{"id":1869,"date":"2018-01-10T16:02:57","date_gmt":"2018-01-10T13:02:57","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1869"},"modified":"2018-02-14T17:46:14","modified_gmt":"2018-02-14T14:46:14","slug":"2015-2-3","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-2-3\/","title":{"rendered":"2015 (2) 3"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.02.131\">https:\/\/doi.org\/10.15407\/polymerj.37.02.131<\/a><\/p>\n<p><strong>Viscoelastic, thermophisics and relaxation properties of the nanofilled composites based on epoxy polymer<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>V.V. Korskanov, N.V. Babkina, A.A. Brovko,\u00a0 I.L. Karpova, V.V. Klepko<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivs\u2019ke shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 2: 131-136.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The viscoelastic and thermophisics properties of the nanocomposites (NC) based on epoxy resin (ER) and carbon nanotubes (CNT\u2019s) with mass fraction (w) from 0,05 t<\/em><em>\u043e<\/em><em> 1,00 %\u00a0 was investigated.\u00a0 Was discovered\u00a0 the two types of the polological transitions. It is found that the transition from isolated inclusions in a continuous cluster of particles at CST w <\/em>\u00bb<em> 0,1 % leads to a rapid increase\u00a0 of the electrical conductivity, the decrease of the elastic modulus of the matrix and increase of mobility of polymer matrix. The transition from cluster to continuous rigid \u201cframe\u201d in the form of aggregates CST\u2019s when 0,3 % <\/em>\u00a3<em> w <\/em>\u00a3<em> 0,5 % leads to an increase in the thermal conductivity and modulus of elasticity.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words: <\/strong>epoxy polymer, carbon nanotubes, viscoelastic properties, thermophisics properties.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Pantano A., Modica G., Cappello F. Multiwalled carbon nanotube reinforced polymer composites \/\/ Materials Science and Engineering.\u2013 2008.\u2013 \u2116 1-2.\u2013 P. 222-227.<br \/>\n2. \u041b\u0438 \u0425., \u041d\u0435\u0432\u0438\u043b\u043b \u041a. \u0421\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u043e\u0435 \u0440\u0443\u043a\u043e\u0432\u043e\u0434\u0441\u0442\u0432\u043e \u043f\u043e \u044d\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u044b\u043c \u0441\u043c\u043e\u043b\u0430\u043c. \/ \u041f\u0435\u0440. \u0430\u043d\u0433\u043b. \u043f\u043e\u0434 \u0440\u0435\u0434. \u041d.\u0412. \u0410\u043b\u0435\u043a-\u0441\u0430\u043d\u0434\u0440\u043e\u0432\u0430. \u2013 \u041c.: \u042d\u043d\u0435\u0440\u0433\u0438\u044f, 1973. \u2013 416 \u0441.<br \/>\n3. \u041a\u043e\u0440\u0441\u043a\u0430\u043d\u043e\u0432 \u0412.\u0412., \u041c\u0430\u043c\u0443\u043d\u044f \u0404.\u041f., \u041a\u0430\u0440\u043f\u043e\u0432\u0430 \u0406.\u041b. \u0442\u0430 \u0456\u043d. \u0422\u0435\u043f\u043b\u043e- \u0442\u0430 \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043f\u0440\u043e\u0432\u0456\u0434\u043d\u0456\u0441\u0442\u044c \u043d\u0430\u043d\u043e\u043d\u0430\u043f\u043e\u0432\u043d\u0435\u043d\u043e\u0433\u043e \u0435\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0433\u043e \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0443 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d.\u2013 2011. \u2013 33, \u2116 2.\u2013 \u0421. 107\u2013110.<br \/>\n4. \u041a\u043e\u0440\u0441\u043a\u0430\u043d\u043e\u0432 \u0412.\u0412., \u041c\u0430\u043c\u0443\u043d\u044f \u0415.\u041f., \u0411\u0430\u0440\u0434\u0430\u0448 \u041b.\u0412., \u0424\u0430\u0439\u043d\u043b\u0435\u0439\u0431 A.\u041c. \u042d\u043b\u0435\u043a\u0442\u0440\u043e\u043f\u0440\u043e\u0432\u043e\u0434\u043d\u043e\u0441\u0442\u044c \u043d\u0430\u043d\u043e\u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u043e\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0435 \u0441\u0435\u0442\u0447\u0430\u0442\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u0438 \u043a\u0430\u0440\u0431\u043e\u043d\u0430\u043d\u043e\u0442\u0440\u0443\u0431\u043e\u043a\/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2012. \u2013 \u2116 12. \u2013 \u0421. 111-117.<br \/>\n5. \u0423\u0441\u0435\u043d\u043a\u043e \u0410.\u0410., \u041a\u043e\u0440\u0441\u043a\u0430\u043d\u043e\u0432 \u0412.\u0412., \u0414\u0430\u0432\u0438\u0434\u0435\u043d\u043a\u043e \u0412.