{"id":1851,"date":"2018-01-10T15:45:34","date_gmt":"2018-01-10T12:45:34","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1851"},"modified":"2018-02-14T18:17:04","modified_gmt":"2018-02-14T15:17:04","slug":"2015-1-10","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-1-10\/","title":{"rendered":"2015 (1) 10"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.01.068\">https:\/\/doi.org\/10.15407\/polymerj.37.01.068<\/a><\/p>\n<p><strong>Self-initiated dispersion homopolymerization of inimer \u2013 2 hydroperoxy-2-metyl-hexen-3-in-3 in water<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>S.M. Varvarenko<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Lviv Polytechnic National University<\/p>\n<p>12, S. Bandera str., Lviv, 79013, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 1: 68-73.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Synthesis polymers.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Features of the formation of polymer dispersed phase obtained via homopolymerization of inimer &#8211; 2 hydroperoxy-2-metyl-hexen-3-in-3 in water have been studied. Concentration and temperature ranges of self-initiated radical polymerization to form stable polymer dispersions are established. Initiator and monomer properties combined in the molecule of 2-hydroperoxy-2metyl-hexen-3-in-3 lead to the peculiarities of its radical polymerization in water and nucleation of polymer particles from initial homogeneous aqueous monomer solution. Study of the monomer conversion affect on the polydispersity coefficient allowed to confirm flocculation processes occurring in the system and to establish the conditions affecting on the formation of polymer dispersions with equal-sized particles.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words:<\/strong> Dispersion polymerization, polydispersity coefficient, conversion, homogeneous nucleation.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u0412\u043e\u0440\u043e\u043d\u043e\u0432 \u0421.\u0410., \u041f\u0443\u0447\u0438\u043d \u0412.\u0410., \u0422\u043e\u043a\u0430\u0440\u0435\u0432 \u0412.\u0421., \u041b\u0430\u0441\u0442\u0443- \u0445\u0438\u043d \u042e.\u0410. \/\/ \u0414\u043e\u043a\u043b. \u0410\u041d \u0423\u0421\u0421\u0420. \u0421\u0435\u0440. \u0411. -1979.- \u2116 10. &#8211; \u0421. 828-831.<br \/>\n2. \u041a\u0438\u0441\u0435\u043b\u0435\u0432 \u0415.\u041c., \u0411\u0443\u0434\u0438\u0448\u0435\u0432\u0441\u043a\u0430\u044f \u041e.\u0413., \u0417\u0430\u0439\u0446\u0435\u0432 \u042e.\u0421., \u0413\u0440\u0438\u0446\u043a\u043e\u0432\u0430 \u0418.\u0410., \u041f\u0443\u0447\u0438\u043d \u0412.\u0410. \/\/ \u041a\u043e\u043b\u043b\u043e\u0438\u0434\u043d. \u0436\u0443\u0440\u043d.-1990.- 52, \u21164.- \u0421. 783-785.<br \/>\n3. \u0411\u0443\u0434\u0438\u0448\u0435\u0432\u0441\u043a\u0430\u044f \u041e.\u0413. \u0421\u0438\u043d\u0442\u0435\u0437 \u0438 \u0444\u0438\u0437\u0438\u043a\u043e-\u0445\u0438\u043c\u0438\u0447\u0435\u0441\u043a\u043e\u0435 \u0438\u0437\u0443\u0447\u0435\u043d\u0438\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u0438 \u0441\u043e\u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u0430\u043b\u043a\u0435\u043d\u0430\u043b\u043a\u0438\u043d\u043d\u043e\u0433\u043e \u0433\u0438\u0434\u0440\u043e\u043f\u0435\u0440\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0433\u043e \u043c\u043e\u043d\u043e\u043c\u0435\u0440\u0430. &#8211; \u0414\u0438\u0441. &#8230; \u043a\u0430\u043d\u0434. \u0445\u0438\u043c. \u043d\u0430\u0443\u043a. &#8211; \u041b\u044c\u0432\u043e\u0432. &#8211; 1991. &#8211; 183\u0441.<br \/>\n4. \u041a\u0435\u0434\u0438\u043a \u0421.\u0410., \u0413\u0440\u0438\u0446\u043a\u043e\u0432\u0430 \u0418.\u0410., \u041f\u0440\u043e\u043a\u043e\u043f\u043e\u0432 \u041d.\u0418., \u0421\u0442\u0430\u043d\u0438\u0448\u0435\u0432\u0441\u043a\u0438\u0439 \u042f.\u041c., \u041f\u0430\u043d\u043e\u0432 \u0410.\u0412., \u0421\u0443\u0441\u043b\u043e\u0432 \u0412.