{"id":1880,"date":"2018-01-10T16:18:28","date_gmt":"2018-01-10T13:18:28","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1880"},"modified":"2018-02-14T17:51:04","modified_gmt":"2018-02-14T14:51:04","slug":"2015-2-6","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-2-6\/","title":{"rendered":"2015 (2) 6"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.02.151\">https:\/\/doi.org\/10.15407\/polymerj.37.02.151<\/a><\/p>\n<p><strong>The influence of copper ion on thermooxidative destruction characteristics of polyglucaneurethane based on xanthan and caprolactame blocked polyisocyanate<\/strong><\/p>\n<p><strong><em>\u00a0N.\u00a0<\/em><\/strong><strong><em>Kozak, K. Didenko, H. Nesterenko, B. Klepko<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 2: 151-156.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The character of polyglucaneurethane interaction with copper ions sorbed from water solution as well as metal ion influence on thermal properties were investigated for polyglucaneurethane based on microbial exopolysaccharide xanthan crosslinked with blocked polyisocyanate. In obedience to electronic paramagnetic resonance method, it was established that, polyglucaneurethane retention of heavy metal ion occurs due to the formation of chelate complexes. According to the results of thermogravimetric analysis, it was shown, that the introduction of copper ions into the system leads to the significant redistribution of the decomposition stage, what is related both to the influence of metal ion complex formation in polyglucaneurethane matrix and to chemical processes changes in the system with catalytically active copper ion complexes.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u041a<\/strong><strong>ey words:<\/strong> polyglucaneurethane, dynamic sorption, copper ion chelates, thermooxydative destruction, activation energy.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Crini G. \/\/ Prog. Polym. Sci. 30. \u2013 2005. \u2013 P. 38\u201370.<br \/>\n2. Kozak N., Hubina A. \/\/ Polyurethane. \u2013 InTech. \u2013 2012. \u2013 P. 431\u2013447.<br \/>\n3. \u0413\u0443\u0431\u0456\u043d\u0430 \u0410.\u0412., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412. \/\/ \u0412\u043e\u043f\u0440. \u0445\u0438\u043c\u0438\u0438 \u0438 \u0445\u0438\u043c. \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438. &#8211; 2011. &#8211; \u2116 6. &#8211; \u0421. 55\u201360.<br \/>\n4. \u0413\u0443\u0431\u0456\u043d\u0430 \u0410.\u0412., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u041f\u043e\u043b\u0456\u0449\u0443\u043a \u041c.\u0412., \u041c\u0430\u0441\u043b\u0435\u043d\u043d\u0456\u043a\u043e-\u0432\u0430 \u041b.\u0414. \/\/ \u0412\u0456\u0441\u043d. \u041a\u041d\u0423\u0414\u0422. &#8211; 2010. &#8211; \u2116 6. &#8211; \u0421. 85\u201391.<br \/>\n5. \u041f\u0430\u0442. \u2116 85207, \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a7 C08\u0412 37\/18, C08G 18\/83. \u0421\u043f\u043e\u0441\u0456\u0431 \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u0430\u0446\u0456\u0457 \u043f\u043e\u043b\u0456\u0441\u0430\u0445\u0430\u0440\u0438\u0434\u0456\u0432 \/ \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u041d\u0456\u0437\u0435\u043b\u044c\u0441\u044c\u043a\u0438\u0439 \u042e.\u041c., \u041c\u043d\u0456\u0445 \u041d.\u0412. \u0442\u0430 \u0456\u043d. \u041e\u043f\u0443\u0431\u043b. 12.01.2009. &#8211; \u0411\u044e\u043b. \u21161.<br \/>\n6. \u041a\u043b\u0438\u043c\u043e\u0432 \u0415.\u0421., \u0411\u0443\u0437\u0430\u0435\u0432\u0430 \u041c.\u0412. \u041f\u0440\u0438\u0440\u043e\u0434\u043d\u044b\u0435 \u0441\u043e\u0440\u0431\u0435\u043d\u0442\u044b \u0438 \u043a\u043e\u043c\u043f\u043b\u0435\u043a\u0441\u043e\u043d\u044b \u0432 \u043e\u0447\u0438\u0441\u0442\u043a\u0435 \u0441\u0442\u043e\u0447\u043d\u044b\u0445 \u0432\u043e\u0434. \u2013 \u0423\u043b\u044c\u044f\u043d\u043e\u0432\u0441\u043a : \u0423\u043b\u0413\u0422\u0423, 2011. \u2013 201 \u0441.