{"id":2032,"date":"2018-01-19T18:56:17","date_gmt":"2018-01-19T15:56:17","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2032"},"modified":"2018-02-14T14:59:40","modified_gmt":"2018-02-14T11:59:40","slug":"2017-4-1","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2017-4-1\/","title":{"rendered":"2017 (4) 1"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.39.04.219<\/a><\/p>\n

Influence of the carbon micro and nanofillers on the electrical and thermal properties of the segregated polymer composites<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

O.V.<\/em><\/strong>\u00a0Maruzhenko<\/em><\/strong>1,2<\/em><\/strong>,<\/em><\/strong> Ye.P.<\/em><\/strong>\u00a0Mamunya<\/em><\/strong>1<\/em><\/strong>,<\/em><\/strong> G.<\/em><\/strong>\u00a0Boiteux<\/em><\/strong>2<\/em><\/strong>,<\/em><\/strong> S.<\/em><\/strong>\u00a0Pruvost<\/em><\/strong>3<\/em><\/strong>,<\/em><\/strong> S.<\/em><\/strong>\u00a0Pusz<\/em><\/strong>4<\/em><\/strong>,<\/em><\/strong> U.<\/em><\/strong>\u00a0Szeluga<\/em><\/strong>4<\/em><\/strong>,<\/em><\/strong> B.<\/em><\/strong>\u00a0Kumanek<\/em><\/strong>4<\/em><\/strong><\/p>\n

 <\/p>\n

1Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

2Universite de Lyon, Universite Lyon 1, Ingenierie des Materiaux Polymeres<\/p>\n

UMR CNRS 5223, 69 622 Villeurbanne Cedex, France<\/p>\n

3Universite de Lyon, INSA Lyon, Ingenierie des Materiaux Polymeres<\/p>\n

UMR CNRS 5223, 69 621 Villeurbanne Cedex, France<\/p>\n

4Centre of Polymer and Carbon Materials, Polish Academy of Sciences<\/p>\n

34, Marii Curie-Sk\u0456odowskiej, 41-819 Zabrze, Poland<\/p>\n

 <\/p>\n

Polym. J., 2017, 39, \u2116 4: 219-226.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Russian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

There were studied electrical and thermal properties of polymer composites with carbon micro- and nano fillers with statistical and segregated filler distribution in polymer matrix. Samples were prepared by hot compacting method, as a filler there were used thermally treated anthracite (A), graphene (Gr) and hybrid filler (Gr-A). There was found that systems with segregated filler distribution has significantly lower percolation threshold comparing to the systems with random distribution. Also, great impact on electrical conductivity has filler sizes \u2013 system with nanofiller (Gr) showed lowest percolation threshold (0,21 %\u00a0vol.) and with microfiller (A) \u2013 highest (2,95\u00a0% vol.). Synergistic effect caused by nano- and microfillers combination was achieved for hybrid systems Gr-A. Thermomechanical analysis showed significant growth of mechanical losses tangent in the area above melting temperature after hitting critical concentration value.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Key words:<\/strong> polymer composites, carbon micro- and nanofillers, segregated systems, electrical conductivity, mechanical losses.<\/p>\n

