{"id":1883,"date":"2018-01-10T16:20:52","date_gmt":"2018-01-10T13:20:52","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1883"},"modified":"2018-02-14T17:52:27","modified_gmt":"2018-02-14T14:52:27","slug":"2015-2-7","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-2-7\/","title":{"rendered":"2015 (2) 7"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.02.157\">https:\/\/doi.org\/10.15407\/polymerj.37.02.157<\/a><\/p>\n<p><strong>Electrical and mechanical properties of the systems based on the\u00a0cross-linked polyurethanes modified with multiwalled carbon nanotubes<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>Z.O. Gagolkina<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, E.V. Lobko<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Y.V. Yakovlev<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, E.A. Lysenkov<\/em><\/strong><strong><em>2<\/em><\/strong><strong><em>, V.V. Klepko<\/em><\/strong><strong><em>1<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine. E-mail: GagolkZoya@i.ua<\/p>\n<p>2Mykolayiv National University named after V.O. Sukhomlynskiy<\/p>\n<p>24, Nikolska str., Mykolayiv, 54030, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 2: 157-161.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Electrical conductivity, tensile strenght and elongation at break of the composites on the base of cross-linked polyurethanes with multiwalled carbon nanotubes were investigated depending on the concentration of fillers. It was shown at the filler content of 0,0034\u00a0vol. the electrical conductivity was increased from 10<\/em><em>-10<\/em><em>\u00a0(for polyurethane matrix) to 10<\/em><em>-6<\/em><em>\u00a0S\/cm (with filler content of 0,0052\u00a0vol.).This effect caused of electrical percolation treshold. It was shown that the introduction of carbon nanotubes leads to growing of tensile strength and decreasing of elongation at break of polyurethane composites. In particular, the increasing of tensile strength passes through the maximum with filler content 0,0042\u00a0vol.. And at this point the value of tensile strenght is equal to 14,3 MPa (the tensile strength for original polyurethane matrix is equal to 4,3\u00a0MPa). In contrast, the elongation at break decreases with increasing of filler concentration (from 837\u00a0% for original polyurethane to 423 % at the filler content is equal 0,0047\u00a0vol.) that causes by reinforcing effect of carbon nanotubes in polyurethane matrix.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords:<\/strong> polyurethanes, carbon nanotubes, electrical conductivity, tensile strength, elongation at break.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430 <\/strong><\/p>\n<p>1. Romero D.B., Carrard M., de Heer W.A., Zuppiroli L. \/\/ AdV. Mater. &#8211; 1996. &#8211; \u2116 4. &#8211; P. 899-902.<br \/>\n2. Curran S.A., Ajayan P.M., Blau W.J., Carroll D.L., Coleman J.N., Dalton A.B., Davey A.P., Drury A., McCarthy B., Maier S., Strevens A.A. \/\/ A. AdV. Mater. \u2013 1998. \u2013 10, \u2116 11. \u2013 P. 1091-1098.<br \/>\n4. Calvert P., Min Xu, Tao Zhang, Bing Gu, Jieli Wu, Qun C. \/\/ Nature.- 1999. &#8211; 45, \u2116 3. &#8211; P. 210-217.<br \/>\n5. Qian D., Dickey E.C., Andrews R, Rantell T. \/\/ Applied Physics Lett. \u2013 2000. \u2013 76. &#8211; P. 2868-2879.<br \/>\n6. Jingrong W., Haiping X., Dandan Y., Yihua Wu. \/\/ Fibers and Polymers. &#8211; 2013. \u2013 14, \u2116.4. &#8211; P. 571-577.<br \/>\n7. Zunfeng L., Gang B., Yi H., Yanfeng M., Feng D., Feifei L., Tianying G., Yongsheng C. \/\/ Carbon. \u2013 2007. \u2013 45. &#8211; P. 821 \u2013 827.<br \/>\n8. Zhang R., Dowden A., Deng H., Baxendale M., Peijs T. \/\/ Composites Sci. and Technology. &#8211; 2009. \u2013 69. &#8211; P. 1499 \u2013 1504.<br \/>\n9. Wang J., Xu H., Yang D., Wu Y. \/\/ Composites Fibers and Polymers. \u2013 2013. \u2013 14, \u2116 4. &#8211; P. 571 &#8211; 577.<br \/>\n10. Shuzhong Guo, Chao Zhang, Weizhi Wang, Tian- ci Liu, Wuiwui Chauhari Tjiu, Chaobin He, Wei-De Zhang. \/\/ Polymers &amp; Polymar Composites. \u2013 2008. \u2013 16, \u2116 8. &#8211; P. 423 &#8211; 430.<br \/>\n11. Chen W., Tao X., Liu Y. \/\/ Composites Sci. and Technology. &#8211; 2006. \u2013 \u2116 66. &#8211; P. 3029 \u2013 3034.<br \/>\n12. Koerner H., Liu W., Max A., Mirau P., Dowty H., Richard V. \/\/ Polymer \u2013 2005. &#8211; \u2116 46. &#8211; P. 4405 \u2013 4420.<br \/>\n13. Kovacs J., Velagala B., Schulte K., Bauhofer W. \/\/ Compos. Sci. Technol. \u2013 2007. &#8211; \u2116 67. &#8211; P. 922 &#8211; 931.<br \/>\n14. Kirkpatrick S. Percolation and conduction \/\/ Reviews of Modern Physics. \u2013 1973. \u2013 45, No. 4. \u2013 P. 574.<br \/>\n15. \u0413\u041e\u0421\u0422 14236-81 \u041f\u043b\u0435\u043d\u043a\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0435. \u041c\u0435\u0442\u043e\u0434 \u0438\u0441\u043f\u044b\u0442\u0430\u043d\u0438\u044f \u043d\u0430 \u0440\u0430\u0441\u0442\u044f\u0436\u0435\u043d\u0438\u0435. &#8211; \u041c.: \u0413\u043e\u0441. \u043a\u043e\u043c. \u043f\u043e \u0441\u0442\u0430\u043d\u0434\u0430\u0440\u0442\u0430\u043c, 1981. &#8211; 9 \u0441.<br \/>\n16. Stauffer D., Aharony A. Introduction to percolation theory. \u2013 London: Taylor &amp; Francis, 2003.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.02.157 Electrical and mechanical properties of the systems based on the\u00a0cross-linked polyurethanes modified with multiwalled carbon nanotubes \u00a0 Z.O. Gagolkina1, E.V. Lobko1, Y.V. Yakovlev1, E.A. Lysenkov2, V.V. Klepko1 &nbsp; 1Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine. E-mail: GagolkZoya@i.ua 2Mykolayiv National University named after V.O. Sukhomlynskiy 24, Nikolska str., Mykolayiv, [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1883"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1883"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1883\/revisions"}],"predecessor-version":[{"id":2221,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1883\/revisions\/2221"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1883"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}