{"id":1939,"date":"2018-01-10T17:44:10","date_gmt":"2018-01-10T14:44:10","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1939"},"modified":"2018-02-14T17:26:45","modified_gmt":"2018-02-14T14:26:45","slug":"2015-3-9","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-3-9\/","title":{"rendered":"2015 (3) 9"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.03.275\">https:\/\/doi.org\/10.15407\/polymerj.37.03.275<\/a><\/p>\n<p><strong>Composites on the base of epoxy polymer metal oxides and polyaniline, cured in constant physical fields: structure, density and <\/strong><strong>\u0430\u0441<\/strong><strong>-coductivity<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong><em>V.<\/em><\/strong><strong><em>\u041e<\/em><\/strong><strong><em>. Vilensky<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Y.V. Bardadym<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Y.P. Gomza<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Y.Y. Kercha<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, <\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>.P. Pozniy<\/em><\/strong><strong><em>2<\/em><\/strong><strong><em>, <\/em><\/strong><strong><em>\u041c<\/em><\/strong><strong><em>.<\/em><\/strong><strong><em>\u041c<\/em><\/strong><strong><em>.Zagorny<\/em><\/strong><strong><em>2<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>2\u00a0Institute\u00a0 Problem of Material Science named I. M. Francevich NAS of Ukraine<\/p>\n<p>3, Krjijanovsky str., Kyiv, 03142, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 3: 275-286.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>t<\/em><em>he mesocomposites density of content <\/em><em>\u0415\u041f<\/em><em> \u2013 3% MeO, <\/em><em>\u0415\u041f<\/em><em> \u2013 3% MeO and <\/em><em>\u0415\u041f<\/em><em> \u2013 3% (Me<\/em><em>\u0406<\/em><em>O<\/em> <em>+ Me<\/em><em>\u0406\u0406<\/em><em>O) in dependence of conditions creation had been carried out. Selective influence of constant magnetic fields (CMF) or constant electrical fields (CEF) upon D<\/em><em>MC <\/em><em>determined by difference in interaction between systems EP \u00ab MeO and MeO\u00a0 EP \u00ab PAn and physical fields was established. Correlation .between density MC and metal filer Me<\/em><em>i<\/em><em>\u00a0also was established. Analysis of <\/em><em>Dr<\/em><em> changes in array of specimens MC had shown the effective using of CMF upon forming polymer matrix density. \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Use of software products XPowder and WinPLOTER fulfilled autoindexing of orthorhombic cell of Cr<\/em><em>2<\/em><em>O<\/em><em>3<\/em><em>\u00a0and trial-and-error procedure was defined parameters of new crystal structure of Cr<\/em><em>2<\/em><em>O<\/em><em>3<\/em><em>: a = 5,58 A; b = 4,82 A; c = 5,98 A; a = b = g = 90\u00b0; V = 160,84 A<\/em><em>3<\/em><em>, Z = 4, which formed in mesocomposites by constitution EP \u2013 3%(Cr2O3 + PAn)cef. Using of Scherrer\u2019 expression with k=1 were calculated dimensions of crystallites for powder Cr<\/em><em>2<\/em><em>O<\/em><em>3<\/em><em>\u00a0and as filler of MC for different constitution and conditions of cured. Was established, in powder content are present crystallites of three dimensions. Introduction of Cr<\/em><em>2<\/em><em>O<\/em><em>3<\/em><em>\u00a0into thermoset lead to grow of it dimensions, decrease theirs dispersion and partial recrystallization. Involving of CMF\/CEF to cured of MC by constitution EP \u2013 3% Cr<\/em><em>2<\/em><em>O<\/em><em>3<\/em><em>\u00a0promote formation of dominant dimension of crystallite: 10,2 \u2013 13,2 nm. Ac-conductivity of MC in dependence of w alternating current had studied. For all MC are typical sharp increase of conductivity up 3 degree in frequency range 10<\/em><em>2 <\/em><em>\u2013 10<\/em><em>5<\/em><em>Hz and steadily satiation of <\/em><em>s<\/em><em>ac <\/em><em>in high frequency range. These confirm that first part is connecting with manifestation of hopping electron conductivity in dielectric matrix what inherent to ordered and disordered systems. On the results of studies make conclusion about changing of mechanisms\u2019 charge transfer from hopping to zonal.