 times increase in thermal conductivity in the composites silicone-Fe and LDPE-Ni with 1D structure of the filler were revealed. Also, there were analyzed in details and quantitatively estimated the factors which restrict the achievement of ultrahigh (approaching the characteristics of metal) thermal and electrical conductivity values in the case of forming a conductive 1D structure. High thermal resistance at the interface between the metal particle\u2013polymer matrix and particle\u2013particle limits the thermal transport along the percolation cluster of the metal filler. The calculations of the interfacial thermal contact resistance were fulfilled. Analysis of the mechanism of heat transfer or flow of electric current through the direct contacts particle\u2013particle and the corresponding calculations show that the contact spot does not make a significant contribution to heat transfer, resulting in the formation of a cluster of conductive filler particles and does not affect the thermal conductivity. In the case of electrical conductivity the contact spots play a crucial role in formation of the conductive cluster and an electric current flow through the metal filler.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Key words<\/strong>: polymer composite, one-dimensional structure, magnetic field, thermal conductivity, electrical conductivity, percolation threshold, contact thermal resistance.<\/p>\n

 <\/p>\n

\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

1. Metal, ceramic and polymeric composites for various uses. Ed.: J. Cuppoletti. \u2013 Rijeka, Croatia: InTech, 2011. \u2013 ISBN 978-953-307-353-8.
\n2. Advances in nanocomposites \u2013 synthesis, characterization and industrial applications. Ed.: B.S.R. Reddy. \u2013 Rijeka, Croatia: InTech, 2011. \u2013 ISBN 978-953-307-165-7.
\n3. Leblanc J.L. Filled polymers. Science and industrial applications. \u2013 Boca Raton, New York: CRC Press \u2013 Taylor & Francis Group., 2010. \u2013 ISBN 978-1-4398-0042-3.
\n4. Conductive polymers and plastics in industrial applications. Ed.: L. Rupprecht. \u2013 New York: Plastics Design Library, 1999. \u2013 ISBN l-884207-77-4.
\n5. Particulate-filled polymer composites. Ed.: R.N. Rothon. \u2013 Shawbury, UK: Rapra Technology, 2003. \u2013 ISBN 1-85957-382-7.
\n6. Functional fillers for plastics. Ed.: M. Xanthos. \u2013 Weinheim: WILEY-VCH Verlag GmbH, 2005. \u2013 ISBN 978-3-527-31054-8.
\n7. Metal-filled polymers. Properties and applications. Ed.: S.K. Bhattachrya. \u2013 New York: Marcel Dekker Inc., 1986. \u2013 ISBN 0-8247-7555-4.
\n8. Mamunya Ye.P., Davydenko V.V., Pissis P., Lebedev E.V. Electrical and thermal conductivity of polymers filled with metal powders \/\/ Europ. Polym. J.- 2002.- 38.- P. 1887-1897.
\n9. Mamunya Ye.P., Muzychenko Yu.V., Pissis P., Lebe- dev E.V., Shut M.I. Percolation phenomena in polymers containing dispersed iron \/\/ Polym. Eng. Sci.- 2002.- 42, No 1.- P. 90-100.
\n10. Xue Q. The influence of particle shape and size on electric conductivity of metal-polymer composites \/\/ Europ. Polym J. \u2013 2004.- 40.- P. 323-327.
\n11. Boudenne A., Ibos L., Fois M., Gehin E., Majeste J-C. Thermophysical properties of PP\/aluminum composites \/\/ J. Polym. Sci. \u2013 Polym. Phys.- 2004.- 42, No 4.- P.722-732.
\n12. Weidenfeller B., Hofer M., Schilling F.R. Thermal conductivity, thermal diffusivity, and specific heat capacity of particle filled polypropylene \/\/ Composites. Part A. – 2004, 35.- P. 423-429.
\n13. Boudenne A., Ibos L., Fois M., Majeste J-C., Gehin E. Electrical and thermal behavior of polypropylene filled with copper particles \/\/ Composites. Part A. \u2013 2005.- 36.- P. 1545-1554.
\n14. Krupa I., Cecen V., Boudenne A., Proke\u0459 J., Novak I. The mechanical and adhesive properties of electrically and thermally conductive polymeric composites based on high density polyethylene filled with nickel powder \/\/ Materials and Design. \u2013 2013.- 51.- P. 620\u2013628.
