{"id":1793,"date":"2018-01-10T14:38:27","date_gmt":"2018-01-10T11:38:27","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1793"},"modified":"2018-02-14T15:45:38","modified_gmt":"2018-02-14T12:45:38","slug":"2016-1-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2016-1-5\/","title":{"rendered":"2016 (1) 5"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.38.01.040<\/a><\/p>\n

Formation and Properties of UV-cured Dyane Epoxy Resins and Epoxy-Acrylate Interpenetrating Polymer Networks on their Base<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

T.F.<\/em><\/strong> Samoilenko<\/em><\/strong>1<\/em><\/strong>,<\/em><\/strong> N.V.<\/em><\/strong> Iarova<\/em><\/strong>1<\/em><\/strong>,<\/em><\/strong> S.M.<\/em><\/strong> Ostapiuk<\/em><\/strong>1<\/em><\/strong>,<\/em><\/strong> M.H.<\/em><\/strong> Tkalich<\/em><\/strong>1<\/em><\/strong>,<\/em><\/strong> O.I.<\/em><\/strong> Demchyna<\/em><\/strong>2<\/em><\/strong>,<\/em><\/strong> I.I.<\/em><\/strong> Ievchuk<\/em><\/strong>2<\/em><\/strong>,<\/em><\/strong> O.O.<\/em><\/strong> Brovko<\/em><\/strong>1<\/em><\/strong><\/p>\n

 <\/p>\n

1Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine. \u0415-mail: s_t_f@ukr.net<\/a><\/u><\/p>\n

2Department of Physics and Chemistry of Combustible Minerals of L.M.\u00a0Lytvynenko Institute of Physical Organic and Coal Chemistry NAS of Ukraine<\/p>\n

3a, Naukova str.,\u00a0Lviv, 79060, Ukraine.<\/p>\n

 <\/p>\n

Polym. J., 2016, 38<\/strong>, no. 1: 40-46.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

The paper represents the results of investigation of kinetics, morphology and properties of photocured epoxy-acrylate interpenetrating polymer networks on the base of dyane epoxy resins and triethylene glycol dimethacrylate. The results of kinetic research of photopolymerization in laboratory and natural conditions under UV-lamp and sunlight respectively, obtained by means of IR-spectroscopy and laser interferometry, showed a favorable effect of high temperature and summer sunlight on the epoxy groups conversion. It was demonstrated that reaction conditions influence such properties of photocured interpenetrating polymer networks as density, gel fraction, molecular mass between cross-links, and phase morphology. In particular, under photopolymerization in oxygen-free conditions unlike under polymerization in the atmosphere of air the samples of interpenetrating polymer networks have higher values of density and gel fraction. The systems that consist of one phase form mainly in the close forms, whereas the systems that consist of two phases form in the open one.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Key words:<\/strong> epoxy-acrylate interpenetrating polymer networks, dyane epoxy resins, sunlight induced photopolymerization, IR-spectroscopy, laser interferometry, dynamic mechanical analysis.<\/p>\n

 <\/p>\n

\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

1. \u0411\u0440\u043e\u0432\u043a\u043e \u041e. \u041e., \u0413\u043e\u043d\u0447\u0430\u0440\u043e\u0432\u0430 \u041b. \u0410., \u0428\u0442\u043e\u043c\u043f\u0435\u043b\u044c \u0412. \u0406., \u0421\u0435\u0440\u0433\u0435\u0454\u0432\u0430 \u041b. \u041c., \u041a\u043e\u0447\u0435\u0442\u043e\u0432 \u041e. \u041e., \u0411\u043e\u043d\u0434\u0430\u0440\u0435\u043d\u043a\u043e \u041f. \u041e. \u0415\u043f\u043e\u043a\u0441\u0438-\u0430\u043a\u0440\u0438\u043b\u0430\u0442\u043d\u0456 \u0432\u0437\u0430\u0454\u043c\u043e\u043f\u0440\u043e\u043d\u0438\u043a\u043d\u0456 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0456 \u0441\u0456\u0442\u043a\u0438: \u0441\u0438\u043d\u0442\u0435\u0437, \u043c\u0456\u043a\u0440\u043e\u0444\u0430\u0437\u043e\u0432\u0430 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0430 \u0442\u0430 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2005. \u2013 27, \u2116 1. \u2013 \u0421. 45-50.
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https:\/\/doi.org\/10.15407\/polymerj.38.01.040 Formation and Properties of UV-cured Dyane Epoxy Resins and Epoxy-Acrylate Interpenetrating Polymer Networks on their Base \u00a0 T.F. Samoilenko1, N.V. Iarova1, S.M. Ostapiuk1, M.H. Tkalich1, O.I. Demchyna2, I.I. Ievchuk2, O.O. Brovko1   1Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine. \u0415-mail: s_t_f@ukr.net 2Department of Physics and Chemistry of Combustible […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1793"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1793"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1793\/revisions"}],"predecessor-version":[{"id":2178,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1793\/revisions\/2178"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1793"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}