\u0412., \u041f\u0435\u0442\u0440\u043e-\u0432\u0430 \u0415.\u0410. \/\/ \u0412\u0435\u0441\u0442\u043d\u0438\u043a \u041c\u0418\u0422\u0425\u0422. &#8211; 2013.- 8, \u21164.- \u0421.26-32.<br \/>\n5. Microarrays. Preparation, Microfluidics, Detection Methods and Biological Applications \/ Ed. by K. Dill, R. Liu, P. Grodzinski. \u2013 Springer, 2009. \u2013 356\u0440.<br \/>\n6. \u0410.\u0421.1225226 \u0421\u0421\u0421\u0420, \u041c\u041a\u04183 \u042107 \u0441179\/06. \u0421\u043f\u043e\u0441\u043e\u0431 \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u0438\u044f \u0433\u0438\u0434\u0440\u043e\u043f\u0435\u0440\u043e\u043a\u0441\u0438\u0434\u043e\u0432\/ \u041c.\u0420. \u0412\u0438\u043b\u0435\u043d\u0441\u043a\u0430\u044f, \u0413.\u0410. \u041f\u0435\u0442-\u0440\u043e\u0432\u0441\u043a\u0430\u044f, \u042e.\u0412. \u041f\u0430\u043d\u0447\u0435\u043d\u043a\u043e. \u2013 \u041e\u043f\u0443\u0431\u043b. 4.09.1985.<br \/>\n7. \u041f\u0430\u043d\u0447\u0435\u043d\u043a\u043e \u042e.\u0412., \u041f\u0435\u0442\u0440\u043e\u0432\u0441\u043a\u0430\u044f \u0413.\u0410., \u041a\u0443\u0448\u043d\u0438\u0440 \u041b.\u0412., \u041f\u0443\u0447\u0438\u043d \u0412.\u0410. \/\/ \u0416\u0443\u0440\u043d. \u043e\u0440\u0433. \u0445\u0438\u043c\u0438\u0438. \u2013 1987. \u2013 \u0425\u0425\u0406\u0406, \u2116 9. &#8211; \u0421. 1844-1846.<br \/>\n8. P.A. Weerts, A.L. German \/\/ Macromolecules. \u2013 1991. &#8211; \u2116 24. \u2013 P. 1622-1628.<br \/>\n9. Ugelstad J., Kaggerud K.H., Hansen F.K. and Berge A. \/\/ Makromol. Chem. \u2013 1979. &#8211; 180. &#8211; P. 730-737.<br \/>\n10. Ugelstad J., Hansen F.K., Lange S. \/\/ Makromol. Chem. \u2013 1974. \u2013 175. &#8211; P. 507-527.<br \/>\n11. \u0414\u0438\u0441\u043f\u0435\u0440\u0441\u0438\u043e\u043d\u043d\u0430\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u0438\u0437\u0430\u0446\u0438\u044f \u0432 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0441\u0440\u0435\u0434\u0430\u0445\/ \u041f\u043e\u0434 \u0440\u0435\u0434. \u041a.\u0415.\u0414\u0436. \u0411\u0430\u0440\u0440\u0435\u0442\u0442\u0430. \u2013 \u041b.: \u0425\u0438\u043c\u0438\u044f, 1979. \u2013 338\u0441.<br \/>\n12. Fitch R.M., Tsai C.H.\/\/ Polymer Colloids. Plenum Press. &#8211; New York, 1971. &#8211; P. 73-103.<br \/>\n13. \u0411\u0430\u043a\u0430\u0435\u0432\u0430 \u0422.\u0418., \u0415\u043b\u0438\u0441\u0435\u0435\u0432\u0430 \u0412.\u0418., \u0417\u0443\u0431\u043e\u0432 \u041f.\u0418. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. &#8211; 1966. &#8211; 8, \u2116 6. &#8211; C. 1073-1078.<br \/>\n14. \u0415\u043b\u0438\u0441\u0435\u0435\u0432\u0430 \u0412.\u0418., \u0411\u0430\u043a\u0430\u0435\u0432\u0430 \u0422.\u0412. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0410. &#8211; 1969. &#8211; \u2116 10. &#8211; \u0421. 2186-2190.<br \/>\n15. \u0417\u0443\u0439\u043a\u043e\u0432 \u0410.\u0412., \u0412\u0430\u0441\u0438\u043b\u0435\u043d\u043a\u043e \u0410.\u0418. \/\/ \u041a\u043e\u043b\u043b\u043e\u0438\u0434\u043d. \u0436\u0443\u0440\u043d. &#8211; 1975.- 37,- \u2116 4. &#8211; \u0421. 640-644.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.01.068 Self-initiated dispersion homopolymerization of inimer \u2013 2 hydroperoxy-2-metyl-hexen-3-in-3 in water \u00a0 S.M. Varvarenko &nbsp; Lviv Polytechnic National University 12, S. Bandera str., Lviv, 79013, Ukraine &nbsp; Polym. J., 2015, 37, no. 1: 68-73. &nbsp; Section: Synthesis polymers. &nbsp; Language: Ukrainian. &nbsp; Abstract: Features of the formation of polymer dispersed phase obtained via homopolymerization of [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1851"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1851"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1851\/revisions"}],"predecessor-version":[{"id":2238,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1851\/revisions\/2238"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1851"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}