{"id":1860,"date":"2018-01-10T15:52:59","date_gmt":"2018-01-10T12:52:59","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1860"},"modified":"2018-02-14T18:21:51","modified_gmt":"2018-02-14T15:21:51","slug":"2015-1-13","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-1-13\/","title":{"rendered":"2015 (1) 13"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.01.085\">https:\/\/doi.org\/10.15407\/polymerj.37.01.085<\/a><\/p>\n<p><strong>Thermostability of epoxide compounds hardened by polyethylenpolyamine<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>V.V.Boyko<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, T.V. Dmitrieva<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, V.I. Bortnitskii<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Yu.R. Ebich<\/em><\/strong><strong><em>2<\/em><\/strong><strong><em>, A.Yu. Poloz<\/em><\/strong><strong><em>2<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>The state higher education institution \u201cUkrainian State University of Chemical Engineering\u201d<\/p>\n<p>8, Gagarina av., Dnipropetrovsk, 49005, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 1: 41-48.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Thermal mass-spectrometry (TMS) has been employed to investigate a processes of thermal destruction of unadulterated and filled with<\/em> <em>the silicon carbide epoxide compounds based on the dian resin ED-20 with addition of diglycidol<\/em> <em>ether diethylene glycol depending on<\/em> <em>parameter<\/em> <em>epoxy cure by the polyethylenpolyamine.<\/em> <em>A<\/em> <em>thermodestruction mechanism of epoxide compounds are explained. It is shown that a temperature of compounds heat treatment has an influence on structural characteristis of their trimerous net and a temperature of glass transition.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words<\/strong>: epoxide compound, polyethylenpolyamine, thermostability, ionic fragment, thermogram, procedure of heat treatment.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u041f\u0435\u043d\u043a\u0438\u043d \u041d.\u0421., \u041a\u0430\u043f\u0440\u0430\u043b\u043e\u0432 \u0415.\u041f. \u041f\u043e\u0432\u044b\u0448\u0435\u043d\u0438\u0435 \u0438\u0437\u043d\u043e\u0441\u043e\u0441\u0442\u043e\u0439\u043a\u043e\u0441\u0442\u0438 \u0433\u043e\u0440\u043d\u043e-\u043e\u0431\u043e\u0433\u0430\u0442\u0438\u0442\u0435\u043b\u044c\u043d\u043e\u0433\u043e \u043e\u0431\u043e\u0440\u0443\u0434\u043e\u0432\u0430\u043d\u0438\u044f. \u2013 \u041c.: \u041d\u0435\u0434\u0440\u0430, 1992. \u2013 265 \u0441.<br \/>\n2. \u0425\u0440\u0443\u0449\u043e\u0432 \u041c.\u041c., \u0411\u0430\u0431\u0438\u0447\u0435\u0432 \u041c.\u0410. \u0410\u0431\u0440\u0430\u0437\u0438\u0432\u043d\u043e\u0435 \u0438\u0437\u043d\u0430\u0448\u0438\u0432\u0430\u043d\u0438\u0435. \u2013 \u041c.: \u041d\u0430\u0443\u043a\u0430, 1970. \u2013 270 \u0441.<br \/>\n3. \u042f\u0433\u0435\u0440 \u041c. \/\/ \u041a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u043d\u044b\u0439 \u043c\u0438\u0440. \u2013 2010. \u2013 \u2116 29. \u2013 \u0421.6-15.<br \/>\n4. \u041f\u043e\u043b\u043e\u0437 \u041e.\u042e., \u041b\u0438\u043f\u0438\u0446\u044c\u043a\u0438\u0439 \u0421.\u0413., \u041a\u0443\u0449\u0435\u043d\u043a\u043e \u0421.