\u0412. \u0442\u0430 \u0456\u043d. \u0422\u0435\u043f\u043b\u043e\u0444\u0456\u0437\u0438\u0447\u043d\u0456 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456 \u0442\u0430 \u0442\u0435\u0440\u043c\u043e\u0434\u0438\u043d\u0430\u043c\u0456\u043a\u0430 \u043d\u0430\u043d\u043e\u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u0456\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u0435\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0433\u043e \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0443 \u0442\u0430 \u043a\u0430\u0440\u0431\u043e\u043d\u0430\u043d\u043e\u0442\u0440\u0443\u0431\u043e\u043a \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2011. \u2013 33, \u2116 4. \u2013 \u0421. 234-243.<br \/>\n6. \u041b\u0435\u043c\u0435\u0448 \u041d.\u0412, \u041b\u044b\u0441\u0435\u043d\u043a\u043e\u0432 \u042d.\u0410., \u0413\u043e\u043c\u0437\u0430 \u042e.\u041f., \u041a\u043b\u0435\u043f\u043a\u043e \u0412.\u0412. \u0438 \u0434\u0440. \u0421\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0430 \u043c\u043d\u043e\u0433\u043e\u0441\u043b\u043e\u0439\u043d\u044b\u0445 \u0443\u0433\u043b\u0435\u0440\u043e\u0434\u043d\u044b\u0445 \u043d\u0430\u043d\u043e\u0442\u0440\u0443\u0431\u043e\u043a, \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u043d\u044b\u0445 \u043a\u0430\u0442\u0430\u043b\u0438\u0442\u0438\u0447\u0435\u0441\u043a\u0438\u043c \u0440\u0430\u0437\u043b\u043e\u0436\u0435\u043d\u0438\u0435\u043c \u044d\u0442\u0438\u043b\u0435\u043d\u0430 \u043d\u0430 \u043d\u0430\u043d\u043e\u0447\u0430\u0441\u0442\u0438\u0447\u0430\u0445 \u043d\u0438\u043a\u0435\u043b\u044f. \/\/ \u0423\u043a\u0440. \u0445\u0456\u043c. \u0436\u0443\u0440\u043d. \u2013 2010. \u2013 76, \u2116 5. \u2013 \u0421. 29\u201336.<br \/>\n7. \u0414\u0438\u043d\u043d\u0438\u0441\u0435\u043d \u0422., \u0422\u0430\u0448\u043d\u0438\u043a\u043e\u0432\u0430 \u042e.,\u0412. \u041a\u043e\u043d\u0446\u0435\u043f\u0446\u0438\u0438 DOW Chemical \u043f\u0440\u0438 \u0441\u043e\u0441\u0442\u0430\u0432\u043b\u0435\u043d\u0438\u0438 \u0440\u0435\u0446\u0435\u043f\u0442\u0443\u0440 \u044d\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u044b\u0445 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0442\u043e\u0432 \u0434\u043b\u044f \u043f\u0440\u0438\u043c\u0435\u043d\u0435\u043d\u0438\u044f \u0432 \u0433\u0440\u0430\u0436\u0434\u0430\u043d\u0441\u043a\u043e\u043c \u0441\u0442\u0440\u043e\u0438\u0442\u0435\u043b\u044c\u0441\u0442\u0432\u0435 \/\/ \u041b\u0430\u043a\u043e\u043a\u0440\u0430\u0441\u043e\u0447\u043d\u044b\u0435 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b \u0438 \u0438\u0445 \u043f\u0440\u0438\u043c\u0435\u043d\u0435\u043d\u0438\u0435. \u2013 2007. \u2013 \u2116 4. \u2013 C. 1-6.<br \/>\n8. Hutchnson J., Montserrat S., Calvenius Y., Cortes P. On the application of the Adam-Gibbs equation to the non-equilibrium glassy state \/\/ J. of Non-Crystalline Solids. \u2013 2002. \u2013 Vol. 307-310. \u2013 P. 412-416.<br \/>\n9. Adam G. and Gibbs J.H. On the Temperature Dependence of Cooperative Relaxation Properties in Glass Forming Liquids \/\/ J. Phem. Phys.\u2013 1965. \u2013 43, \u2116 1. \u2013 \u0420. 139-146.<br \/>\n10. Calventus Y., Monterrat S., Hutchinson J.M. Enthalpy relaxation of non-stiometric epoxy-amine resins \/\/ Polymer. \u2013 2001. \u2013 42, \u2116 16. \u2013 P. 7081-7093.<br \/>\n11. Angell C.A. Relaxation in liquids, polymers and plastic crystals \u2013 strong\/fragil pattern and problems. \/\/ J. Non-Crystal. Solids. \u2013 1991. \u2013 Vol. 131-133. \u2013 P. 13-31.<br \/>\n12. Rahmanian S., Suraya A.R., Shazed M.A., Zahari R., Zainudin E.S. Mechanical characterization of epoxy composite with multiscale reinforcements: Carbon nanotubes and short carbon \/\/ Materials &amp; Design. \u2013 2014. \u2013 Vol. 60. \u2013 P. 34-40.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.02.131 Viscoelastic, thermophisics and relaxation properties of the nanofilled composites based on epoxy polymer \u00a0 V.V. Korskanov, N.V. Babkina, A.A. Brovko,\u00a0 I.L. Karpova, V.V. Klepko &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivs\u2019ke shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2015, 37, no. 2: 131-136. &nbsp; Section: Structure and properties. &nbsp; Language: Ukrainian. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1869"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1869"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1869\/revisions"}],"predecessor-version":[{"id":2215,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1869\/revisions\/2215"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1869"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}