\n15. \u041c\u0430\u043c\u0443\u043d\u044f \u0404.\u041f., \u042e\u0440\u0436\u0435\u043d\u043a\u043e \u041c.\u0412., \u041b\u0435\u0431\u0435\u0434\u0454\u0432 \u0404.\u0412., \u041b\u0435\u0432\u0447\u0435\u043d\u043a\u043e \u0412.\u0412., \u0427\u0435\u0440\u0432\u0430\u043a\u043e\u0432 \u041e.\u0412., \u041c\u0430\u0442\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u041e.\u041a., \u0421\u0432\u0435\u0440\u0434\u043b\u0456\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u041e.\u0421. \u0415\u043b\u0435\u043a\u0442\u0440\u043e\u0430\u043a\u0442\u0438\u0432\u043d\u0456 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0456 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0438. \u2013 \u041a\u0438\u0457\u0432: \u0410\u043b\u044c\u0444\u0430-\u0440\u0435\u043a\u043b\u0430\u043c\u0430, 2013, 402 \u0441. \u2013 ISBN 978-966-2477-94-8.
\n16. Roussel F., King R.C.Y., Kuriakose M., Depriester M., Hadj-Sahraoui A., Gors C., Addad A., Brun J-F. Electrical and thermal transport properties of polyaniline\/silver composites and their use as thermoelectric materials \/\/ Synthetic Metals. \u2013 2015. – 199.- P. 196-204.
\n17. Jouni M., Boudenne A., Boiteux G., Massardier V., Garnie B., Serghei A. Electrical and thermal properties of polyethylene\/silver nanoparticle composites \/\/ Polym. Compos.- 2013.- 34.- P. 778\u2013786.
\n18. Goh P.S., Ismail A.F., Ng B.C. Directional alignment of carbon nanotubes in polymer matrix: contemporary approaches and future advances \/\/ Composites (JCOMA). Part A. \u2013 2014.- 56. \u2013 P. 103-126.
\n19. Filipcsei G., Csetneki I., Szilagyi A., Zrinyi M. Magnetic field-responsive smart polymer composites \/\/ Adv. Polym. Sci. – 2007. – 206. \u2013 P. 137\u2013189.
\n20. Camponeschi E., Vance R., Al-Haik M., Garmestani H., Tannenbaum R. Properties of carbon nanotube\u2013polymer composites aligned in a magnetic field \/\/ Carbon. – 2007.- 45.- P. 2037\u20132046.
\n21. Kaleta J., Lewandowski D., Mech R., Zaja P. Smart magnetic composites.- Chapter 24. \/\/ In book: Metal, ceramic and polymeric composites for various uses. Ed.: J. Cuppoletti.- Rijeka, Croatia: InTech, 2011. \u2013 ISBN 978-953-307-353-8.
\n22. Varga Z., Filipcsei G., Zrinyi M. Magnetic field sensitive functional elastomers with tuneable elastic modulus \/\/ Polymer. \u2013 2006.- 47.- P. 227\u2013233.
\n23. Fischer J.E., Zhou W., Vavro J., Llaguno M.C., Guthy C., Haggenmueller R. Magnetically aligned single wall carbon nanotube films: preferred orientation and anisotropic transport properties \/\/ J. Appl. Phys.- 2003.- 93, No 4.- P. 2157-2163.
\n24. Leng J.S., Huang W.M., Lan X., Liu Y.J., Du S.Y. Significantly reducing electrical resistivity by forming conductive Ni chains in a polyurethane shape-memory polymer\/carbon-black composite \/\/ Appl. Phys. Lett.- 2008.- 92.- P. 204101-3.
\n25. Han B., Ma F., Feng T., Jiang H., Wang Y. Effect of magnetis field treatment on properties of thermosetting polymers and their composites \/\/ Proceed. 9th Int. Conf. on Properties and applications of dielectric materials – 2009, Harbin, China.
\n26. Kim I.T., Tannenbaum A., Tannenbaum R. Anisotropic conductivity of magnetic carbon nanotubes embedded in epoxy matrices \/\/ Carbon. \u2013 2011.- 49.- P. 54\u201361.
\n27. Boudenne A., Mamunya Ye., Levchenko V., Garnier B., Lebedev E. Improvement of thermal and electrical properties of silicone-Ni composites using magnetic field \/\/ Europ. Polym. J.- 2015.- 63.- P. 11\u201319.
\n28. Abdalla M., Dean D., Theodore M., Fielding J., Nyairo E., Price G. Magnetically processed carbon nanotube\/epoxy nanocomposites: Morphology, thermal, and mechanical properties \/\/ Polymer. \u2013 2010.- 51.- P. 1614\u20131620.
\n29. Hu T., Xie H., Chen L., Zhong G., Zhang H. Preparation and orientation behavior of multi-walled carbon nanotubes grafted with a side-chain azobenzene liquid crystalline polymer \/\/ Polym. Int.- 2011.- 60.- P. 93\u2013101.
