{"id":1892,"date":"2018-01-10T16:28:12","date_gmt":"2018-01-10T13:28:12","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1892"},"modified":"2018-02-14T17:57:10","modified_gmt":"2018-02-14T14:57:10","slug":"2015-2-10","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-2-10\/","title":{"rendered":"2015 (2) 10"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.02.174\">https:\/\/doi.org\/10.15407\/polymerj.37.02.174<\/a><\/p>\n<p><strong>The influence of the phenalenone dyes on the kinetics of the polyurethanes formation with different nature of the diisocyanate unit<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>L.F. Kosyanchuk, M.S. Stratilat, N.V. Kozak, T.T. Todosiichuk<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 2: 174-178.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Synthesis polymers.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Russian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The influence of phenalenone dyes containing different functional groups on the kinetics of polyurethane matrices formation was studied. The polyurethanes differ in nature of diisocyanate components (aromatic and aliphatic). It was shown that their introduction mainly leads to slower the reaction of urethane formation. The observed changes are due to: the spatial structure of the dye molecules, their ability to chemical bonding with formed polyurethane; in the case of an aromatic diisocyanate component with the nature of <\/em><em>p<\/em><em>&#8211;<\/em><em>p<\/em><em>&#8211; interaction between its aromatic rings and dye fused rings. Dyes substituents, which are not located in the plane of a condensed ring, cause large steric hindrance, which slows the reaction of urethane formation. The chemical bonding of the dye molecules with a polyurethane matrix differently affect the reaction.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords<\/strong>: polyurethane, phenalenone dyes, the reaction rate constant, electron spectroscopy.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0438\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Bezrodnyi V.I., Negryiko A.M., Klishevich G.V., Strati-lat M.S., Kosyanchuk L.F., Todosiichuk T.T. \/\/ J. Polym. Reserch. \u2013 2013. \u2013 20, N 8. \u2013 \u0410rticle:246. \u2013 \u0420. 1-8.<br \/>\n2. \u0413\u0443\u043d\u0434\u0435\u0440 \u041e.\u0410., \u0422\u0438\u0446\u043a\u0430\u044f \u0412.\u0414., \u041c\u0430\u043b\u0438\u043d\u043e\u0432\u0441\u043a\u0430\u044f \u0421.\u0410. \u0438 \u0434\u0440. \/\/ \u0421\u0431\u043e\u0440\u043d\u0438\u043a \u043d\u0430\u0443\u0447\u043d\u044b\u0445 \u0442\u0440\u0443\u0434\u043e\u0432 \u00ab\u0421\u0446\u0438\u043d\u0442\u0438\u043b\u043b\u044f\u0446\u0438\u043e\u043d\u043d\u044b\u0435 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b \u0438 \u043e\u0441\u043e\u0431\u043e \u0447\u0438\u0441\u0442\u044b\u0435 \u0432\u0435\u0449\u0435\u0441\u0442\u0432\u0430\u00bb. &#8211; \u0425\u0430\u0440\u044c\u043a\u043e\u0432: \u0412\u041d\u0418\u0418 \u043c\u043e\u043d\u043e\u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u043e\u0432. \u2013 1986. \u2013 \u2116 16. \u2013 \u0421. 79-98.<br \/>\n3. \u041f\u0443\u0437\u0438\u043d \u042e.\u0418., \u0415\u0433\u043e\u0440\u043e\u0432 \u0410.\u0415., \u0425\u0430\u0442\u0447\u0435\u043d\u043a\u043e \u0415.\u0410., \u041a\u0438\u0440\u0438\u043b\u043b\u043e\u0432 \u0413.\u0410., \u041a\u0443\u0434\u0430\u0448\u0435\u0432 \u0420.\u0425., \u041a\u0440\u0430\u0439\u043a\u0438\u043d \u0412.\u0410. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u2013 2000. \u2013 42, \u2116 9. \u2013 \u0421. 