{"id":2080,"date":"2018-02-07T15:37:03","date_gmt":"2018-02-07T12:37:03","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2080"},"modified":"2018-02-07T15:37:53","modified_gmt":"2018-02-07T12:37:53","slug":"2014-4-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2014-4-5\/","title":{"rendered":"2014 (4) 5"},"content":{"rendered":"<p><strong>Properties and structure of composites, comprising organopilisized montmorillinite <\/strong><\/p>\n<p><em>\u00a0<\/em><\/p>\n<p><strong><em>L.P. Robota, N.I. Parkhomenko, <\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>.N. Gonchar, V.I. Litvyakov, V.G. Sierov, V.I. Shtompel, G.M. Shumikova,\u00a0 Yu.V. Savelyev <\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2014, <strong>36<\/strong>, no. 4: 369-377.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Russian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>Montmorillonite-comprising film-forming composites where montmorillonite has been organophilisized (<\/em><em>\u043e<\/em><em>&#8211;<\/em><em>\u041c\u041c\u0422<\/em><em>) with both cationic surfactant &#8211; hexadecyltrimethylammonium bromide and tris (hydroxymethyl) aminomethane chloride (TGAM), that has been confirmed by IR-, and thermogravimetric study, have been prepared. The structure of obtained materials has been studied by IR-spectroscopy (including the computer prosessing of the spectra) and X-ray scattering. Materials modification with Zn acetylacetonate and its chlorides results in hydrogen bonds redistribution with the participation of Zn-cations, <\/em><em>\u043e<\/em><em>&#8211;<\/em><em>\u041c\u041c\u0422<\/em><em> and polar fragments of polymeric chain providing the <\/em><em>\u043e<\/em><em>&#8211;<\/em><em>\u041c\u041c\u0422<\/em><em> exfoliation. The composite, comprising 4 % <\/em><em>\u043e<\/em><em>&#8211;<\/em><em>\u041c\u041c\u0422<\/em><em> possesses the optimal physic-mechanical properties and increased thermooxidative stability.<\/em><\/p>\n<p>&nbsp;<\/p>\n<p><strong>Key words:<\/strong> composites, montmorillonite, organophilization, modification, properties, intermolecular interactions, intercalation.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0438\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1. \u0420\u043e\u043c\u0430\u043d\u043e\u0432\u0441\u043a\u0438\u0439 \u0411.\u0412., \u041c\u0430\u043a\u0448\u0438\u043d\u0430 \u0415.\u0412. \/\/ \u0421\u043e\u0440\u043e\u0441\u043e\u0432\u0441\u043a\u0438\u0439 \u043e\u0431\u0440\u0430\u0437\u043e\u0432. \u0436\u0443\u0440\u043d. &#8211; 2004. &#8211; 8, \u2116 2. &#8211; \u0421. 50-55.<br \/>\n2. \u0422\u0430\u0440\u0430\u0441\u0435\u0432\u0438\u0447 \u042e.\u0418. \u0421\u0442\u0440\u043e\u0435\u043d\u0438\u0435 \u0438 \u0445\u0438\u043c\u0438\u044f \u043f\u043e\u0432\u0435\u0440\u0445\u043d\u043e\u0441\u0442\u0438 \u0441\u043b\u043e\u0438\u0441\u0442\u044b\u0445 \u0441\u0438\u043b\u0438\u043a\u0430\u0442\u043e\u0432 \/ \u042e. \u0418. \u0422\u0430\u0440\u0430\u0441\u0435\u0432\u0438\u0447. \u2013 \u041a. : \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1988. \u2013 \u0421. 