{"id":1966,"date":"2018-01-10T18:07:01","date_gmt":"2018-01-10T15:07:01","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1966"},"modified":"2018-02-14T17:00:30","modified_gmt":"2018-02-14T14:00:30","slug":"2015-4-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-4-5\/","title":{"rendered":"2015 (4) 5"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.04.362\">https:\/\/doi.org\/10.15407\/polymerj.37.04.362<\/a><\/p>\n<p><strong>Destructive properties of exopolysaccharides based polyurethanes<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>L.<\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>. Markovskaya, E.R. Akhranovich, O.A. Savelyeva, N.I. Parkhomenko, T.V. Dmitrieva, Yu.V. Savelyev<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 4: 362-368.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Interaction between exopolysaccharide hydroxyls (xanthan and bacterial cellulose) and urethane and urea groups of PUF as well as diisocyanate has been elucidated by PMS method. This interaction results in new structure formation defined by exopolysaccharide nature and by the method of its insertion into reaction mixture during the PUF synthesis.\u00a0 It has been shown that the insertion of exopolysaccharides into the PUF structure imparts the ability to degrade when incubated into a soil, initiates the processes of fragmentation and leads to the rise of its velocity.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Key words<\/strong>:\u00a0 foam polyurethanes, exopolysaccharides, destructive properties,\u00a0 interaction.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>1. Anastas P., Warner J. Green Chemistry: Theory and Practice. London: Oxford University Press, 1998. &#8211; 144 \u0440.<br \/>\n2. Singh B., Sharma N. Mechanistic implications of plastic degradation \/\/ Polymer Degradation and Stability. \u2013 2008. \u2013 93, \u2116 3. &#8211; \u0420. 561-584.<br \/>\n3. Lu D.R., Xiao C.M., Xu S.J. Starch-based completely biodegradable polymer materials \/\/ Express Polymer Letters. \u2013 2009. \u2013 3, \u2116 6. \u2013 \u0420. 366\u2013375.<br \/>\n4. \u0417\u0435\u0437\u0438\u043d \u0410. \u0411. \u041f\u043e\u043b\u0438\u043c\u0435\u0440\u044b \u0438 \u043e\u043a\u0440\u0443\u0436\u0430\u044e\u0449\u0430\u044f \u0441\u0440\u0435\u0434\u0430 \/\/ \u0421\u043e\u0440\u043e\u0441\u043e\u0432\u0441\u043a\u0438\u0439 \u043e\u0431\u0440\u0430\u0437\u043e\u0432. \u0436\u0443\u0440\u043d. \u2013 1996. \u2013 \u2116 2. \u2013 \u0421. 57\u201364.<br \/>\n5. Howard G. Biodegradation of polyurethane: a review \/\/ Internat. Biodeterioration &amp; Biodegradation. \u2013 2002. \u2013 \u2116 49. \u2013 \u0420. 245\u2013252.<br \/>\n6. Sivan A. New perspectives in plastic biodegradation \/\/ Current Opinion in Biotechnology. \u2013 2011. \u2013 22, \u2116 3. \u2013 P. 422-426.<br \/>\n7. Galgali P., Agashe M., Varma J. Sugar-linked bidegradable polymers: regio-spesific ester bonds of glucose hydroxyls in their reaction with maleic anhydride functionalized polystyrene and elucidation of the polymer structures formed \/\/ Carbohydrate Polym. \u2013 2007. \u2013 67, \u2116 4. \u2013 \u0420. 576\u2013585.<br \/>\n8. \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0417\u0430\u043c\u0443\u043b\u0456\u043d\u0430 \u041b.\u0406., \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410. \u0421\u0438\u043d\u0442\u0435\u0437 \u0442\u0430 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043d\u044f \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0438 \u043d\u043e\u0432\u043e\u0433\u043e \u043b\u0430\u043a\u0442\u043e\u0437\u043e\u0432\u043c\u0456\u0441\u043d\u043e\u0433\u043e \u043c\u043e\u043d\u043e\u043c\u0435\u0440\u0443 2,4-\u0442\u043e\u043b\u0443\u0457\u043b\u0435\u043d-\u0434\u0456-\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u043b\u0430\u043a\u0442\u043e\u0437\u0438 \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2004. \u2013 26, \u2116 2. \u2013 \u0421. 83-85.<br \/>\n9. \u041f\u0430\u0442. 37345 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a8 \u042108G18\/08, C08K3\/34, C08K5\/03, C08K5\/06 \u041f\u0456\u043d\u043e\u043f\u043e\u043b\u0456\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432\u0438\u0439 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \/ \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432 \u042e.\u0412., \u041c\u0430\u0440\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u041b.