\u00a0 <\/em><\/p>\n<p>&nbsp;<\/p>\n<p><strong>Key words:<\/strong> constant magnetic fields, constant electric fields, crystalline structure, orthorhombic cell, ac-conductivity.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0414\u0435\u043c\u0447\u0435\u043d\u043a\u043e \u0412.\u041b. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440\u043d. \u0436\u0443\u0440\u043d. \u2013 2008. \u2013 30, \u2116 2. \u2013 \u0421. 133 \u2013 140.<br \/>\n2. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0414\u0435\u043c\u0447\u0435\u043d\u043a\u043e \u0412.\u041b. \/\/ \u041d\u0430\u0443\u043a\u043e\u0432\u0456 \u0432\u0456\u0441\u0442\u0456. \u2013 2009. \u2013 \u21161. \u2013 \u0421.227 \u2013 232.<br \/>\n3. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0414\u0435\u043c\u0447\u0435\u043d\u043a\u043e \u0412.\u041b. \/\/ \u0416\u0443\u0440\u043d. \u0444\u0456\u0437. \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u044c. \u2013 2010. \u2013 14, \u2116 1. \u2013 \u0421. 1401.<br \/>\n4. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0411\u0430\u0440\u0434\u0430\u0434\u0438\u043c \u042e. \u0412., \u042e\u0440\u0436\u0435\u043d\u043a\u043e \u041c.\u0412., \u0417\u0430\u0433\u043e\u0440\u043d\u0438\u0439 \u041c.\u041c. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440.\u0436\u0443\u0440\u043d. \u2013 2012, \u2013 34, \u21164. \u2013 \u0421. 382 \u2013 386.<br \/>\n5. \u0411\u0430\u0440\u0434\u0430\u0434\u0438\u043c \u042e.\u0412., \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0413\u043e\u043c\u0437\u0430 \u042e.\u041f., \u041a\u0435\u0440-\u0447\u0430 \u042e.\u042e. \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2014. \u2013 \u2116 1. \u2013 \u0421. 63 \u2013 71.<br \/>\n6. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u041a\u0435\u0440\u0447\u0430 \u042e.\u042e., \u0413\u043e\u043d\u0447\u0430\u0440\u0435\u043d\u043a\u043e \u041b.\u0410., \u0414\u0435\u043c\u0447\u0435\u043d\u043a\u043e \u0412.\u041b. \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2012. \u2013 \u2116 4. \u2013 \u0421. 128 \u2013 137.<br \/>\n7. \u0412\u0438\u043b\u0435\u043d\u0441\u043a\u0438\u0439 \u0412.\u0410. \u041f\u043e\u0441\u0442\u043e\u044f\u043d\u043d\u044b\u0435 \u043c\u0430\u0433\u043d\u0438\u0442\u043d\u044b\u0435 \u0438 \u044d\u043b\u0435\u043a\u0442\u0440\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043f\u043e\u043b\u044f \u043a\u0430\u043a \u0444\u0430\u043a\u0442\u043e\u0440\u044b \u0432\u043b\u0438\u044f\u043d\u0438\u044f \u043d\u0430 \u0444\u0430\u0437\u043e\u0432\u044b\u0435 \u043f\u0440\u043e\u0446\u0435\u0441\u0441\u044b \u0432 \u0433\u0435\u0442\u0435\u0440\u043e\u0433\u0435\u043d\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u0441\u0438\u0441\u0442\u0435\u043c\u0430\u0445 \/ \u0424\u0430\u0437\u043e\u0432\u044b\u0435 \u043f\u0440\u043e\u0446\u0435\u0441\u0441\u044b \u0432 \u0433\u0435\u0442\u0435\u0440\u043e\u0433\u0435\u043d\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u0441\u0438\u0441\u0442\u0435\u043c\u0430\u0445. \u2013 \u041a\u0438\u0435\u0432: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 2012. \u2013 157. \u2013 186 \u0441.<br \/>\n8. \u041f\u0430\u0442. 56201 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041a\u04127 \u041f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0430 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u044f \u0434\u043b\u044f \u0437\u0430\u0445\u0438\u0441\u0442\u0443 \u0432\u0456\u0434 \u0440\u0435\u043d\u0442\u0433\u0435\u043d\u0456\u0432\u0441\u044c\u043a\u043e\u0433\u043e \u0432\u0438\u043f\u0440\u043e\u043c\u0456\u043d\u044e\u0432\u0430\u043d\u043d\u044f \/ \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0413\u043e\u043d\u0447\u0430\u0440\u0435\u043d\u043a\u043e \u041b.\u0410., \u041a\u0435\u0440\u0447\u0430 \u042e.