{"id":1957,"date":"2018-01-10T17:59:53","date_gmt":"2018-01-10T14:59:53","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1957"},"modified":"2018-02-14T16:56:25","modified_gmt":"2018-02-14T13:56:25","slug":"2015-4-2","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-4-2\/","title":{"rendered":"2015 (4) 2"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.04.341\">https:\/\/doi.org\/10.15407\/polymerj.37.04.341<\/a><\/p>\n<p><strong>The influence of ratio of reagents on the rheokinetics and viscoelastic properties of epoxy resin cured with amine hardener<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong><em>M.G. Tkalich, L.A. Gorbach, V.P. Shumskiy, I.P. Getmanchuk, <\/em><\/strong><strong><em>\u041e<\/em><\/strong><strong><em>.O.Brovko<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48 Kharkivs\u2019ke shose, 02160 Kyiv, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 4: 341-346.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>By using rheokinetic and dynamic mechanical analysis methods the rheokinetic and viscoelastic properties of epoxide based on the epoxy resin ED-20 and amine hardener in different ratios were investigated. The ratios of epoxy resin and hardener 8:1, 10:1, and 12:1were taken. It was found that reaching gel point was the fastest for the most significant content of hardener, whereas with decreasing of content of hardener much more time was needed to reach gel point that also led to the decrease in a density of crosslinks. The increasing of hardener amount was defined to be followed by the increasing of glass temperature. In the ratio only 10:1 the epoxy composition was shown to provide the optimal balance of the technologic, rheokinetic, and physic-mechanical parameters.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words:<\/strong> epoxies, rheokinetic, gel point, viscoelastic properties.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. \u0427\u0435\u0440\u043d\u0438\u043d \u0418.\u0417., \u0421\u043c\u0435\u0445\u043e\u0432 \u0424.\u041c., \u0416\u0435\u0440\u0434\u0435\u0432 \u042e.\u0412. \u042d\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u044b\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u044b \u0438 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u0438. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1982. \u2013 232 \u0441.<br \/>\n2. \u0423\u043e\u0440\u0434 \u0422., \u0411\u0440\u0438\u043d\u043a\u043b\u0438 \u0410., \u0428\u0435\u0440\u0438\u0434\u0430\u043d \u041c., \u041a\u0451\u043d\u0438\u0433 \u041f. \u0412 \u043a\u043d.: \u0410\u0434\u0433\u0435\u0437\u0438\u0432\u044b \u0438 \u0430\u0434\u0433\u0435\u0437\u0438\u043e\u043d\u043d\u044b\u0435 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f.\u2013 \u041c.: \u041c\u0438\u0440, 1988. &#8211; \u0421. 49\u201358.<br \/>\n3. Ehlers J.-E. , Rondan N.G. , Huynh L.K. , Pham H., Marks M., Truong T.N. Theoretical study on mechanisms of the epoxy amine curing reaction \/\/ Macromol. \u2013 2007.- 40, No.12- P.4370-4377<br \/>\n4. \u041e\u043c\u0430\u043b\u044c\u0447\u0435\u043d\u043a\u043e \u0421.\u0418., \u0411\u043e\u043a\u0430\u043b\u043e \u0413.\u0410., \u0417\u0430\u043f\u0443\u043d\u043d\u0430\u044f \u041a.\u0412. \u0412\u043b\u0438\u044f\u043d\u0438\u0435 \u0441\u043e\u043e\u0442\u043d\u043e\u0448\u0435\u043d\u0438\u044f \u0438\u0441\u0445\u043e\u0434\u043d\u044b\u0445 \u0440\u0435\u0430\u0433\u0435\u043d\u0442\u043e\u0432 \u043d\u0430 \u043f\u0440\u043e\u0446\u0435\u0441\u0441 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \u0435\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0433\u043e \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u0430 \u0442\u0440\u0438\u044d\u0442\u0430\u043d\u043e\u043b\u043f\u043c\u0438\u043d\u043e\u0442\u0438\u0442\u0430\u043d\u0430\u0442\u043e\u043c \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b. \u0441\u043e\u0435\u0434.-1978.-20, \u211610. \u2013 \u0421.734-737.<br \/>\n5. \u0417\u0430\u043f\u0443\u043d\u043d\u0430\u044f \u041a.\u0412., \u041b\u0438\u043f\u0430\u0442\u043e\u0432 \u042e.\u0421.,\u0422\u043e\u0434\u043e\u0441\u0438\u0439\u0447\u0443\u043a \u0422.