 <\/p>\n

References<\/strong><\/h3>\n

 <\/p>\n

1. Friedrich K., Breuer U. Multifunctionality of polymer composites. Challenges and new solutions. USA: Elsevier Inc. 2015, 964 p.
\n2. Advances in nanocomposites – synthesis, characterization and industrial applications. Reddy B., ed., Rijeka, Croatia: InTech; 2011. https:\/\/doi.org\/10.5772\/604<\/a>
\n3. Metal, ceramic and polymeric composites for various uses. J. Cuppoletti, ed.: InTech, Rijeka, Croatia, 2011. https:\/\/doi.org\/10.5772\/1428<\/a>
\n4. Carbon nanotubes \u2013 polymer nanocomposites. S. Yellampalli, ed., InTech, Rijeka, Croatia, 2011. https:\/\/doi.org\/10.5772\/979<\/a>
\n5. The new frontiers of organic and composite nanotechnology. V. Erokhin, M.K. Ram, O. Yavuz, eds., Amsterdam, Netherlands: Elsevier, 2008.
\n6. Conductive polymers and plastics in industrial applications. L. Rupprecht, ed., NY, USA: William Andrew Inc., 1999.
\n7. Kusy R. P. Influence of particle size ratio on the continuity of aggregates. J. Appl. Phys., 1977, 48: 5301\u20135305. https:\/\/doi.org\/10.1063\/1.323560<\/a>
\n8. Gong T., Peng S. P., Bao R. Y., Yang W., Xie B. H., Yang M. B. Low percolation threshold and balanced electrical and mechanical performances in polypropylene\/carbon black composites with a continuous segregated structure. Compos. Part B Eng., 2016, 99: 348\u2013357. https:\/\/doi.org\/10.1016\/j.compositesb.2016.06.031<\/a>
\n9. George N., Bipinbal P. K., Bhadran B., Mathiazha- gan A., Joseph R. Segregated network formation of multiwalled carbon nanotubes in natural rubber through surfactant assisted latex compounding: A novel technique for multifunctional properties. Polymer, 2017, 112: 264\u2013277. https:\/\/doi.org\/10.1016\/j.polymer.2017.01.082<\/a>
\n10. Yoo T. J., Hwang E. B., Jeong Y. G., Thermal and electrical properties of poly(phenylene sulfide)\/carbon nanotube nanocomposite films with a segregated structure. Compos. Part A Appl. Sci. Manuf., 2016, 91: 77\u201384. https:\/\/doi.org\/10.1016\/j.compositesa.2016.09.022<\/a>
\n11. Ren P. G., Hou S. Y., Ren F., Zhang Z. P., Sun Z. F., Xu L. The influence of compression molding techniques on thermal conductivity of UHMWPE\/BN and UHMWPE\/(BN+MWCNT) hybrid composites with segregated structure. Compos. Part A Appl. Sci. Manuf., 2016, 90: 13\u201321. https:\/\/doi.org\/10.1016\/j.compositesa.2016.06.019<\/a>
\n12. Pusz S., Szeluga U., Nagel B., Czajkowska S., Galina H., Strzezik J. The influence of structural order of anthracite fillers on the curing behavior, morphology, and dynamic mechanical thermal properties of epoxy composites. Polym. Compos., 2014, 36: 336\u2013347. https:\/\/doi.org\/10.1002\/pc.22948<\/a>
\n13. Mamunya Ye.P., Iurzhenko M.V., Lebedev E.V., Levchenko V.V., Chervakov O.V., Matkovska O.K., Sverdlikovska O.S. Electroactive polymer materials, Kyiv: Alpha-reklama, 2013: 398 (in Ukrainian).
\n14. Stauffer D., Aharony A., Introduction to Percolation Theory, Computer, 1994, 1, no. 4: 192.
\n15. Lebovka N., Lisunova M., Mamunya Y. P., Vygornitskii N. Scaling in percolation behaviour in conductive\u2013insulating composites with particles of different size. J. Phys. D. Appl. Phys., 2006, 39, no. 10: 2264\u20132271. https:\/\/doi.org\/10.1088\/0022-3727\/39\/10\/040<\/a>
\n16. Kogut P. M., Straley J. P. Distribution-induced non-universality of the percolation conductivity exponents. J. Phys. C Solid State Phys., 1979, 12, no. 11: 2151. https:\/\/doi.org\/10.1088\/0022-3719\/12\/11\/023<\/a>
\n17. Mamunya Y., Boudenne A., Lebovka N., Ibos L., Candau Y., Lisunova M. Electrical and thermophysical behaviour of PVC-MWCNT nanocomposites. Compos. Sci. Technol., 2008, 68, no. 9: 1981\u20131988. https:\/\/doi.org\/10.1016\/j.compscitech.2007.11.014<\/a>