\u042e., \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0430 \u041b.\u041c. \u2013 \u041e\u043f\u0443\u0431\u043b. 2003. \u2013 \u0411\u044e\u043b.2.<br \/>\n9. \u0411\u0430\u0440\u0434\u0430\u0434\u0438\u043c \u042e.\u0412., \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e., \u0411\u043e\u0439\u043a\u043e \u0412.\u0412., \u0414\u043c\u0438\u0442\u0440\u0456\u0454\u0432\u0430 \u0422.\u0412., \u0411\u043e\u0440\u0442\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u0412.\u0406. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2014. \u2013 34. \u2116 2. \u2013 \u0421. 146 \u2013 153.<br \/>\n10. \u041f\u0430\u0442. 61\u2013266435 \u042f\u043f\u043e\u043d\u0438\u044f, \u041c\u041a\u04185 \u0421 08 G 73\/00, H 01 L 29\/28. \u0421\u043f\u043e\u0441\u043e\u0431 \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u0438\u044f \u0442\u043e\u043d\u043a\u0438\u0445 \u043f\u043b\u0435\u043d\u0435\u043a \u0442\u043e\u043a\u043e\u043f\u0440\u043e\u0432\u043e\u0434\u044f\u0449\u0438\u0445 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \/ \u0422\u0430\u043c\u0443\u0440\u0430 \u0421\u0451\u0445\u044d\u0439. \u2013 \u041e\u043f\u0443\u0431\u043b. 26.11.86.<br \/>\n11. \u041b\u0438\u043f\u0430\u0442\u043e\u0432 \u042e.\u0421., \u0428\u0438\u043b\u043e\u0432 \u0412.\u0412., \u0413\u043e\u043c\u0437\u0430 \u042e.\u041f. \u0420\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0433\u0440\u0430\u0444\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u043c\u0435\u0442\u043e\u0434\u044b \u0438\u0437\u0443\u0447\u0435\u043d\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u0441\u0438\u0441\u0442\u0435\u043c. \u2013 \u041a\u0438\u0435\u0432: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1982. \u2013 296 \u0441.<br \/>\n12. \u041c\u0438\u0440\u043a\u0438\u043d \u041b.\u0418. \u0421\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u0438\u043a \u043f\u043e \u0440\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u043c\u0443 \u0430\u043d\u0430\u043b\u0438\u0437\u0443 \u043f\u043e\u043b\u0438\u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u043e\u0432. \u2013 \u041c.: \u0413\u043e\u0441. \u0438\u0437\u0434-\u0432\u043e \u0444\u0438\u0437.-\u043c\u0430\u0442. \u043d\u0430\u0443\u043a, 1961. \u2013 863 \u0441.<br \/>\n13. \u0412\u0456\u043b\u0435\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041e. \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 1996. 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Roldunghin V.I., Vysotskii V.V. \/\/ Progress in Organic Coatings. \u2013 2000. \u2013 39. \u2013 P. 81 \u2013 100.<br \/>\n21. Dyre J.C., Schr\u0448der T.B \/\/ Reviews of Modern Physics. \u2013 2000. \u2013 72. \u2013 P. 873 \u2013 892.<br \/>\n22. Hippel A.R. Dielectrics and Waves. \u2013 Boston: Artech, 1995. \u2013 300 \u0440.<br \/>\n23. Kremer F., Schonhals A. Broadband dielectric spectroscopy. \u2013 Berlin: Springer, 2003. \u2013 729p.<br \/>\n24. Schroder T. B., Dyre Jeppe C. \/\/ Physical Review Letters. \u2013 2008. \u2013 4. \u2013 p. 101.<br \/>\n25. Cotton F.A., Wilkinson G. Advanced Inorganic Chemistry. \u2013 New York: Wiley Interscience, 1980. \u2013 1401 p.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.03.275 Composites on the base of epoxy polymer metal oxides and polyaniline, cured in constant physical fields: structure, density and \u0430\u0441-coductivity &nbsp; V.\u041e. Vilensky1, Y.V. Bardadym1, Y.P. Gomza1, Y.Y. Kercha1, \u0410.P. Pozniy2, \u041c.\u041c.Zagorny2 &nbsp; 1Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine 2\u00a0Institute\u00a0 Problem of Material Science named I. M. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1939"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1939"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1939\/revisions"}],"predecessor-version":[{"id":2207,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1939\/revisions\/2207"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1939"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}