\u0422., \u042f\u0449\u0435\u043d\u043a\u043e \u041b.\u041d., \u041a\u0440\u0438\u0432\u0447\u0435\u043d\u043a\u043e \u0413.\u041d., \u0413\u043e\u0440\u0431\u0430\u0442\u0435\u043d\u043a\u043e \u0410.\u041d. \u0412\u043b\u0438\u044f\u043d\u0438\u0435 \u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0438 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \u044d\u043f\u043e\u043a\u0441\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432\u044b\u0445 \u0430\u0434\u0433\u0435\u0437\u0438\u0432\u043e\u0432 \u043d\u0430 \u043f\u0440\u043e\u0447\u043d\u043e\u0441\u0442\u044c \u043a\u043b\u0435\u0435\u0432\u044b\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439 \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b.- 2006.-\u21169.- \u0421. 16-20.<br \/>\n6. \u0422\u043a\u0430\u043b\u0456\u0447 \u041c.\u0413., \u0413\u043e\u0440\u0431\u0430\u0447 \u041b.\u0410., \u0411\u0440\u043e\u0432\u043a\u043e \u041e.\u041e. \u0412\u043f\u043b\u0438\u0432 \u0444\u0443\u043d\u043a\u0446\u0456\u043e\u043d\u0430\u043b\u0456\u0437\u043e\u0432\u0430\u043d\u0438\u0445 \u0441\u0438\u043b\u0456\u0446\u0456\u0439\u0432\u043c\u0456\u0441\u043d\u0438\u0445 \u043a\u043e\u043c\u043f\u043e\u043d\u0435\u043d\u0442\u0456\u0432 \u043d\u0430 \u043a\u0456\u043d\u0435\u0442\u0438\u043a\u0443 \u0442\u0432\u0435\u0440\u0434\u043d\u0435\u043d\u043d\u044f \u0435\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u043e\u0457 \u0441\u043c\u043e\u043b\u0438 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. &#8211; 2014. -36, \u2116 2. &#8211; \u0421.134-139.<br \/>\n7. \u041c\u0430\u043b\u043a\u0438\u043d \u0410.\u042f., \u041a\u0443\u043b\u0438\u0447\u0438\u0445\u0438\u043d \u0421.\u0413. \u0420\u0435\u043e\u043b\u043e\u0433\u0438\u044f \u0432 \u043f\u0440\u043e\u0446\u0435\u0441\u0441\u0430\u0445 \u043e\u0431\u0440\u0430\u0437\u043e\u0432\u0430\u043d\u0438\u044f \u0438 \u043f\u0440\u0435\u0432\u0440\u0430\u0449\u0435\u043d\u0438\u044f \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. -\u041c.: \u0425\u0438\u043c\u0438\u044f, 1985. &#8211; 285 \u0441.<br \/>\n8. \u041c\u0435\u0436\u0438\u043a\u043e\u0432\u0441\u043a\u0438\u0439 \u0421.\u041c., \u0418\u0440\u0436\u0430\u043a \u0412.\u0418. \u0425\u0438\u043c\u0438\u0447\u0435\u0441\u043a\u0430\u044f \u0444\u0438\u0437\u0438\u043a\u0430 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u043e\u0432.-\u041c.:\u041d\u0430\u0443\u043a\u0430, 2008. &#8211; 269 \u0441.<br \/>\n9. Malkin A.Y., Kulichikhin S.G. Rheokinetics: Rheological Transformation in Synthesis and Reaction of Oligomers and Polymers.-John&amp;Sons, Incorporation, 1998. \u2013 326 \u0440.<br \/>\n10. \u0422\u0430\u0440\u0430\u043d\u0435\u043d\u043a\u043e \u0415.\u0412., \u041a\u0430\u043d\u0434\u044b\u0440\u0438\u043d \u041b.\u0411. \u0420\u0435\u043e\u043b\u043e\u0433\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u0438 \u0440\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0430 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \u043c\u043e\u0434\u0438\u0444\u0438\u0446\u0438\u0440\u043e\u0432\u0430\u043d\u043d\u044b\u0445 \u0442\u0435\u0440\u043c\u043e\u0440\u0435\u0430\u043a\u0442\u0438\u0432\u043d\u044b\u0445 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u043e\u0432 \/\/ \u0412\u0435\u0441\u0442\u043d\u0438\u043a \u041c\u0418\u0422\u0425\u0422. -2008. -3, \u21161. &#8211; \u0421.82-88.<br \/>\n11. \u0416\u0430\u0432\u043e\u0440\u043e\u043d\u043e\u043a \u0415.\u0421., \u0427\u0430\u043b\u044b\u0445 \u0410.\u0415., \u041a\u043e\u043b\u0435\u0441\u043d\u0438\u043a\u043e\u0432\u0430 \u0415.\u0424. \u0412\u043b\u0438\u044f\u043d\u0438\u0435 \u043f\u0440\u0438\u0440\u043e\u0434\u044b \u0438 \u0444\u0443\u043d\u043a\u0446\u0438\u043e\u043d\u0430\u043b\u044c\u043d\u043e\u0441\u0442\u0438 \u044d\u043f\u043e\u043a\u0441\u0438\u0434\u043d\u044b\u0445 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u043e\u0432 \u043d\u0430 \u0440\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u043a\u0443 \u0438\u0445 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b.\u20132013.\u2013\u21164.\u2013 \u0421.16-20.<br \/>\n12. \u041a\u0443\u043b\u0438\u0447\u0438\u0445\u0438\u043d \u0421.