{"id":2092,"date":"2018-02-07T15:58:45","date_gmt":"2018-02-07T12:58:45","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2092"},"modified":"2018-02-07T15:58:45","modified_gmt":"2018-02-07T12:58:45","slug":"2014-4-8","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2014-4-8\/","title":{"rendered":"2014 (4) 8"},"content":{"rendered":"

Preparation and properties of (bio) degradable ionomeric polyurethanes based on xanthan<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

\u0422<\/em><\/strong>.V. Travinskaya, <\/em><\/strong>\u0410<\/em><\/strong>.N. Brykova, V.I. Bortnitsky, Yu.V. Savelyev<\/em><\/strong><\/p>\n

 <\/p>\n

Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine, travinskaya-tamara@rambler.ru<\/u><\/p>\n

 <\/p>\n

Polym. J., 2014, 36<\/strong>, no. 4: 393-400.<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Russian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

New potentially (bio)degradable environmentally friendly ionomeric polyurethanes (IPU) on the basis of oligomeric polyurethane (OPU) and xanthan (Xn) have been obtained. The influence of component composition on colloid-chemical and physic-mechanical properties of IPU \/ Xn and based films, as well as their changes under the influence of environmental factors has been studied. <\/em>\u0414\u043e\u043a\u0430\u0437\u0430\u043d\u043d\u043e\u0435 \u043d\u0430\u043b\u0438\u0447\u0438\u0435 \u043c\u0435\u0436\u0434\u0443 \u043a\u043e\u043c\u043f\u043e\u043d\u0435\u043d\u0442\u0430\u043c\u0438 \u043a\u0430\u043a \u043a\u043e\u0432\u0430\u043b\u0435\u043d\u0442\u043d\u043e\u0433\u043e, \u0442\u0430\u043a \u0438 \u0432\u043e\u0434\u043e\u0440\u043e\u0434\u043d\u043e\u0433\u043e \u0441\u0432\u044f\u0437\u044b\u0432\u0430\u043d\u0438\u044f \u043e\u0431\u0435\u0441\u043f\u0435\u0447\u0438\u0432\u0430\u0435\u0442 \u043f\u0440\u043e\u0442\u0435\u043a\u0430\u043d\u0438\u0435 \u0434\u0435\u0441\u0442\u0440\u0443\u043a\u0442\u0438\u0432\u043d\u044b\u0445 \u043f\u0440\u043e\u0446\u0435\u0441\u0441\u043e\u0432 \u0432\u0441\u0435\u0439 \u0441\u0438\u0441\u0442\u0435\u043c\u044b \u0432 \u0446\u0435\u043b\u043e\u043c. <\/em>Proven availability between components both covalent and hydrogen bonding provides proceeding of destructive processes of the whole system.<\/em> The infrared and pyrolytic mass spectrometry results have confirmed that introduction of Xn into OPU results in formation of new structural organization different from that of the original IPU (matrix), which is the result of chemical interaction between Xn and OPU. The data of acid, alkaline hydrolysis and ground incubation indicate that degradation processes in the IPU \/ Xn occur with greater intensity in comparison with the IPU matrix.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Keywords<\/strong>: ionomeric polyurethanes, xanthan, biodegradation.<\/p>\n