\u0410., \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432\u0430 \u041e.\u041e., \u041f\u0430\u0440\u0445\u043e\u043c\u0435\u043d\u043a\u043e \u041d.\u0419. &#8211; \u041e\u043f\u0443\u0431\u043b. 25.11.2008.- \u0411\u044e\u043b. \u2116 22.<br \/>\n10. \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432 \u042e.\u0412., \u042f\u043d\u043e\u0432\u0438\u0447 \u0406.\u0412., \u041c\u0430\u0440\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u041b.\u0410., \u0410\u0445\u0440\u0430\u043d\u043e\u0432\u0438\u0447 \u041e.\u0420., \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432\u0430 \u041e.\u0410., \u0420\u043e\u0431\u043e\u0442\u0430 \u041b.\u041f. \u0421\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u043d\u043e\u0432\u0438\u0445 \u043b\u0430\u043a\u0442\u043e\u0437\u043e\u0432\u043c\u0456\u0441\u043d\u0438\u0445 \u043f\u0456\u043d\u043e\u043f\u043e\u043b\u0456\u0443\u0440\u0435\u0442\u0430\u043d\u0456\u0432, \u0437\u0434\u0430\u0442\u043d\u0438\u0445 \u0434\u043e \u0434\u0435\u0433\u0440\u0430\u0434\u0430\u0446\u0456\u0457 \u0432 \u043d\u0430\u0432\u043a\u043e\u043b\u0438\u0448\u043d\u044c\u043e\u043c\u0443 \u0441\u0435\u0440\u0435\u0434\u043e\u0432\u0438\u0449\u0456 \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2011. &#8211; \u2116 7. \u2013 \u0421. 138-142<br \/>\n11. \u041f\u0430\u0442. 68668 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a8 C08 J 9\/08,\u042108 \u041a 3\/34,\u042108 \u041a 5\/03,\u042108 \u041a 5\/06. \u041f\u0456\u043d\u043e\u043f\u043e\u043b\u0456\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432\u0438\u0439 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \/\/\u042e.\u0412.\u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432, \u0406.\u0412.\u042f\u043d\u043e\u0432\u0438\u0447 ,\u041b.\u0410.\u041c\u0430\u0440\u043a\u043e\u0432\u0441\u044c\u043a\u0430, \u041e.\u0420. \u0410\u0445\u0440\u0430-\u043d\u043e\u0432\u0438\u0447 \u2013 \u041e\u043f\u0443\u0431\u043b. 10.04.2012. &#8211; \u0411\u044e\u043b. \u2116 7.<br \/>\n12. \u0415\u0440\u043c\u043e\u043b\u043e\u0432\u0438\u0447 \u041e.\u0410., \u041c\u0430\u043a\u0430\u0440\u0435\u0432\u0438\u0447 \u0410.\u0412., \u0413\u043e\u043d\u0447\u0430\u0440\u043e\u0432\u0430 \u0415.\u041f., \u0412\u043b\u0430\u0441\u043e\u0432\u0430 \u0413.\u041c. \u041c\u0435\u0442\u043e\u0434\u044b \u043e\u0446\u0435\u043d\u043a\u0438 \u0431\u0438\u043e\u0440\u0430\u0437\u043b\u0430\u0433\u0430\u0435\u043c\u043e\u0441\u0442\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u043e\u0432 \/\/ \u0411\u0438\u043e\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u044f. \u2013 2005. &#8211; \u2116 4. \u2013 \u0421. 47-54.<br \/>\n13. \u0411\u0430\u0431\u044c\u0435\u0432\u0430 \u0418.\u041f., \u0417\u0435\u043d\u043e\u0432\u0430 \u0413.\u041c. \u0411\u0438\u043e\u043b\u043e\u0433\u0438\u044f \u043f\u043e\u0447\u0432. \u2013 \u041c.: \u0418\u0437\u0434-\u0432\u043e \u041c\u043e\u0441\u043a. \u0443\u043d-\u0442\u0430, 1989. \u2013 320 \u0441.<br \/>\n14. \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u043a\u0438\u0439 \u0420.\u0410., \u041b\u0443\u043a\u0430\u0448\u0435\u043d\u043a\u043e \u0418.\u041c., \u0411\u0440\u043e\u0434\u0441\u043a\u0438\u0439 \u0415.\u0421. \u041f\u0438\u0440\u043e\u043b\u0438\u0442\u0438\u0447\u0435\u0441\u043a\u0430\u044f \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u044f \u0432\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435-\u043a\u0443\u043b\u044f\u0440\u043d\u044b\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439. \u2013 \u041c.: \u0425\u0438\u043c\u0438\u044f, 1980. \u2013 280 \u0441.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.04.362 Destructive properties of exopolysaccharides based polyurethanes \u00a0 L.\u0410. Markovskaya, E.R. Akhranovich, O.A. Savelyeva, N.I. Parkhomenko, T.V. Dmitrieva, Yu.V. Savelyev &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2015, 37, no. 4: 362-368. &nbsp; Section: Structure and properties. &nbsp; Language: Ukrainian. &nbsp; Abstract: Interaction between exopolysaccharide [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1966"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1966"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1966\/revisions"}],"predecessor-version":[{"id":2190,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1966\/revisions\/2190"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1966"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}