{"id":1831,"date":"2018-01-10T15:29:29","date_gmt":"2018-01-10T12:29:29","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1831"},"modified":"2018-02-14T18:08:35","modified_gmt":"2018-02-14T15:08:35","slug":"2015-1-4","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-1-4\/","title":{"rendered":"2015 (1) 4"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.37.01.027<\/a><\/p>\n

The effect of molecular weight on the kinetics of nanolayers formation under adsorption of the mixtures of nonpolar polymers<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

V.N. Chornaya, G.Y. Menzheres, T.T. Todosiichuk<\/em><\/strong><\/p>\n

 <\/p>\n

Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

 <\/p>\n

Polym. J., 2015, 37<\/strong>, no. 1: 27-33.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Russian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

Kinetics of adsorption from the solutions of nonpolar polymer mixtures was studied by IR-spectroscopy under the changing of molecular weight of the polymer components. It was shown that value of adsorption, energy of adsorption interaction, and heat of adsorption decreases with the increasing of polymer chain length, which indicates a deterioration of adsorbent macromolecules affinity to the surface with the increasing of their molecular weight. The separate adsorptive interactions were registered in the IR spectra for each mixture component in the region of valence vibrations of the hydroxyl groups of adsorbent (aerosil. The intensity of these interactions diminishes with the increasing of the molecular weight.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Keywords: <\/strong>adsorption kinetics, solutions of polymer mixtures, molecular weight, adsorption nanolayers.<\/p>\n

