{"id":2077,"date":"2018-02-07T15:32:27","date_gmt":"2018-02-07T12:32:27","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2077"},"modified":"2018-02-07T15:32:27","modified_gmt":"2018-02-07T12:32:27","slug":"2014-4-4","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2014-4-4\/","title":{"rendered":"2014 (4) 4"},"content":{"rendered":"

Ion-conductive polymer system based on aliphatic epoxy resin and LiClO<\/strong>4<\/strong><\/p>\n

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L.K. Matkovska<\/em><\/strong>1<\/em><\/strong>, M.V. Iurzhenko<\/em><\/strong>1<\/em><\/strong>, Ye.P. Mamunya<\/em><\/strong>1<\/em><\/strong>, O.K. Matkovska<\/em><\/strong>1<\/em><\/strong>, E.V. Lebedev<\/em><\/strong>1<\/em><\/strong>, G. Boiteux<\/em><\/strong>2<\/em><\/strong>, A. Serghei<\/em><\/strong>2<\/em><\/strong><\/p>\n

 <\/p>\n

1Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

2Universite de Lyon, Universite Lyon 1, Ingenierie des Materiaux Polymeres<\/p>\n

UMR CNRS 5223, IMP@LYON1, France<\/p>\n

 <\/p>\n

Polym. J., 2014, 36<\/strong>, no. 4: 361-368.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

Ion-conductive polymer material based on epoxy oligomer of diglycide aliphatic ester of polyethylene glycol (DEG) was synthesized cured by polyethylenepolyamine and in the presence of lithium perchlorate (LiClO<\/em>4<\/em>). The effect of LiClO<\/em>4<\/em>\u00a0content on electrophysical properties of epoxy polymers has been studied by means of methods of the Differential scanning calorimetry (DSC) and the broadband dielectric spectroscopy (BDS). Perchlorate lithium affects on structure of the epoxy DEG as evidenced from a significant increase in the glass transition temperature with increasing concentration of LiClO<\/em>4<\/em>\u00a0coordination complexes, as a result {ether oxygen – lithium cations – ether oxygen} formed. The obtained polymer material has high values of ionic conductivity <\/em>s<\/em>‘ ( 10<\/em>-3<\/em>\u00a0S\/cm) and dielectric constant <\/em>e<\/em>‘ (6\u00b710<\/em>5<\/em>) at elevated temperatures (200 \u00b0<\/em>\u0421<\/em>). The presence of ether oxygen in the chemical structure of DEG polymer chain that is similar to polyethylene oxide provides a transfer mechanism of the lithium cations with the ether oxygen. In contrast to PEO the polyepoxide DEG has high heat resistance, therefore DEG-LiClO4 systems are of interest as perspective solid polymer electrolytes, which are able to work at high temperature.<\/em><\/p>\n

 <\/p>\n

Key words:<\/strong> ion-conductive polymer, epoxy resin, lithium perchlorate, glass transition temperature, electrical and dielectric characteristics.<\/p>\n

 <\/p>\n

\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

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\n30. \u041f\u0435\u0440\u0448\u0438\u043d\u0430 \u041a.\u0414., \u041a\u0430\u0437\u0434\u043e\u0431\u0456\u043d \u041a.\u041e. \u0421\u043f\u0435\u043a\u0442\u0440\u043e\u0441\u043a\u043e\u043f\u0456\u044f \u0456\u043c\u043f\u0435\u0434\u0430\u043d\u0441\u0443 \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043b\u0456\u0442\u0438\u0447\u043d\u0438\u0445 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0456\u0432. – \u041a.: \u041e\u0441\u0432\u0456\u0442\u0430 \u0423\u043a\u0440\u0430\u0457\u043d\u0438, 2012. – 224 \u0441.<\/p>\n

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Ion-conductive polymer system based on aliphatic epoxy resin and LiClO4   L.K. Matkovska1, M.V. Iurzhenko1, Ye.P. Mamunya1, O.K. Matkovska1, E.V. Lebedev1, G. Boiteux2, A. Serghei2   1Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine 2Universite de Lyon, Universite Lyon 1, Ingenierie des Materiaux Polymeres UMR CNRS 5223, IMP@LYON1, France   […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2077"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2077"}],"version-history":[{"count":1,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2077\/revisions"}],"predecessor-version":[{"id":2078,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2077\/revisions\/2078"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2077"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}