248.<br \/>\n3. Ray S.S., Okamoto M. \/\/ Prog. Polym. Sci. &#8211; 2003. &#8211; V. 28. &#8211; P. 1539-1641.<br \/>\n4. Giannelis E.P., Krishnamoorti R., Manias E. \/\/ Adv. Polym. Sci. \u2013 1999. \u2013 Vol. 138. \u2013 P. 107\u2013154.<br \/>\n5. Usuki A., Kawasumi M., Kojima Y. J. [et al.] \/\/ Mater. Res. \u2013 1993. \u2013 Vol. 8. \u2013 P. 1174\u20131182.<br \/>\n6. \u0421\u0432\u043e\u0439\u0441\u0442\u0432\u0430 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439 \/ \u041f\u043e\u0434. \u0440\u0435\u0434. \u0410.\u0410. \u041f\u043e\u0442\u0435\u0445\u0438\u043d\u0430, \u0441\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u0438\u043a.- \u041b.: \u0425\u0438\u043c\u0438\u044f, 1984. &#8211; 520 \u0441.<br \/>\n7. \u041f\u0430\u0442\u0435\u043d\u0442 \u0423\u043a\u0440\u0430\u0457\u043d\u0438 7346. \u041c\u041f\u041a7 \u041828 \u04213\/00, \u0421 01 \u0421\/18 \/ \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u043d\u044f \u043e\u0440\u0433\u0430\u043d\u0456\u0447\u043d\u043e \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u0448\u0430\u0440\u0443\u0432\u0430\u0442\u043e\u0433\u043e \u0441\u0438\u043b\u0456\u043a\u0430\u0442\u0443 \/ \u042e.\u0412. \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432, \u0412.\u0406. \u041b\u0438\u0442\u0432\u044f\u043a\u043e\u0432, \u0412.\u0413. \u0421\u0454\u0440\u043e\u0432. &#8211; \u041e\u043f\u0443\u0431\u043b. 25.11.08. \u0411\u044e\u043b. \u211622.<br \/>\n8. \u0413\u0440\u0438\u043c \u0420. \u041c\u0438\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0438\u044f \u0438 \u043f\u0440\u0430\u043a\u0442\u0438\u0447\u0435\u0441\u043a\u043e\u0435 \u0438\u0441\u043f\u043e\u043b\u044c\u0437\u043e\u0432\u0430\u043d\u0438\u0435 \u0433\u043b\u0438\u043d \/ \u041f\u0435\u0440. \u0441 \u0430\u043d\u0433\u043b. \u043f\u043e\u0434 \u0440\u0435\u0434. \u0412.\u041f. \u041f\u0435\u0442\u0440\u043e\u0432\u0430. &#8211; \u041c.: \u041c\u0438\u0440, 1967. &#8211; \u0421. 405.<br \/>\n9. \u0420\u043e\u0431\u043e\u0442\u0430 \u041b.\u041f., \u0421\u0430\u0432\u0435\u043b\u044c\u0435\u0432 \u042e.\u0412., \u041a\u0443\u0437\u044c\u043c\u0430\u043a \u041d.\u0410. \u0438 \u0434\u0440. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. &#8211; 2005.- \u21163. \u2013 C. 186-194.<br \/>\n10. \u0413\u041e\u0421\u0422 15139. \u041f\u043b\u0430\u0441\u0442\u043c\u0430\u0441\u0441\u044b. \u041c\u0435\u0442\u043e\u0434\u044b \u043e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u043f\u043b\u043e\u0442\u043d\u043e\u0441\u0442\u0438.<br \/>\n11. \u0413\u041e\u0421\u0422 14236. \u041f\u043b\u0435\u043d\u043a\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0435. \u041c\u0435\u0442\u043e\u0434 \u0438\u0441\u043f\u044b\u0442\u0430\u043d\u0438\u044f \u043d\u0430 \u0440\u0430\u0441\u0442\u044f\u0436\u0435\u043d\u0438\u0435.