{"id":1787,"date":"2018-01-10T14:31:10","date_gmt":"2018-01-10T11:31:10","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1787"},"modified":"2018-02-14T15:42:51","modified_gmt":"2018-02-14T12:42:51","slug":"2016-1-3","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2016-1-3\/","title":{"rendered":"2016 (1) 3"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.38.01.024\">https:\/\/doi.org\/10.15407\/polymerj.38.01.024<\/a><\/p>\n<p><strong>Features of the formation, the phase structure, viscoelastic and mechanical properties of the binary polymer matrice based on polymethylmethacrylate, modified by crosslinked polyurethane<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong><em>N.V. Babkina, T.D. Ignatova, L.F. Kosyanchuk,\u00a0 O.I. Antonenko, L.A. Vorontsova, O.V. Babich <\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske sh\u043ese, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2016, <strong>38<\/strong>, no. 1: 24-33.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The kinetic regularities of formation, feature of the phase morphology, viscoelastic and mechanical properties of binary polymer matrice based on polymethylmethacrylate modified with 10, 20 and 30 % wt. of crosslinked polyurethane have been studied. It has been shown that the formation of polymethylmethacrylate-polyurethane semi-IPNs accompanied by phase separation that occurs in two stages: on the first stage the mechanism of nucleation and growth takes place, and the second stage is superposition of mechanisms of nucleation and spinodal decomposition. As a result the polymer system with two phases and quasicompatible interfacial region is formed. The increase of polyurethane content leads to acceleration of the phase separation process in the system. At that the domains with larger size are formed and the fraction of the interfacial region depending on the content of polyurethane is growing. An increase of the fraction of interfacial region in polymethylmethacrylate modified by crosslinked polyurethane is accompanied by increasing of elongation and can enhance its impact resistance.<\/em><\/p>\n<p>&nbsp;<\/p>\n<p><strong>Keywords:<\/strong> impact-resistant polymethylmethacrylate, kinetics, phase morphology, interfacial region, viscoelastic properties.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u041d\u0438\u043b\u044c\u0441\u0435\u043d \u041b. \u041c\u0435\u0445\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u0438 \u0438\u0445 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u0439. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1978. \u2013 312 \u0441.<br \/>\n2. Michler G.H. High-impact rubber-modified polymers. In: Electron microscopy of polymers. \u2013 Berlin: Springer, 2008. \u2013 P. 351\u2013371.<br \/>\n3. Hur T., Manson J.A., Hertzberg R.W., Sperling L.H. Fatigue behavior of acrylic interpenetrating polymer networks. II \/\/ J. Appl. Polym. Sci. \u2013 1990. \u2013 39, \u2116 9. \u2013 P. 1933\u20131947.<br \/>\n4. Heim Ph., Wrotecki C., Avenel M., Gaillard P. High impact cast sheets of poly(methyl methacrylate) with low levels of polyurethane \/\/ Polymer. \u2013 1993. \u2013 34, \u2116 8. \u2013 \u0420. 1653\u20131660.<br \/>\n5. \u0428\u0443\u043c\u0441\u043a\u0438\u0439 \u0412.\u0424, \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a \u041b.\u0424., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u0413\u0435\u0442\u043c\u0430\u043d\u0447\u0443\u043a \u0418.\u041f., \u0411\u0430\u0431\u0438\u0447 \u041e.\u0412., \u0413\u043e\u043c\u0437\u0430 \u042e.