{"id":1932,"date":"2018-01-10T17:08:14","date_gmt":"2018-01-10T14:08:14","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1932"},"modified":"2018-02-14T17:22:54","modified_gmt":"2018-02-14T14:22:54","slug":"2015-3-7","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-3-7\/","title":{"rendered":"2015 (3) 7"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.03.263\">https:\/\/doi.org\/10.15407\/polymerj.37.03.263<\/a><\/p>\n<p><strong>The influence of pectin based metal-complexes on degradation of polyethylene<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>T.V. Dmitrieva, S.M. Kobylinsky, V.V. Boyko, S.V. Riabov, V.I. Bortnitskiy, S.K. Krymovska, G.F. Nevmerzhitska, O.M. Komljakova<\/em><\/strong><\/p>\n<p><em>\u00a0<\/em><\/p>\n<p>Institute of Macromolecular Chemistry the NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 3: 263-268.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The complexes based on pectin and metal ions such as zinc, cobalt and manganese have been prepared. Their effect on mechanic and thermal properties of polyethylene composites and the change of these characteristics under the effect of UV- radiation and soil microorganisms are investigated. The structural changes in the composites, which occur under the influence of metal-complex additives have been established taking into account the volatile components\u2019 temperatures of maximum emission and their intensities after exposure to the UV-radiation and soil. It is ascertained that the most effective additives and their concentration increase the degradation of polyethylene. <\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords: <\/strong>metal-complex, pectin, polyethylene, degradation.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u041f\u0430\u0442. \u2116 33258 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a7 \u042108\u041a 9\/00, \u042108J 3\/20, C08L 23\/00. \u0411\u0456\u043e\u0434\u0435\u0433\u0440\u0430\u0434\u0430\u0431\u0435\u043b\u044c\u043d\u0430 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0430 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u044f. \/ \u042e.\u042e.\u041a\u0435\u0440\u0447\u0430, \u0412.\u0412.\u0411\u043e\u0439\u043a\u043e, \u0421.\u0412. \u0420\u044f\u0431\u043e\u0432, \u0422.\u0412. \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430, \u041b.\u0412. \u041a\u043e\u0431\u0440\u0456\u043d\u0430. &#8211; \u041e\u043f\u0443\u0431\u043b. 10.06.2008. \u2013 \u0411\u044e\u043b.11.<br \/>\n2. \u041f\u0430\u0442. \u2116 70854. \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a7 \u042108\u041a 3\/10, \u042108\u041a 3\/18. \u0414\u0435\u0433\u0440\u0430\u0434\u0430\u0431\u0435\u043b\u044c\u043d\u0430 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0430 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u044f \/ \u0422.\u0412. \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430, \u0421.\u0412. \u0420\u044f\u0431\u043e\u0432, \u0412.\u0412. \u0411\u043e\u0439\u043a\u043e, \u042e.\u042e. \u041a\u0435\u0440\u0447\u0430 \u0442\u0430 \u0456\u043d. &#8211; \u041e\u043f\u0443\u0431\u043b. 25.06.2012. \u2013 \u0411\u044e\u043b.12.<br \/>\n3. \u0428\u0442\u043e\u043c\u043f\u0435\u043b\u044c \u0412.\u0406., \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430 \u0422.\u0412., \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u041a\u0440\u0438\u043c\u043e\u0432\u0441\u044c\u043a\u0430 \u0421.\u041a., \u041d\u0435\u0432\u043c\u0435\u0440\u0436\u0438\u0446\u044c\u043a\u0430 \u0413.\u0424., \u041a\u043e\u0431\u0440\u0456\u043d\u0430 \u041b.\u0412., \u042f\u043d\u043e\u0432\u0430 \u041a.\u0412. \u0421\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u0456 \u043e\u0441\u043e\u0431\u043b\u0438\u0432\u043e\u0441\u0442\u0456 \u043f\u043e\u043b\u0456\u0435\u0442\u0438\u043b\u0435\u043d\u0443 \u0432\u0438\u0441\u043e\u043a\u043e\u0433\u043e \u0442\u0438\u0441\u043a\u0443 \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u043a\u043e\u043c\u043f\u043b\u0435\u043a\u0441\u043e\u043d\u0430\u0442\u0430\u043c\u0438 \u0442\u0430 \u0430\u0446\u0435\u0442\u0430\u0442\u0430\u043c\u0438 \u043c\u0435\u0442\u0430\u043b\u0456\u0432 \/\/ \u0423\u043a\u0440. \u0445\u0456\u043c. \u0436\u0443\u0440\u043d. &#8211; 2013. &#8211; 79, \u2116 1. &#8211; \u0421. 56\u201361.<br \/>\n4. \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430 \u0422.\u0412., \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u0411\u043e\u0440\u0442\u043d\u0438\u0446\u044c-\u043a\u0438\u0439 \u0412.\u0406., \u0413\u043e\u043d\u0447\u0430\u0440 \u041c.\u0412., \u041f\u0440\u043e\u043a\u043e\u043f\u0456\u0432 \u0422.