<br \/>\n7. \u041c\u0430\u0442\u0432\u0435\u0435\u0432\u0430 \u0422. \u041d. \u0424\u0438\u0437\u0438\u043a\u043e-\u0445\u0438\u043c\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u0441\u043e\u0440\u0431\u0435\u043d\u0442\u043e\u0432, \u043c\u043e\u0434\u0438\u0444\u0438\u0446\u0438\u0440\u043e\u0432\u0430\u043d\u043d\u044b\u0445 \u0430\u0446\u0435\u0442\u0438\u043b\u0430\u0446\u0435\u0442\u043e\u043d\u0430\u0442\u0430\u043c\u0438 \u043c\u0435\u0442\u0430\u043b\u043b\u043e\u0432, \u0438 \u0438\u0445 \u0438\u0441\u043f\u043e\u043b\u044c\u0437\u043e\u0432\u0430\u043d\u0438\u0435 \u0432 \u0433\u0430\u0437\u043e\u0445\u0440\u043e\u043c\u0430\u0442\u043e\u0433\u0440\u0430\u0444\u0438\u0447\u0435\u0441\u043a\u043e\u043c \u0430\u043d\u0430\u043b\u0438\u0437\u0435: \u0430\u0432\u0442\u043e\u0440\u0435\u0444. \u0434\u0438\u0441. \u2026 \u0434.\u0445.\u043d. \u2013 \u0422\u043e\u043c\u0441\u043a, 2002. \u2013 156 \u0441.<br \/>\n8. \u041f\u0430\u0442. \u211661307 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a7 C07C 263\/00, C07C 265\/00 \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u043d\u044f \u0431\u043b\u043e\u043a\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u0456\u0437\u043e\u0446\u0456\u0430\u043d\u0430\u0442\u043d\u043e\u0433\u043e \u043f\u0440\u043e\u0434\u0443\u043a\u0442\u0443 \/ \u041b.\u0424. \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a, \u041d.\u0412. \u041a\u043e\u0437\u0430\u043a, \u042e.\u041c. \u041d\u0456\u0437\u0435\u043b\u044c\u0441\u044c\u043a\u0438\u0439. \u2013 \u041e\u043f\u0443\u0431\u043b. 15.11.2005. &#8211; \u0411\u044e\u043b. \u2116 11.<br \/>\n9. \u0414\u0456\u0434\u0435\u043d\u043a\u043e \u041a.\u0421. \/\/ \u041c\u0430\u0442\u0435\u0440. 8-\u043e\u0439 \u0421\u0430\u043d\u043a\u0442-\u041f\u0435\u0442\u0435\u0440\u0431. \u043a\u043e\u043d\u0444. \u043c\u043e\u043b\u043e\u0434\u044b\u0445 \u0443\u0447\u0435\u043d\u044b\u0445 \u201c\u0421\u043e\u0432\u0440\u0435\u043c\u0435\u043d\u043d\u044b\u0435 \u043f\u0440\u043e\u0431\u043b\u0435\u043c\u044b \u043d\u0430\u0443\u043a\u0438 \u043e \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u0430\u0445\u201d, 12\u201315 \u043d\u043e\u044f\u0431\u0440\u044f 2012 \u0433. \u2013 \u0421\u0430\u043d\u043a\u0442-\u041f\u0435\u0442\u0435\u0440\u0431\u0443\u0440\u0433: \u0418\u0412\u0421 \u0420\u0410\u041d, 2012. \u2013 82 \u0441.<br \/>\n10. \u041d\u043e\u0432\u044b\u0435 \u043c\u0435\u0442\u043e\u0434\u044b \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u0438\u044f \u0438 \u0438\u0441\u0441\u043b\u0435\u0434\u043e\u0432\u0430\u043d\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041a.: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1978. \u2013 204 \u0441.<br \/>\n11. Jan H. Smith and Gary W. Pace. \/\/ J. Chem. Tech. Biotechnol. &#8211; 1982 \u2013 32, \u2116 1. &#8211; P. 119\u2013129.<br \/>\n12. \u0428\u043a\u043b\u044f\u0435\u0432 \u0410.\u0410., \u0410\u043d\u0443\u0444\u0440\u0438\u0435\u043d\u043a\u043e \u0412.\u0424., \u041e\u0433\u043e\u0440\u043e\u0434\u043d\u0438\u043a\u043e\u0432 \u0412.\u0414. \/\/ \u0416\u0443\u0440\u043d. \u0441\u0442\u0440\u0443\u043a\u0442. \u0445\u0438\u043c\u0438\u0438. -1973. \u2013 14, \u2116 6. &#8211; \u0421. 994-1002.<br \/>\n13. \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u0413\u0443\u0431\u0438\u043d\u0430 \u0410.\u0412., \u041a\u043b\u0435\u043f\u043a\u043e \u0412.\u0412. \u0442\u0430 \u0456\u043d. \/\/ \u041c\u0435\u0436\u0432\u0443\u0437. \u0441\u0431. \u0424\u0438\u0437\u0438\u043a\u043e-\u0445\u0438\u043c\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 2010. \u2013 \u0412\u044b\u043f. 16. \u2013 \u0421. 204-209.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.02.151 The influence of copper ion on thermooxidative destruction characteristics of polyglucaneurethane based on xanthan and caprolactame blocked polyisocyanate \u00a0N.\u00a0Kozak, K. Didenko, H. Nesterenko, B. Klepko &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2015, 37, no. 2: 151-156. &nbsp; Section: Structure and properties. &nbsp; Language: [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1880"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1880"}],"version-history":[{"count":4,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1880\/revisions"}],"predecessor-version":[{"id":2220,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1880\/revisions\/2220"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1880"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}