{"id":1969,"date":"2018-01-10T18:09:37","date_gmt":"2018-01-10T15:09:37","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=1969"},"modified":"2018-02-14T17:01:46","modified_gmt":"2018-02-14T14:01:46","slug":"2015-4-6","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2015-4-6\/","title":{"rendered":"2015 (4) 6"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.37.04.369\">https:\/\/doi.org\/10.15407\/polymerj.37.04.369<\/a><\/p>\n<p><strong>Physico-chemical and mechanical properties of organic-inorganic composites<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>G.I. Khovanets\u2019<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, Y.G. Medvedevskikh<\/em><\/strong><strong><em>1<\/em><\/strong><strong><em>, V.P. Zakordonskiy<\/em><\/strong><strong><em>2<\/em><\/strong><strong><em>, V.V. Kochubey<\/em><\/strong><strong><em>3<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1Department of Physical Chemistry of Fossil Fuels InPOCC NAS of Ukraine<\/p>\n<p>3a, Naukova str., Lviv, 79060, Ukraine<\/p>\n<p>2Ivan Franko National University of Lviv<\/p>\n<p>6, Kyryla and Mefodiya str., Lviv, 79005, Ukraine<\/p>\n<p>3National University \u201cLvivska Politechnika\u201d<\/p>\n<p>12, S. Bandery str., Lviv, 79013, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2015, <strong>37<\/strong>, no. 4: 369-374.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The influence of the composition of hybrid organic-inorganic composites (HOIC) based on the system 2-hydroxyethylmethacrylate (HEMA) \u2013 tetraethoxysilane (TEOS) on their physico-chemical and mechanical properties and parameters of their molecular structure was investigated. The data obtained at the study of microhardness, thermomechanical and thermal properties of the composites are well correlated with each other. It was found that at small amount of the inorganic component (2,5 and 5 vol. %) the phase of this component, which is formed as nanoparticles, is more compatible with the organic phase component and the composite has characterized improved properties.<\/em><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Keywords:<\/strong> organic-inorganic composite, photoinitiated polymerization, thermomechanical analysis, derivatographic analysis, microhardness.<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1. \u0411\u0430\u0431\u043a\u0438\u043d\u0430 \u041d.\u0412., \u041c\u0430\u0440\u0442\u044b\u043d\u044e\u043a \u0418.\u0421., \u0410\u043b\u0435\u043a\u0441\u0435\u0435\u0432\u0430 \u0422.\u0422. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2013. \u2013 35, \u2116 3. \u2013 \u0421. 237\u2013242.<br \/>\n2. \u0428\u0438\u043b\u043e\u0432\u0430 \u041e.\u0410., \u0428\u0438\u043b\u043e\u0432 \u0412.\u0412. \/\/ Nanosystems, Nanomaterials, Nanotechnologies. \u2013 2003. \u2013 1, \u2116 1. \u2013 \u0421. 9\u201383.<br \/>\n3. Bronstein L.M., Karlinsey R.L., Ritter K., Joo C.G., Stein B., Zwanziger J.W. \/\/ J. Mater. Chem. \u2013 2004. \u2013 14. \u2013 P. 1812\u20131820.<br \/>\n4. Membrane Technologies and Applications \/ Edited by Kaustubha Mohanty, Mihir K. Purkait. \u2013 New York: Taylor &amp; Francis Group, CRC Press, 2012. \u2013 503 p.<br \/>\n5. Jiang H., Kakkar A.K. \/\/ Adv. Mater. \u2013 1998. \u2013 10, \u2116 2. \u2013 P. 1093\u20131097.<br \/>\n6. Cho J.W., Sul K.I. \/\/ Polymer. \u2013 2001. \u2013 42, \u2116 2. \u2013 P. 727\u2013736.<br \/>\n7. \u041f\u043e\u043c\u0430\u0433\u0430\u0439\u043b\u043e \u0410.\u0414. \/\/ \u0423\u0441\u043f\u0435\u0445\u0438 \u0445\u0438\u043c\u0438\u0438. \u2013 2000. \u2013 69, \u2116 1. \u2013 \u0421. 60\u201389.<br \/>\n8. \u041c\u0456\u0448\u0443\u0440\u043e\u0432 \u0414.\u041e., \u0410\u0432\u0440\u0430\u043c\u0435\u043d\u043a\u043e \u0412.\u041b., \u0411\u0440\u043e\u0432\u043a\u043e \u041e.\u041e. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2013. \u2013 35, \u2116 3. \u2013 \u0421. 217\u2013230.