 <\/p>\n

\u041b\u0438\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

1. Kaboto Moses T., Blum Frank D., Kulkeratiyut Suntree, Kulkeratiyut Suriyaphongse, Krisanangkura Piyawan. \/\/ J. Polym. Sci. B. -2008. \u2013 46, N 6. – P. 649-658.
\n2. Zhao J.C., Jiand S.C., Wang Q., Liu X.B., Ji M.L., Jiang B.Z. \/\/ Applied Surface Sci. – 2004. – 236, N 1-4. – P. 131-140.
\n3. Fan Lixin, Degen Mike, Grupido Nick, Bendle Scott, Pennartz Paul. \/\/ Mater. Sci. and Eng. Part A. – 2010. \u2013 528, N 1. – P. 127-136.
\n4. Lipatov Yu.S., Todosiichuk T.T., Chornaya V.N. \/\/ Composite Interfaces – 1994. – 2, N 1. – P. 53- 69.
\n5. Curthoys G., Davidov V.Ya., Kiselev A.V., Kiselev S. A., Kuznetsov B.V. \/\/ J. Colloid Interface Sci. – 1974. \u2013 48, N 1. – P. 58-72.
\n6. E. Dietz. \/\/ Makromol. Chem. 1976. – 177. – S. 2113-2137.
\n7. \u0427\u043e\u0440\u043d\u0430\u044f \u0412.\u041d., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u041c\u0435\u043d\u0436\u0435\u0440\u0435\u0441 \u0413.\u042f. \/\/ \u041f\u043e\u043b\u0438\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. – 2013. \u2013 35, \u2116 4. – \u0421. 355-361.
\n8. \u0424\u043b\u0438\u0440 \u0413., \u041b\u0438\u043a\u043b\u0435\u043c\u0430 \u042f. \u0410\u0434\u0441\u043e\u0440\u0431\u0446\u0438\u044f \u0438\u0437 \u0440\u0430\u0441\u0442\u0432\u043e\u0440\u043e\u0432 \u043d\u0430 \u043f\u043e\u0432\u0435\u0440\u0445\u043d\u043e\u0441\u0442\u044f\u0445 \u0442\u0432\u0435\u0440\u0434\u044b\u0445 \u0442\u0435\u043b. IV \u0433\u043b. \u0410\u0434\u0441\u043e\u0440\u0431\u0446\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \/ \u041f\u043e\u0434. \u0440\u0435\u0434. \u041f\u0430\u0440\u0444\u0438\u0442\u0430 \u0413., \u0420\u043e\u0447\u0435\u0441\u0442\u0435\u0440\u0430 \u041a. – \u041c.: \u041c\u0438\u0440, 1986. – \u0421. 182-260.
\n9. Seyrek Emek, Hierezuelo Jos\u043b, Sadeghpour Amin, Szilagyi Istvan, Borkovec Michal. \/\/ Phys. Chem. Chem. Phys. – 2011. \u2013 13, N 28. – P. 12716-12719.
\n10. Kawaguchi M., Kawarabayashi M., Nagata N., Ka- to T.,Yoshioka A. \/\/ Macromolecules. – 1988. – 21. – P. 1059-1062.
\n11. Babak V.G., Boury F. \/\/ Colloids Surf. Part A. – 2004. \u2013 243, N 13. – P. 3580-3588.
\n12. Lipatov Y.S. Adsorption of polymers in mixed polymer systems. Encyclopedia of surface and colloid sci. – New York:Marsel Dekker, 2004. – P. 1-18.
\n13. \u041b\u0438\u043f\u0430\u0442\u043e\u0432 \u042e.\u0421., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u0427\u043e\u0440\u043d\u0430\u044f \u0412.\u041d. \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. – 2005. \u2013 71, \u2116 5. – \u0421. 3-11.
\n14. \u0422\u0440\u0435\u0442\u044c\u044f\u043a\u043e\u0432 \u0414.\u0414. \/\/ \u0423\u0441\u043f\u0435\u0445\u0438 \u0445\u0438\u043c\u0438\u0438. -2003. \u2013 72, \u2116 8. – \u0421. 731-763.
\n15. Kawaguchi M., Aoki M., Takahashi A. \/\/ Macromolecules – 1983. \u2013 16, N 2. – P. 635-640.
\n16. Lipatov Yu.S., Chornaya V.N., Todosiichuk T.T., Menzheres G. Ya. \/\/ J. Colloid Interface Sci. – 2004. \u2013 272, N 2. – P. 281-287.
\n17. Sintes N., Sumithra K., Straude E. \/\/ Macromolecules. – 2001. \u2013 34, N 5. – P. 1352-1357.
\n18. Kramarenko E.Yu., Winkler R.G., Khalature P.G., Khoklov A.R., Reineker P. \/\/ J. Chem. Phys. – 1996. \u2013 104, \u2116 12. – P. 4806 – 4814.
\n19. Lipatov Y.S., Chornaya V.N., Todosiychuk T.T., Menzheres G. Ya., Maslak Yu.V. \/\/ Colooids and Surfaces. Part A: Physicochem. Eng. Aspects – 2007. \u2013 299, N 1-3. – P. 239-246.
\n20. Chornaya V.N., Todosiychuk T.T., Menzheres G. Ya., Lipatov Y.S., Maslak Yu.V. \/\/ Colooids and Surfaces. Part A: Physicochem. Eng. Aspects – 2008. \u2013 318, N 1-3. – P. 53-61.
\n21. \u0427\u043e\u0440\u043d\u0430\u044f \u0412.\u041d., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u041c\u0435\u043d\u0436\u0435\u0440\u0435\u0441 \u0413.\u042f. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0410. – 2009. \u2013 51, \u2116 7. – \u0421. 1155-1164.<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.37.01.027 The effect of molecular weight on the kinetics of nanolayers formation under adsorption of the mixtures of nonpolar polymers \u00a0 V.N. Chornaya, G.Y. Menzheres, T.T. Todosiichuk   Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine   Polym. J., 2015, 37, no. 1: 27-33.   Section: Structure and properties.   […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1831"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1831"}],"version-history":[{"count":3,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1831\/revisions"}],"predecessor-version":[{"id":2232,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1831\/revisions\/2232"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1831"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}