1461-1471.<br \/>\n4. Bojinov V.B., Konstantinova T.N. \/\/ Dye and Pigments. \u2013 1996. \u2013 32, N 3. \u2013 P. 151-157.<br \/>\n5. \u0422\u0438\u0446\u043a\u0430\u044f \u0412.\u0414., \u041a\u043e\u0441\u0442\u0435\u043d\u043a\u043e \u0418.\u041d., \u0421\u043a\u0440\u0438\u043f\u043a\u0438\u043d\u0430 \u0412.\u0422. \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. \u2013 1996. \u2013 62, \u2116 3\/4. \u2013 \u0421. 124-128.<br \/>\n6. \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a \u041b.\u0424., \u0421\u0442\u0440\u0430\u0442\u0438\u043b\u0430\u0442 \u041c.\u0421., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422. \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. &#8211; 2015. &#8211; 81, \u2116 1. &#8211; \u0421. 56-61.<br \/>\n7. Stagg H.E. \/\/ Analyst. \u2013 1946. \u2013 71, N 849. \u2013 \u0420. 557-559.<br \/>\n8. \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a \u041b.\u0424., \u0422\u0440\u0430\u0447\u0435\u0432\u0441\u043a\u0438\u0439 \u0412.\u0412., \u0421\u0442\u0440\u0430\u0442\u0438\u043b\u0430\u0442 \u041c.\u0421., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u041c\u0435\u043d\u0436\u0435\u0440\u0435\u0441 \u0413.\u042f. \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. \u2013 2014. \u2013 80, \u2116 7-8. \u2013 \u0421. 124-128<br \/>\n9. \u0421\u0442\u0440\u0430\u0442\u0438\u043b\u0430\u0442 \u041c.\u0421, \u041a\u043e\u0441\u044f\u043d\u0447\u0443\u043a \u041b.\u0424., \u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u041c\u0435\u043d\u0436\u0435\u0440\u0435\u0441 \u0413.\u042f, \u0411\u0435\u0437\u0440\u043e\u0434\u043d\u0430\u044f \u0422.\u0412. \/\/ \u041f\u043e\u043b\u0438\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2014. \u2013 36, \u2116 3. \u2013 \u0421. 245-250<br \/>\n10. Kosyanchuk L.F., Bezrodna T.V., Stratilat M.S., Menzheres G.Ya., Kozak N.V., Todosiichuk T.T. \/\/ J. Polym. Research. \u2013 2014. \u2013 21, N 10. \u2013 \u0410rticle:564. &#8211; \u0420. 1-7.<br \/>\n11. \u041d\u0438\u0437\u0435\u043b\u044c\u0441\u043a\u0438\u0439 \u042e.\u041d., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412, \u041b\u0438\u043f\u0430\u0442\u043e\u0432\u0430 \u0422.\u042d. \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. \u2013 1987. \u2013 53, \u2116 7. \u2013 \u0421. 772-777.<br \/>\n12. Luo R., Gilson H.S.R, Potter M.J., Gilson M.K. \/\/ Biophysical J. \u2013 2001. \u2013 80. \u2013 \u0420. 140\u2013148.<br \/>\n13. \u0420\u0430\u0439\u0442 \u041f., \u041a\u0430\u043c\u043c\u0438\u043d\u0433 \u0424. \u041f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432\u044b\u0435 \u044d\u043b\u0430\u0441\u0442\u043e\u043c\u0435\u0440\u044b. \u2013 \u041b\u0435\u043d\u0438\u043d\u0433\u0440\u0430\u0434: \u0425\u0438\u043c\u0438\u044f, 1973. \u2013 304 \u0441.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.02.174 The influence of the phenalenone dyes on the kinetics of the polyurethanes formation with different nature of the diisocyanate unit \u00a0 L.F. Kosyanchuk, M.S. Stratilat, N.V. Kozak, T.T. Todosiichuk &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2015, 37, no. 2: 174-178. &nbsp; Section: Synthesis [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1892"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1892"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1892\/revisions"}],"predecessor-version":[{"id":2224,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1892\/revisions\/2224"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1892"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}