<br \/>\n9. \u0425\u043e\u0432\u0430\u043d\u0435\u0446\u044c \u0413., \u0417\u0430\u043a\u043e\u0440\u0434\u043e\u043d\u0441\u044c\u043a\u0438\u0439 \u0412., \u041c\u0435\u0434\u0432\u0435\u0434\u0435\u0432\u0441\u044c\u043a\u0438\u0445 \u042e. \/\/ \u0412\u0456\u0441\u043d\u0438\u043a \u041b\u044c\u0432\u0456\u0432. \u0443\u043d-\u0442\u0443. \u0421\u0435\u0440. \u0445\u0456\u043c. \u2013 2003. \u2013 43, \u0427. 2. \u2013 \u0421. 190\u2013198.<br \/>\n10. \u0417\u0430\u043a\u043e\u0440\u0434\u043e\u043d\u0441\u044c\u043a\u0438\u0439 \u0412., \u0421\u043a\u043b\u0430\u0434\u0430\u043d\u044e\u043a \u0420., \u0422\u0438\u0445\u043e\u0432\u0435\u0446\u044c\u043a\u0438\u0439 \u0410. \/\/ \u0412\u0456\u0441\u043d\u0438\u043a \u041b\u044c\u0432\u0456\u0432. \u0443\u043d-\u0442\u0443. \u0421\u0435\u0440. \u0445\u0456\u043c. \u2013 2014. \u2013 55, \u0427. 2. \u2013 \u0421. 432\u2013441.<br \/>\n11. \u0422\u0435\u0439\u0442\u0435\u043b\u044c\u0431\u0430\u0443\u043c \u0411.\u042f. \u0422\u0435\u0440\u043c\u043e\u043c\u0435\u0445\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0439 \u0430\u043d\u0430\u043b\u0438\u0437 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041c.: \u041d\u0430\u0443\u043a\u0430, 1979. \u2013 236 \u0441.<br \/>\n12. \u0418\u0432\u0430\u043d\u0447\u0435\u0432 \u0421.\u0421., \u041c\u0435\u0448 \u0410.\u041c., Reichelt N., \u0425\u0430\u0439\u043a\u0438\u043d \u0421.\u042f., Hesse A., \u041c\u044f\u043a\u0438\u043d \u0421.\u0412. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0410. \u2013 2002. \u2013 44, \u2116 6. \u2013 \u0421. 996\u20131002.<br \/>\n13. \u041a\u0430\u0440\u0430\u0431\u0430\u043d\u043e\u0432\u0430 \u041b.\u0412., \u0413\u043e\u043c\u0437\u0430 \u042e.\u041f., \u041d\u0435\u0441\u0438\u043d \u0421.\u0414., \u0413\u043b\u0438\u0435\u0432\u043e\u0439 \u0410.\u0411., \u0411\u043e\u043d\u0434\u0430\u0440\u0443\u043a \u041e.\u041d. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2012. \u2013 34, \u2116 1. \u2013 \u0421. 138\u2013147.<br \/>\n14. \u0424\u0438\u0437\u0438\u043a\u043e-\u0445\u0438\u043c\u0438\u044f \u043c\u043d\u043e\u0433\u043e\u043a\u043e\u043c\u043f\u043e\u043d\u0435\u043d\u0442\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0445 \u0441\u0438\u0441\u0442\u0435\u043c, \u0432 2 \u0442. \/ \u041f\u043e\u0434 \u0440\u0435\u0434. \u042e.\u0421. \u041b\u0438\u043f\u0430\u0442\u043e\u0432\u0430. \u2013 \u041a.: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1986. \u2013 \u0422. 2. \u2013 \u0421. 137\u2013228.<br \/>\n15. \u0417\u0430\u043a\u043e\u0440\u0434\u043e\u043d\u0441\u044c\u043a\u0438\u0439 \u0412.\u041f., \u041c\u0430\u0440\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u0420.\u041f., \u0423\u043a\u0440\u0430\u0457- \u043d\u0435\u0446\u044c \u0410.\u041c. \u041c\u0435\u0442\u043e\u0434\u0438\u0447\u043d\u0456 \u0432\u043a\u0430\u0437\u0456\u0432\u043a\u0438 \u0434\u043e \u0432\u0438\u0432\u0447\u0435\u043d\u043d\u044f \u0440\u0435\u043e\u043b\u043e\u0433\u0456\u0457 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0456\u0432. \u2013 \u041b\u044c\u0432\u0456\u0432: \u041b\u0414\u0423, 1988. \u2013 16 \u0441.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.37.04.369 Physico-chemical and mechanical properties of organic-inorganic composites \u00a0 G.I. Khovanets\u20191, Y.G. Medvedevskikh1, V.P. Zakordonskiy2, V.V. Kochubey3 &nbsp; 1Department of Physical Chemistry of Fossil Fuels InPOCC NAS of Ukraine 3a, Naukova str., Lviv, 79060, Ukraine 2Ivan Franko National University of Lviv 6, Kyryla and Mefodiya str., Lviv, 79005, Ukraine 3National University \u201cLvivska Politechnika\u201d 12, S. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1969"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=1969"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1969\/revisions"}],"predecessor-version":[{"id":2191,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/1969\/revisions\/2191"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=1969"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}