\u041c., \u0421\u0435\u043c\u0435-\u043d\u0435\u0446\u044c \u041e.\u0410., \u0415\u0431\u0456\u0447 \u042e.\u0420. \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c. \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. \u2013 2012. &#8211; \u2116 1. \u2013 \u0421. 75-80.<br \/>\n5. Durand J. M., Vardavoulias M, Jeandin M. \/\/ Wear. \u20131995. \u2013 \u2116 181\u2013183. \u2013 \u0420. 833\u2013839.<br \/>\n6. Axen N., Jacobson S. \/\/ Wear. \u2013 1994. \u2013 \u2116 174. \u2013 \u0420. 187\u2013189.<br \/>\n7. \u0414\u044b\u0440\u0434\u0430 \u0412.\u0418., \u0427\u0438\u0436\u0438\u043a \u0415.\u0424., \u041a\u0438\u044f\u0448\u043a\u043e \u0412.\u0418., \u041a\u0430\u0440\u0430\u0447\u0430- \u0431\u0430\u043d \u041d.\u0413. \u0420\u0435\u0437\u0438\u043d\u043e\u0432\u044b\u0435 \u0434\u0435\u0442\u0430\u043b\u0438 \u0432 \u0438\u043d\u0436\u0435\u043d\u0435\u0440\u043d\u043e\u0439 \u043f\u0440\u0430\u043a\u0442\u0438\u043a\u0435. \u2013 \u0414\u043d\u0435\u043f\u0440\u043e\u043f\u0435\u0442\u0440\u043e\u0432\u0441\u043a: \u041f\u043e\u043b\u0456\u0433\u0440\u0430\u0444\u0456\u0441\u0442, 1998. \u2013 303 \u0441.<br \/>\n8. \u0414\u044b\u0440\u0434\u0430 \u0412.\u0418. \/\/ \u041f\u0440\u043e\u0431\u043b\u0435\u043c\u044b \u043f\u0440\u043e\u0447\u043d\u043e\u0441\u0442\u0438. \u2013 1982. &#8211; \u21167. \u2013 \u0421. 102-104.<br \/>\n9. \u041b\u0438 \u0425., \u041d\u0435\u0432\u0438\u043b\u043b \u041a. \u0421\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u043e\u0435 \u0440\u0443\u043a\u043e\u0432\u043e\u0434\u0441\u0442\u0432\u043e \u043f\u043e \u044d\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u044b\u043c \u0441\u043c\u043e\u043b\u0430\u043c. \/ \u041f\u0435\u0440. \u0441 \u0430\u043d\u0433\u043b. \u043f\u043e\u0434 \u0440\u0435\u0434. \u041d.\u0412. \u0410\u043b\u0435\u043a-\u0441\u0430\u043d\u0434\u0440\u043e\u0432\u0430. \u2013 \u041c.: \u042d\u043d\u0435\u0440\u0433\u0438\u044f, 1973. \u2013 410 \u0441.<br \/>\n10. \u0411\u043e\u0431\u044b\u043b\u0435\u0432 \u0412.\u0410. \/\/ \u041a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u043d\u044b\u0439 \u043c\u0438\u0440. \u2013 2006. &#8211; \u2116 4. \u2013 \u0421. 20-24.<br \/>\n11. \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u043a\u0438\u0439 \u0420.\u0410., \u041b\u0443\u043a\u0430\u0448\u0435\u043d\u043a\u043e \u0418.\u041c., \u0411\u0440\u043e\u0434\u0441\u043a\u0438\u0439 \u0415.\u0421. \u041f\u0438\u0440\u043e\u043b\u0438\u0442\u0438\u0447\u0435\u0441\u043a\u0430\u044f \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u044f \u0432\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435-\u043a\u0443\u043b\u044f\u0440\u043d\u044b\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1980. &#8211; 280 \u0441.<br \/>\n12. \u0422\u0435\u0440\u0435\u043d\u0442\u044c\u0435\u0432 \u041f.\u0411. \u041c\u0430\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u044f \u0432 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u043e\u0439 \u0445\u0438\u043c\u0438\u0438. &#8211; \u041c.: \u0412\u044b\u0441\u0448\u0430\u044f \u0448\u043a\u043e\u043b\u0430, 1979. \u2013 223 \u0441.