\n30. Ma C., Zhang W., Zhu Y., Ji L., Zhang R., Koratkar N., Liang J. Alignment and dispersion of functionalized carbon nanotubes in polymer composites induced by an electric field \/\/ Carbon. – 2008.- 46.- P. 706-720.
\n31. Schwarz M-K., Bauhofer W., Schulte K. Alternating electric field induced agglomeration of carbon black filled resins \/\/ Polymer. \u2013 2002.- 43, No 10.- P. 3079\u20133082.
\n32. Park C., Wilkinson J., Banda S., Ounaies Z., Wise K.E., Sauti G., Lillehei P.T., Harrison J.S. Aligned singlewall carbon nanotube polymer composites using an electric field \/\/ J. Polym. Sci. Part B. – 2006.- 44, No 12.- P. 1751\u20131762.
\n33. Kai Yu., Zhang Z., Liu Y., Leng J. Carbon nanotube chains in a shape memory polymer\/carbon black composite: to significantly reduce the electrical resistivity \/\/ Appl. Phys. Lett.- 2011.- 98.- P. 074102(1-3).
\n34. Chen Y.M., Ting J.M. Ultra high thermal conductivity polymer composites \/\/ Carbon. \u2013 2002.- 40, No 3.- P. 359\u2013362.
\n35. Stauffer D., Aharony A. Introduction to percolation theory. \u2013 London: Taylor&Francis Ltd., 1992.
\n36. Grimaldi C., Balberg I. Tunneling and nonuniversality in continuum percolation systems \/\/ Phys. Rev. Lett.- 2006.- 96, No 6.- P. 066602(1-4).
\n37. Thomsen C. Critical exponents and percolation thresholds in two-dimensional systems with a finite interplane coupling \/\/ Phys. Rev.- 2002.- 65.- P. 065104(1-4).
\n38. Mamunya Ye.P., Zois H., Apekis L., Lebedev E.V. Influence of pressure on the electrical conductivity of metal powders used as fillers in polymer composites \/\/ Powder Technology. \u2013 2004.- 140.- P. 49-55.
\n39. Diaz-Bleis D., Vales-Pinz\u0443n C., Freile-Pelegr\u043dn Y., Alvarado-Gil J.J. Thermal characterization of magnetically aligned carbonyl iron\/agar composites \/\/ Carbohydr. Polym.- 2014.- 99.- P. 84- 90.
\n40. Huang H., Liu C., Wu Y., Fan S. Aligned carbon nanotube composite films for thermal management \/\/ Advanced Materials. \u2013 2005.- 17.- P. 1652-1656.
\n41. Datsyuk V., Trotsenko S., Reich S. Carbon-nanotube\u2013polymer nanofibers with high thermal conductivity \/\/ Carbon. \u2013 2013.- 52.- P. 605\u2013608.
\n42. Carson J.K., LovattS.J., Tanner D.J., Cleland A.C. Predicting the effective thermal conductivity of unfrozen, porous foods \/\/ J. Food Eng.- 2006.- 75.- P. 297\u2013307.
\n43. Pal R. On the Lewis-Nielsen model for thermal\/electrical conductivity of composites \/\/ Composites: Part A: Appl. Sci. & Manufact.- 2008.- 39.- P. 718-726.
\n44. Chikhi M., Agoudjil B., Haddadi M., Boudenne A. Numerical modelling of the effective thermal conductivity of heterogeneous materials \/\/ J. Thermopl. Comp. Mater.- 2013.- 26, No 3.- P. 336-345.
\n45. Progelhof R.C., Throne J.L., Ruetsch R.R. Methods for predicting the thermal conductivity of composite systems: a review \/\/ Polym. Eng. Sci.- 1976.- 16, No 9.- P. 615\u2013625.
\n46. Han Z., Fina A. Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review \/\/ Progress in Polym. Sci. \u2013 2010.- 36, No 7.- P. 914-944.
\n47. Sebastian M.T., Jantunen H. Polymer\u2013ceramic composites of 0\u20133 connectivity for circuits in electronics: a review \/\/ Int. J. Appl. Ceram. Technol.- 2010.- 7, No 4.- P. 415\u2013434.
\n48. Nejad S.J. A review on modeling of the thermal conductivity of polymeric nanocomposites \/\/ e-Polymers. \u2013 2012. \u2013 No. 025. \u2013 P. ???
\n49. Duong H.M., Yamamoto N., Papavassiliou D.V., Maruyama S., Wardle B.L. Inter-carbon nanotube contact in thermal transport of controlled-morphology polymer nanocomposites \/\/ Nanotechnology. \u2013 2009.- 20, No 15.- P. 5702.
\n50. Huxtable S.T., Cahill D.G., Shenogin S., Xue L., Ozisik R., Barone P., Usrey M., Strano M.S., Siddons G., Shim M., Keblinski P. Interfacial heat flow in carbon nanotube suspensions \/\/ Nature Materials. \u2013 2003.- 2, No 11.- P. 731-734.