\n18. McLachlan D. S., Chiteme C., Heiss W. D., Wu J. Fitting the DC conductivity and first order AC conductivity results for continuum percolation media, using percolation theory and a single phenomenological equation. Phys. B Condens. Matter, 2003, 338, no. 1\u20134: 261\u2013265. https:\/\/doi.org\/10.1016\/j.physb.2003.08.003<\/a>
\n19. Levchenko V., Mamunya Y., Boiteux G., Lebovka M., Alcouffe P., Seytre G., Lebedev E., Influence of organo-clay on electrical and mechanical properties of PP\/MWCNT\/OC nanocomposites, Eur. Polym. J., 2011, 47, no. 7: 1351\u20131360. https:\/\/doi.org\/10.1016\/j.eurpolymj.2011.03.012<\/a>
\n20. Mamunya E. P., Davidenko V. V., Lebedev E. V. Percolation conductivity of polymer composites filled with dispersed conductive filler. Polym. Compos., 1995, 16, no. 4: 319\u2013324. https:\/\/doi.org\/10.1002\/pc.750160409<\/a>
\n21. Ma P. C., Liu M. Y., Zhang H., Wang S. Q., Wang R., Wang K., Wong Y. K., Tang B. Z., Hong S. H., Paik K. W., Kim J. K. Enhanced electrical conductivity of nanocomposites containing hybrid fillers of carbon nanotubes and carbon black. ACS Appl. Mater. Interfaces, 2009, 1, no. 5: 1090\u20131096. https:\/\/doi.org\/10.1021\/am9000503<\/a>
\n22. Al-Saleh M. H. Electrical and mechanical properties of graphene\/carbon nanotube hybrid nanocomposites. Synth. Met., 2015, 209: 41\u201346. https:\/\/doi.org\/10.1016\/j.synthmet.2015.06.023<\/a>
\n23. Chukov D. I., Stepashkin A. A., Maksimkin A. V, Tcherdyntsev V. V, Kaloshkin S. D., Kuskov K. V, Buga-kov V. I. Investigation of structure, mechanical and tribological properties of short carbon fiber reinforced UHMWPE-matrix composites. Compos. Part B, 2015, 76: 79\u201388. https:\/\/doi.org\/10.1016\/j.compositesb.2015.02.019<\/a>
\n24. Mierczynska A., Mayne-L’Hermite M., Boiteux G., Jeszka J. K. Electrical and mechanical properties of carbon nanotube\/ ultrahigh-molecular-weight polyethylene composites prepared by a filler prelocalization method. J. Appl. Polym. Sci., 2007, 105: 158\u2013168. https:\/\/doi.org\/10.1002\/app.26044<\/a>
\n25. Pegoretti M. A., Migliaresi C., Marom G. Relaxation processes in polyethylene \u00aebre-reinforced polyethylene composites. Compos. Sci. Technol., 2000, 60: 1181\u20131189. https:\/\/doi.org\/10.1016\/S0266-3538(00)00024-5<\/a>
\n26. You Z., Li D. The dynamical viscoelasticity and tensile property of new highly filled charcoal powder\/ultra-high molecular weight polyethylene composites. Mater. Lett., 2013, 112: 197\u2013199. https:\/\/doi.org\/10.1016\/j.matlet.2013.09.013<\/a>
\n27. Li S., Li X., Deng Q., Li D. Three kinds of charcoal powder reinforced ultra-high molecular weight polyethylene composites with excellent mechanical and electrical properties. Mater. Des., 2015, 85: 54\u201359. https:\/\/doi.org\/10.1016\/j.matdes.2015.06.163<\/a>
\n28. Kar S., Maji P. K., Bhowmick A. K. Chlorinated polyethylene nanocomposites: Thermal and mechanical behaviour. J. Mater. Sci., 2010, 45: 64\u201373. https:\/\/doi.org\/10.1007\/s10853-009-3891-z<\/a>
\n29. Shrivastava N. K., Suin S., Maiti S., Khatua B. B. An approach to reduce the percolation threshold of MWCNT in ABS\/MWCNT nanocomposites through selective distribution of CNT in ABS matrix. RSC Adv., 2014, 4: 84. https:\/\/doi.org\/10.1039\/c4ra01952k<\/a>
\n30. Landel R. F., Nielsen L. E. Mechanical Properties of Polymers and Composites, Second Edition. CRC Press, 1993: 580. ISBN 978-082-47-8964-0.<\/p>\n

 <\/p>\n

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