\u0413., \u041d\u0435\u0447\u0438\u0442\u0430\u0439\u043b\u043e \u041b.\u0413., \u0413\u0435\u0440\u0430\u0441\u0438\u043c\u043e\u0432 \u0418.\u0413., \u041a\u043e\u0436\u0438\u043d\u0430 \u0412.\u0410., \u0417\u0430\u0439\u0446\u0435\u0432 \u042e.\u0421., \u042f\u0440\u043e\u0432\u0430\u044f \u0415.\u041f. \u0420\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0430 \u0433\u0435\u043b\u0435\u043e\u0431\u0440\u0430\u0437\u043e\u0432\u0430\u043d\u0438\u044f \u043f\u0440\u0438 \u0432\u0437\u0430\u0438\u043c\u043e\u0434\u0435\u0439\u0441\u0442\u0432\u0438\u0438 \u044d\u043f\u043e\u043a\u0441\u0438\u0434\u0438\u0430\u043d\u043e\u0432\u044b\u0445 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u043e\u0432 \u0441 \u0430\u0440\u043e\u043c\u0430\u0442\u0438\u0447\u0435\u0441\u043a\u0438\u043c \u0434\u0438\u0430\u043c\u0438\u043d\u043e\u043c \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440.\u0410. \u20131989. \u2013 31, \u2116 12. \u2013 \u0421. 2538-2543.<br \/>\n13. Richter E.B., Macosko C.W. Viscosity changes during isothermal and adiabatic network polymerization \/\/ Polym. Eng. Sci. \u2013 1980. \u201320, \u21167 \u2013 P. 921\u2013927.<br \/>\n14. \u0413\u043e\u0440\u0431\u0443\u043d\u043e\u0432\u0430 \u0418.\u042e., \u041a\u0435\u0440\u0431\u0435\u0440 \u041c.\u041b., \u0411\u0430\u043b\u0430\u0448\u043e\u0432 \u0418.\u041d., \u041a\u0430\u0437\u0430\u043a\u043e\u0432 \u0421.\u0418., \u041c\u0430\u043b\u043a\u0438\u043d \u0410.\u042f. \u0420\u0435\u043e\u043a\u0438\u043d\u0435\u0442\u0438\u043a\u0430 \u043e\u0442\u0432\u0435\u0440\u0436\u0434\u0435\u043d\u0438\u044f \u0438 \u0438\u0437\u043c\u0435\u043d\u0435\u043d\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432 \u0444\u0435\u043d\u043e\u043b-\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432\u043e\u0439 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u0438. \u0421\u043e\u043f\u043e\u0441\u0442\u0430\u0432\u043b\u0435\u043d\u0438\u0435 \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u043e\u0432, \u043f\u043e\u043b\u0443\u0447\u0435\u043d\u044b\u0445 \u0440\u0430\u0437\u043b\u0438\u0447\u043d\u044b\u043c\u0438 \u043c\u0435\u0442\u043e\u0434\u0430\u043c\u0438 \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u2013 2001. \u2013 43, \u2116 8. \u2013 \u0421. 1331-1339.<br \/>\n15. \u041f\u0440\u0430\u043a\u0442\u0438\u043a\u0443\u043c \u043f\u043e \u0445\u0438\u043c\u0438\u0438 \u0438 \u0444\u0438\u0437\u0438\u043a\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \/ \u041f\u043e\u0434 \u0440\u0435\u0434. \u041a\u0443\u0440\u0435\u043d\u043a\u043e\u0432\u0430 \u041c.\u0410.-\u041c.: \u0425\u0438\u043c\u0438\u044f, 1995. \u2013 256 \u0441.<br \/>\n16. \u0411\u0435\u0440\u043b\u0438\u043d \u0410.\u0410.\u0438 \u0434\u0440. \u0410\u043a\u0440\u0438\u043b\u043e\u0432\u044b\u0435 \u043e\u043b\u0438\u0433\u043e\u043c\u0435\u0440\u044b \u0438 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b \u043d\u0430 \u0438\u0445 \u043e\u0441\u043d\u043e\u0432\u0435 &#8211; \u041c.: \u0425\u0438\u043c\u0438\u044f, 1983. \u2013 386 \u0441.<br \/>\n17. \u041d\u0438\u043b\u044c\u0441\u0435\u043d \u041b. \u041c\u0435\u0445\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0435 \u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0438\u0439. &#8211; New York, 1974.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.04.341 The influence of ratio of reagents on the rheokinetics and viscoelastic properties of epoxy resin cured with amine hardener \u00a0 M.G. Tkalich, L.A. Gorbach, V.P. Shumskiy, I.P. Getmanchuk, \u041e.O.Brovko &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48 Kharkivs\u2019ke shose, 02160 Kyiv, Ukraine &nbsp; Polym. J., 2015, 37, no. 4: 341-346. &nbsp; Section: Structure [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1957"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1957"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1957\/revisions"}],"predecessor-version":[{"id":2187,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1957\/revisions\/2187"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1957"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}