\n51. Hida S., Hori T., Shiga T., Elliott J. Shiomi J. Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene \/\/ Int. J. Heat & Mass Transfer. \u2013 2013.- 67.- P. 1024\u20131029.
\n52. Garnier B., Dupuis T., Gilles J., Bardon J.P., Danes F. Thermal contact resistance between matrix and particle in composite materials measured by a thermal microscopic method using a semi-intrinsic thermocouple \/\/ Proc. 12 th Int. Heat Transfer Conf.- Grenoble, France, 2002.- P. 9-14, Paris: Elsevier, 2002.
\n53. Nan C-W., Liu G., Lin Y., Li M. Interface effect on thermal conductivity of carbon nanotube composites \/\/ Appl. Phys. Lett.- 2004.- 85, No 16.- P. 3549-3551.
\n54. Droval G., Feller J.-F., Salagnac P., Glouannec P. Thermal conductivity enhancement of electrically insulating syndiotactic poly(styrene) matrix for diphasic conductive polymer composites \/\/ Polym. Adv. Technol.- 2006.- 17.- P. 732\u2013745.
\n55. Shenogina N., Shenogin S., Xue L., Keblinski P. On the lack of thermal percolation in carbon nanotube composites \/\/ Appl. Phys. Lett.- 2005.- 87.- P. 133106.
\n56. Cheng Z., Liu L., Lu M., Wang X. Temperature dependence of electrical and thermal conduction in single silver nanowire \/\/ Scientific Reports. \u2013 2015.- 5.- P. 10718, DOI: 10.1038\/srep10718.
\n57. Wu H., Drzal L.T. High thermally conductive graphite nanoplatelet\/polyetherimide composite by precoating: effect of percolation and particle size \/\/ Polym. Compos.- 2013.- 34.- P. 2148-2153.
\n58. Ahn K., Kim K., Kim J. Fabrication of surface-treated BN\/ETDS composites for enhanced thermal and mechanical properties \/\/ Ceramics International. \u2013 2015.- 41, No 8.- P. 9488\u20139495.
\n59. Mamunya E.P. Electrical and thermal conductivity of metal-filled composites \/\/ Functional Materials. \u2013 1998. – 5, No 3.- P. 410-412.
\n60. \u0425\u043e\u043b\u044c\u043c \u0420. \u042d\u043b\u0435\u043a\u0442\u0440\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043a\u043e\u043d\u0442\u0430\u043a\u0442\u044b. \u2013 \u041c: \u0418\u0437\u0434-\u0432\u043e \u0438\u043d\u043e\u0441\u0442\u0440. \u043b-\u0440\u044b, 1961. \u2013 464 \u0441.
\n61. \u0413\u0443\u043b\u044c \u0412.\u0415., \u0428\u0435\u043d\u0444\u0438\u043b\u044c \u041b.\u0417. \u042d\u043b\u0435\u043a\u0442\u0440\u043e\u043f\u0440\u043e\u0432\u043e\u0434\u044f\u0449\u0438\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0435 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u0438. \u2013 \u041c: \u0425\u0438\u043c\u0438\u044f, 1984. \u2013 240 \u0441.
\n62. Strumpler R., Glatz-Reichenbach J. Conducting polymer composites \/\/ J. Electroceramics. – 1999. – 3, No 4. – P. 329-346.
\n63. Nicolics J., M\u044cndlein M. Electrically conductive adhesives \/\/ In book: Eds.: Suhir E., Lee Y.C., Wong C.P. Micro- and Opto- Electronic Materials and Structures: Physics, Mechanics, Design, Reliability, Packaging.- Berlin: Springer, 2007. \u2013 v.2., Chapter 21. \u2013 P. 571-610. \u2013 ISBN 978-0-387-27974-9.
\n64. Pezzotti G., Kamada I., Miki S. Thermal conductivity of AlN\/polystyrene interpenetrating networks \/\/ J. Europ. Ceram. Soc.- 2000.- 20.- P. 1197-1203.<\/p>\n

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https:\/\/doi.org\/10.15407\/polymerj.38.01.003 Thermal and electrical conductivity of the polymer-metal composites with 1D structure of filler formed in a magnetic field \u00a0 Ye.P Mamunya V.V. Levchenko, I.M. Parashchenko, E.V. Lebedev   Institute of Macromolecular Chemistry of NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine   Polym. J., 2016, 38, no. 1: 3-17.   Section: Structure and […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1781"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1781"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1781\/revisions"}],"predecessor-version":[{"id":2174,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1781\/revisions\/2174"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1781"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}