\u041f. \u0412\u043b\u0438\u044f\u043d\u0438\u0435 \u043d\u0430\u043d\u043e\u043d\u0430\u043f\u043e\u043b\u043d\u0438\u0442\u0435\u043b\u044f \u043d\u0430 \u0440\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0443 \u0444\u043e\u0440\u043c\u0438\u0440\u0443\u044e\u0449\u0435\u0439\u0441\u044f in situ \u0441\u043c\u0435\u0441\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0442\u0438\u043b\u043c\u0435\u0442\u0430\u043a\u0440\u0438\u043b\u0430\u0442 \u2013 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2011. \u2013 \u2116 2. \u2013 \u0421. 137\u2013143.<br \/>\n6. \u0428\u0443\u043c\u0441\u043a\u0438\u0439 \u0412.\u0424, \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a \u041b.\u0424., \u0418\u0433\u043d\u0430\u0442\u043e\u0432\u0430 \u0418.\u041f., \u0413\u0435\u0442\u043c\u0430\u043d\u0447\u0443\u043a \u0418.\u041f., \u0413\u0440\u0438\u0449\u0435\u043d\u043a\u043e \u0412.\u041a., \u0411\u0443\u0441\u044c\u043a\u043e \u041d.\u0410., \u0410\u043d\u0442\u043e\u043d\u0435\u043d-\u043a\u043e \u041e.\u0418., \u0411\u0430\u0431\u0438\u0447 \u041e.\u0412. \u0420\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0430 \u0444\u043e\u0440\u043c\u0438\u0440\u043e\u0432\u0430\u043d\u0438\u044f in situ \u0441\u043c\u0435\u0441\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0442\u0438\u043b\u043c\u0435\u0442\u0430\u043a\u0440\u0438\u043b\u0430\u0442 \u2013 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d \u0432 \u043f\u0440\u0438\u0441\u0443\u0442\u0441\u0442\u0432\u0438\u0438 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u043d\u043e\u0433\u043e \u0438\u043d\u0438\u0446\u0438\u0430\u0442\u043e\u0440\u0430 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u0438\u0437\u0430\u0446\u0438\u0438. \u041c\u043e\u0440\u0444\u043e\u043b\u043e\u0433\u0438\u044f \u0438 \u043c\u0435\u0445\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u043a\u043e\u043d\u0435\u0447\u043d\u044b\u0445 \u043f\u0440\u043e\u0434\u0443\u043a\u0442\u043e\u0432 \u0440\u0435\u0430\u043a\u0446\u0438\u0438 \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0411. \u2013 2015. \u2013 57, \u2116 5. &#8211; \u0421. ????<br \/>\n7. Sperling L.H. Interpenetrating polymer networks and related materials. \u2013 New York, London: Plenum Press, 1981. \u2013 260 p.<br \/>\n8. Lipatov Yu.S., Alekseeva T.T. Phase-separated interpenetrating polymer networks \/\/ Adv. Polym. Sci. \u2013 2007. \u2013 208. \u2013 P. 1\u2013234.<br \/>\n9. Ignatova T.D., Kosyanchuk L.F., Todosiychuk T.T., Nesterov A.E. Reaction-induced phase separation and structure formation in polymer blends \/\/ Composite Interfaces. \u2013 2011. \u2013 18, \u2116 3. \u2013 P. 185\u2013236.<br \/>\n10. Yamanaka K., Takagi Y., Inoue T. Reaction-induced phase separation in rubber-modified epoxy resins \/\/ Polymer. \u2013 1989. \u2013 30, \u2116 10. \u2013 \u0420. 1839\u20131844.<br \/>\n11. Yamanaka K., Inoue T. Structure development in epoxy resin modified with poly(ether sulphone) \/\/ Polymer. \u2013 1989. \u2013 30, \u2116 4. \u2013 \u0420. 662\u2013667.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.38.01.024 Features of the formation, the phase structure, viscoelastic and mechanical properties of the binary polymer matrice based on polymethylmethacrylate, modified by crosslinked polyurethane &nbsp; N.V. Babkina, T.D. Ignatova, L.F. Kosyanchuk,\u00a0 O.I. Antonenko, L.A. Vorontsova, O.V. Babich &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske sh\u043ese, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2016, [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1787"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1787"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1787\/revisions"}],"predecessor-version":[{"id":2176,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1787\/revisions\/2176"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1787"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}