{"id":1854,"date":"2018-01-10T15:48:11","date_gmt":"2018-01-10T12:48:11","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1854"},"modified":"2018-02-14T18:18:26","modified_gmt":"2018-02-14T15:18:26","slug":"2015-1-11","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-1-11\/","title":{"rendered":"2015 (1) 11"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.01.074\">https:\/\/doi.org\/10.15407\/polymerj.37.01.074<\/a><\/p>\n<p><strong>Features thermolysis of peroxide groups in copolymers<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>N.G. Nosova<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Lviv Polytechnic National University<\/p>\n<p>12, S. Bandera str., Lviv, 79013, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 1: 74-80.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Synthesis polymers.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Features of ditertiary peroxide group thermolysis during thermal decomposition of the peroxide groups in copolymer have been discovered and described. Based on these studies it was concluded that the conformation of macromolecules of peroxide-containing copolymers affects the ratio between the primary and induced peroxide groups decomposition. Reducing of contribution of the induced decomposition can take place due to macromolecule conformation changes in \u201cgood\u201d solvents or temperature increase above 443 K.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords:<\/strong> peroxide, thermolysis, macroinitiator.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Voronov S., Tokarev V., Datsyuk V., Kozar M. \/\/ Progr. Colloid Polym. Sci.-No.101.-1996.-P.182-193.<br \/>\n2. Wagenknecht U., Kretcschmar B., Tokarev V., Voro-nov S. \/\/ Technomer \u2013 97.- 1997.- S.1-7.<br \/>\n3. Voronov S., Tokarev V., Petrovska G. Heterofunctional polyperoxides. Theoretical basis of their synthesis and application in compounds. \u2013 Lviv: State University Lvivska Polytechnica Press, 1994. \u2013 P. 85.<br \/>\n4. Roiter Yu., Samaryk V., Nosova N., Varvarenko S., Poetschke P., Voronov S. \/\/ Macromol. Symp. -2001. &#8211; \u2116164. &#8211; P. 377-387.<br \/>\n5. \u0412\u043e\u0440\u043e\u043d\u043e\u0432 \u0421.\u0410., \u0421\u0430\u043c\u0430\u0440\u0438\u043a \u0412.\u042f., \u0412\u0430\u0440\u0432\u0430\u0440\u0435\u043d\u043a\u043e \u0421.\u041c., \u041d\u043e\u0441\u043e\u0432a \u041d.\u0413., \u0420\u043e\u0439\u0442\u0435\u0440 \u042e.\u0412. \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. &#8211; 2002. &#8211; \u2116 6. &#8211; \u0421.147-150.<br \/>\n6. Nosova N., Roiter Yu., Samaryk V., Varvarenko S., Stetsyshyn Yu., Minko S., Stamm M., Voronov S. \/\/ Macromol. Symp. &#8211; 2004. &#8211; \u2116 210. &#8211; P.339-338.<br \/>\n7. \u0412\u043e\u0440\u043e\u043d\u043e\u0432 \u0421.\u0410., \u0412\u0430\u0440\u0432\u0430\u0440\u0435\u043d\u043a\u043e \u0421.\u041c. \u041f\u0435\u0440\u043e\u043a\u0441\u0438\u0434\u043e\u0432\u043c\u0456\u0441\u043d\u0456 \u043c\u0430\u043a\u0440\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u0438 \u043d\u0430 \u043c\u0435\u0436\u0456 \u0440\u043e\u0437\u0434\u0456\u043b\u0443 \u0444\u0430\u0437. \u2013 \u041b\u044c\u0432\u0456\u0432: \u041b\u044c\u0432\u0456\u0432\u0441\u044c\u043a\u0430 \u043f\u043e\u043b\u0456\u0442\u0435\u0445\u043d\u0456\u043a\u0430, 2011. \u2013 333 \u0441.<br \/>\n8. Varvarenko S., Voronov A., Samaryk V., Tarnavchyk I., Nosova N., Kohut A., Voronov S. \/\/ Reactive and Functional Polymers \u2013 2010.- \u2116 70.- P. 647-655.<br \/>\n9. Samaryk V., Voronov A., Tarnavchyk I., Varvarenko S., Nosova N., Kohut A., Voronov S. \/\/ Radical Polymerization: New Developments. Nova Science Publishers Inc. -Chapter 1. &#8211; 2011.- P.3-62.<br \/>\n10. Samaryk V., Nosova N., Varvarenko S., Tarnavchyk I., Puzko N., Voronov S. \/\/ Chem. and Chem. Technol. &#8211; 2011.- 5, \u2116 4. &#8211; P. 377-383.<br \/>\n11. Voronov S., Kohut A., Tarnavchyk I., Voronov A. \/\/ Curr. Opin. Colloid Interface Sci. -2014. &#8211; 19, \u2116 2. &#8211; P. 95-121.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.01.074 Features thermolysis of peroxide groups in copolymers \u00a0 N.G. Nosova &nbsp; Lviv Polytechnic National University 12, S. Bandera str., Lviv, 79013, Ukraine &nbsp; Polym. J., 2015, 37, no. 1: 74-80. &nbsp; Section: Synthesis polymers. &nbsp; Language: Ukrainian. &nbsp; Abstract: Features of ditertiary peroxide group thermolysis during thermal decomposition of the peroxide groups in copolymer [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1854"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1854"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1854\/revisions"}],"predecessor-version":[{"id":2239,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1854\/revisions\/2239"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1854"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}