<br \/>\n12. \u0413 \u041e\u0421\u0422 22900. \u041a\u043e\u0436\u0430 \u0438\u0441\u043a\u0443\u0441\u0441\u0442\u0432\u0435\u043d\u043d\u0430\u044f \u0438 \u043f\u043b\u0435\u043d\u043e\u0447\u043d\u044b\u0435 \u043c\u0430\u0442\u0435\u0440\u0438\u0430\u043b\u044b. \u041c\u0435\u0442\u043e\u0434\u044b \u043e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u043f\u0430\u0440\u043e\u043f\u0440\u043e\u043d\u0438\u0446\u0430\u0435\u043c\u043e\u0441\u0442\u0438 \u0438 \u0432\u043b\u0430\u0433\u043e\u043f\u043e\u0433\u043b\u043e\u0449\u0435\u043d\u0438\u044f.<br \/>\n13. \u0413\u041e\u0421\u0422 4650. \u041f\u043b\u0430\u0441\u0442\u043c\u0430\u0441\u0441\u044b. \u041c\u0435\u0442\u043e\u0434\u044b \u043e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u0432\u043e\u0434\u043e\u043f\u043e\u0433\u043b\u043e\u0449\u0435\u043d\u0438\u044f.<br \/>\n14. \u0413\u0440\u0438\u043d\u044c\u0435 \u0410. \u0420\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0433\u0440\u0430\u0444\u0438\u044f \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u043e\u0432. \u0422\u0435\u043e\u0440\u0438\u044f \u0438 \u043f\u0440\u0430\u043a\u0442\u0438\u043a\u0430. &#8211; \u041c: \u0424\u0438\u0437\u043c\u0430\u0442\u0433\u0438\u0437, 1961. \u2013 604 \u0441.<br \/>\n15. Kim D.S., Lee K.M. \/\/ J. Appl. Polym. Sci. \u2013 2003. \u2013Vol. 90, N 10. \u2013 P. 2629-2633.<br \/>\n16. \u041d\u0430\u043a\u0430\u043d\u0438\u0441\u0438 \u041a. \u0418\u043d\u0444\u0440\u0430\u043a\u0440\u0430\u0441\u043d\u044b\u0435 \u0441\u043f\u0435\u043a\u0442\u0440\u044b \u0438 \u0441\u0442\u0440\u043e\u0435\u043d\u0438\u0435 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439, \u043f\u0440\u0438\u043a\u043b\u0430\u0434\u043d\u043e\u0435 \u0440\u0443\u043a\u043e\u0432\u043e\u0434\u0441\u0442\u0432\u043e. \u2013 \u041c.: \u041c\u0438\u0440, 1963. &#8211; \u0421. 583.<br \/>\n17. Ruland W. \/\/ J. Appl. Cryst. \u2013 1971. \u2013 4, N 1. \u2013 P. 70-73.<br \/>\n18. Perret R., Ruland W. \/\/ Kolloid Z. \u2013 Z. Polymere. Part B. \u20131971. \u2013 247, N 1. \u2013 S. 835-843.<br \/>\n19. Ruland W. \/\/ J. Appl. Cryst. \u2013 1971. \u2013 4, \u2116 1. \u2013 P. 70-73.<br \/>\n20. \u0428\u043b\u044f\u043f\u043d\u0438\u043a\u043e\u0432 \u042e.\u0410. \/\/ \u0423\u0441\u043f\u0435\u0445\u0438 \u0445\u0438\u043c\u0438\u0438. -1981. &#8211; 50, \u2116 6. &#8211; \u0421. 1105-1140.<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Properties and structure of composites, comprising organopilisized montmorillinite \u00a0 L.P. Robota, N.I. Parkhomenko, \u0410.N. Gonchar, V.I. Litvyakov, V.G. Sierov, V.I. Shtompel, G.M. Shumikova,\u00a0 Yu.V. Savelyev &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2014, 36, no. 4: 369-377. &nbsp; Section: Structure and properties. &nbsp; Language: Russian. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2080"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2080"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2080\/revisions"}],"predecessor-version":[{"id":2082,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2080\/revisions\/2082"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2080"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}