<br \/>\n13. \u041c\u0430\u0434\u043e\u0440\u0441\u043a\u0438\u0439 \u0421. \u0422\u0435\u0440\u043c\u0438\u0447\u0435\u0441\u043a\u043e\u0435 \u0440\u0430\u0437\u043b\u043e\u0436\u0435\u043d\u0438\u0435 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \/ \u041f\u0435\u0440. \u0441 \u0430\u043d\u0433\u043b.- \u041c.: \u041c\u0438\u0440, 1967. \u2013 328 \u0441.<br \/>\n14. \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0411\u043e\u0440\u0442\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u0412.\u0406., \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430 \u0422.\u0412. \u0442\u0430 \u0456\u043d. \/\/ \u0423\u043a\u0440. \u0445\u0456\u043c. \u0436\u0443\u0440\u043d. \u2013 2009.- 75, \u2116 11. &#8211; \u0421. 58-62.<br \/>\n15. \u0413\u043e\u0440\u0434\u043e\u043d \u0410., \u0424\u043e\u0440\u0434 \u0420. \u0421\u043f\u0443\u0442\u043d\u0438\u043a \u0445\u0438\u043c\u0438\u043a\u0430 \/ \u041f\u0435\u0440. \u0441 \u0430\u043d\u0433\u043b. &#8211; \u041c.:\u041c\u0438\u0440, 1976. &#8211; 541 \u0441.<br \/>\n16. \u041a\u0430\u0442\u0430\u043b\u043e\u0433 \u0441\u043e\u043a\u0440\u0430\u0449\u0435\u043d\u043d\u044b\u0445 \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u0432. &#8211; \u041d\u043e\u0432\u043e\u0441\u0438\u0431\u0438\u0440\u0441\u043a: \u041d\u0430\u0443\u043a\u0430, 1981. \u2013 187 \u0441.<br \/>\n17. \u041f\u0430\u0440\u0430\u043c\u043e\u043d\u043e\u0432 \u042e.\u041c., \u0410\u0440\u0442\u0435\u043c\u043e\u0432 \u0412.\u041d., \u041a\u043b\u0435\u0431\u0430\u043d\u043e\u0432 \u041c.\u0421. \/\/ \u0420\u0435\u0430\u0446\u0438\u043e\u043d\u043d\u043e\u0441\u043f\u043e\u0441\u043e\u0431\u043d\u044b\u0435 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u044b \u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0435 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b \u043d\u0430 \u0438\u0445 \u043e\u0441\u043d\u043e\u0432\u0435. \u2013 \u041c.: \u041d\u041f\u041e \u00ab\u041f\u043b\u0430\u0441\u0442\u0438\u043a\u00bb, 1976. \u2013 \u0412\u044b\u043f. \u0406\u0406\u0406. \u2013 \u0421. 81-87.<br \/>\n18. \u041d\u043e\u0432\u0430\u043a\u043e\u0432 \u0418.\u0410., \u0427\u0430\u043b\u044b\u0445 \u0410.\u0415., \u041d\u0438\u0441\u0442\u0440\u0430\u0442\u043e\u0432 \u0410.\u0412., \u0424\u0440\u043e\u043b\u043e\u0432\u0430 \u0412.\u0418., \u0425\u0430\u0441\u0431\u0438\u0443\u043b\u043b\u0438\u043d \u0420.\u0420. \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b. \u2013 2011. &#8211; \u2116 6. \u2013 \u0421. 18-22.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.01.085 Thermostability of epoxide compounds hardened by polyethylenpolyamine \u00a0 V.V.Boyko1, T.V. Dmitrieva1, V.I. Bortnitskii1, Yu.R. Ebich2, A.Yu. Poloz2 &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine The state higher education institution \u201cUkrainian State University of Chemical Engineering\u201d 8, Gagarina av., Dnipropetrovsk, 49005, Ukraine &nbsp; Polym. J., 2015, 37, no. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1860"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1860"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1860\/revisions"}],"predecessor-version":[{"id":2241,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1860\/revisions\/2241"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1860"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}