\u041c. \u041e\u0441\u043e\u0431\u043b\u0438\u0432\u043e\u0441\u0442\u0456 \u0432\u043f\u043b\u0438\u0432\u0443 \u043c\u0456\u043a\u0440\u043e\u043e\u0440\u0433\u0430\u043d\u0456\u0437\u043c\u0456\u0432 \u043d\u0430 \u043f\u043e\u043b\u0456\u0435\u0442\u0438\u043b\u0435\u043d, \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u0438\u0439 \u0431\u0456\u043e\u0434\u0435\u0433\u0440\u0430\u0434\u0430\u0431\u0435\u043b\u044c\u043d\u0438\u043c\u0438 \u0434\u043e\u0431\u0430\u0432\u043a\u0430\u043c\u0438 \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. &#8211; 2013.- \u2116 6. &#8211; \u0421. 122\u2013125.<br \/>\n5. \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430 \u0422.\u0412., \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u0411\u043e\u0440\u0442\u043d\u0438\u0446\u044c-\u043a\u0438\u0439 \u0412.\u0406., \u041a\u0440\u0438\u043c\u043e\u0432\u0441\u044c\u043a\u0430 \u0421.\u041a., \u041d\u0435\u0432\u043c\u0435\u0440\u0436\u0438\u0446\u044c\u043a\u0430 \u0413.\u0424., \u0413\u043e\u043d-\u0447\u0430\u0440 \u041c.\u0412., \u041f\u0440\u043e\u043a\u043e\u043f\u0456\u0432 \u0422.\u041c. \u0412\u043f\u043b\u0438\u0432 \u0434\u0440\u0456\u0436\u0434\u0436\u0456\u0432 \u2013 \u0430\u0441\u043a\u043e\u043c\u0456\u0446\u0435\u0442\u0456\u0432 Yarrowia lipolytica \u043d\u0430 \u043f\u043e\u043b\u0456\u043e\u043b\u0435\u0444\u0456\u043d\u0438, \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u0456 \u0434\u0435\u0433\u0440\u0430\u0434\u0430\u0431\u0435\u043b\u044c\u043d\u0438\u043c\u0438 \u0434\u043e\u0431\u0430\u0432\u043a\u0430\u043c\u0438 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. &#8211; 2013. &#8211; 35, \u2116 2. &#8211; \u0421. 140-144.<br \/>\n6. \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u043a\u0438\u0439 \u0420.\u0410., \u041b\u0443\u043a\u0430\u0448\u0435\u043d\u043a\u043e \u0418.\u041c., \u0411\u0440\u043e\u0434\u0441\u043a\u0438\u0439 \u0415.\u0421. \u041f\u0438\u0440\u043e\u043b\u0438\u0442\u0438\u0447\u0435\u0441\u043a\u0430\u044f \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u044f \u0432\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443-\u043b\u044f\u0440\u043d\u044b\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1980. &#8211; 280 \u0441.<br \/>\n7. \u0411\u0435\u0439\u043d\u043e\u043d \u0414\u0436. \u041c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u044f \u0438 \u0435\u0435 \u043f\u0440\u0438\u043c\u0435\u043d\u0435\u043d\u0438\u0435 \u0432 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u043e\u0439 \u0445\u0438\u043c\u0438\u0438. \/ \u041f\u0435\u0440. \u0441 \u0430\u043d\u0433\u043b.- \u041c.:\u041c\u0438\u0440, 1964. &#8211; 701 \u0441.<br \/>\n8. \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u041a\u043e\u0431\u0440\u0438\u043d\u0430 \u041b.\u0412., \u0414\u043c\u0438\u0442\u0440\u0438\u0435\u0432\u0430 \u0422.\u0412., \u0428\u0442\u043e\u043c\u043f\u0435\u043b\u044c \u0412.\u0418., \u0413\u0430\u0439\u0434\u0443\u043a \u0420.\u041b., \u041a\u0435\u0440\u0447\u0430 \u042e.\u042e. \u041f\u0440\u043e\u0446\u0435\u0441\u0441\u044b \u0431\u0438\u043e\u0434\u0435\u0433\u0440\u0430\u0434\u0430\u0446\u0438\u0438 \u0441\u0435\u0433\u043c\u0435\u043d\u0442\u0438\u0440\u043e\u0432\u0430\u043d\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432 \/\/ \u0423\u043a\u0440. \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. &#8211; 2007. &#8211; 73, \u2116 7. &#8211; \u0421. 51-60.<br \/>\n9. \u041a\u0430\u0442\u0430\u043b\u043e\u0433 \u0441\u043e\u043a\u0440\u0430\u0449\u0435\u043d\u043d\u044b\u0445 \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u0432.- \u041d\u043e\u0432\u043e\u0441\u0438\u0431\u0438\u0440\u0441\u043a: \u041d\u0430\u0443\u043a\u0430.- 1981.- 187 \u0441.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.03.263 The influence of pectin based metal-complexes on degradation of polyethylene \u00a0 T.V. Dmitrieva, S.M. Kobylinsky, V.V. Boyko, S.V. Riabov, V.I. Bortnitskiy, S.K. Krymovska, G.F. Nevmerzhitska, O.M. Komljakova \u00a0 Institute of Macromolecular Chemistry the NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2015, 37, no. 3: 263-268. &nbsp; Section: Structure and [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1932"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1932"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1932\/revisions"}],"predecessor-version":[{"id":2205,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1932\/revisions\/2205"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1932"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}