 <\/p>\n

\u041b\u0438\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

 <\/p>\n

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\n2. \u0420\u043e\u0433\u043e\u0432\u0438\u043d\u0430 \u0421.\u0417., \u0413\u0440\u0430\u0447\u0435\u0432 \u0410.\u0412., \u0410\u043b\u0435\u043a\u0441\u0430\u043d\u044f\u043d \u041a.\u0412., \u041f\u0440\u0443\u0442 \u042d.\u0412 \/\/. \u0425\u0438\u043c\u0438\u044f \u0440\u0430\u0441\u0442\u0438\u0442\u0435\u043b\u044c\u043d\u043e\u0433\u043e \u0441\u044b\u0440\u044c\u044f.- 2010. – \u21164. – \u0421. 45-50.
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\n4. \u0422\u0440\u0430\u0432\u0438\u043d\u0441\u043a\u0430\u044f \u0422.\u0412., \u041c\u0438\u0449\u0443\u043a \u0415.\u0410., \u0420\u043e\u0431\u043e\u0442\u0430 \u041b.\u041f., \u0421\u0430\u0432\u0435\u043b\u044c- \u0435\u0432 \u042e.\u0412. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2010. \u2013 32, \u2116 4. \u2013 \u0421. 362\u2013366.
\n5. \u0428\u0442\u043e\u043c\u043f\u0435\u043b\u044c \u0412.\u0406., \u041c\u0456\u0449\u0443\u043a \u041e.\u0410., \u0422\u0440\u0430\u0432\u0456\u043d\u0441\u044c\u043a\u0430 \u0422.\u0412., \u0421\u0430\u0432\u0435\u043b\u044c-\u0454\u0432 \u042e.\u0412. \/\/ \u0412\u0456\u0441\u043d. \u041a\u0438\u0457\u0432\u0441\u044c\u043a. \u043d\u0430\u0446. \u0443\u043d-\u0442\u0443 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0439 \u0442\u0430 \u0434\u0438\u0437\u0430\u0439\u043d\u0443. – 2010. – \u2116 4. – \u0421. 148-1540.
\n6. \u041f\u0430\u0442. 51301 \u0423\u043a\u0440\u0430\u0457\u043d\u0430 \u041c\u041f\u041a8 C 08 J 3\/02, C 08 G 18\/10, C 08 L 3\/00. \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e\u0457 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0457 \/ \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432 \u042e. \u0412., \u041c\u0456\u0449\u0443\u043a \u041e. \u0410., \u041c\u0430\u0440\u043a\u043e\u0432\u0441\u044c\u043a\u0430 \u041b. \u0410., \u0422\u0440\u0430\u0432\u0456\u043d\u0441\u044c\u043a\u0430 \u0422. \u0412. \u2013 \u041e\u043f\u0443\u0431\u043b. 12.07.10. – \u0411\u044e\u043b. \u2116 13.
\n7. \u041d\u0456\u0437\u0435\u043b\u044c\u0441\u043a\u0438\u0439 \u042e.\u041c., \u041a\u043e\u0437\u0430\u043a \u041d.\u0412., \u0413\u0443\u0431\u0456\u043d\u0430 \u0410.\u0412., \u041d\u0435\u0441\u0442\u043e\u0440\u0435\u043d\u043a\u043e \u0413.\u041c., \u0413\u0432\u043e\u0437\u0434\u044f\u043a \u0417.\u0418., \u0412\u043e\u0446\u0435\u043b\u043a\u043e \u0421.\u041a. \/\/ \u041c\u0430\u043f\u0441\u0442\u0435\u0440\u0456\u0443\u043c. \u0425\u0456\u043c\u0456\u0447\u043d\u0456 \u043d\u0430\u0443\u043a\u0438. \u0412\u0438\u043f. 24. – 2006. – \u0421. 58-64.
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\n9. \u041f\u0430\u0442. 93372 \u0423\u043a\u0440\u0430\u0438\u043d\u0430, \u041c\u041f\u041a51 C08J 3\/02, C08G 18\/10, C08L 5\/00 \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e\u0457 \u0431\u0456\u043e\u0434\u0435\u0441\u0442\u0440\u0443\u043a\u0442\u0443\u044e\u0447\u043e\u0457 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0457\/ \u0421\u0430\u0432\u0435\u043b\u044c\u0454\u0432 \u042e.\u0412., \u0422\u0440\u0430\u0432\u0456\u043d\u0441\u044c\u043a\u0430 \u0422.\u0412., \u041c\u0430\u0440\u043a\u043e\u0432-\u0441\u044c\u043a\u0430 \u041b.\u0410., \u0411\u0440\u0438\u043a\u043e\u0432\u0430 \u041e.\u041c. \u2013 \u041e\u043f\u0443\u0431\u043b. 25.09.2014. – \u0411\u044e\u043b. \u2116 18.
\n10. ISO 976: 1996 \u041a\u0430\u0443\u0447\u0443\u043a \u0438 \u043f\u043b\u0430\u0441\u0442\u043c\u0430\u0441\u0441\u044b. \u0414\u0438\u0441\u043f\u0435\u0440\u0441\u0438\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432 \u0438 \u043a\u0430\u0443\u0447\u0443\u043a\u043e\u0432\u044b\u0435 \u043b\u0430\u0442\u0435\u043a\u0441\u044b. \u041e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u0435 pH.
\n11. \u0429\u0435\u0433\u043e\u043b\u0435\u0432 \u0421.\u0410., \u041a\u043b\u0435\u043d\u0438\u043d \u0412.\u0418. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0411. \u2013 1971. \u2013 13, \u2116 12. \u2013 \u0421. 2809\u20132815.
\n12. \u0413\u041e\u0421\u0422 14236-81 \u041f\u043b\u0435\u043d\u043a\u0438 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043d\u044b\u0435. \u041c\u0435\u0442\u043e\u0434 \u0438\u0441\u043f\u044b\u0442\u0430\u043d\u0438\u044f \u043d\u0430 \u0440\u0430\u0441\u0442\u044f\u0436\u0435\u043d\u0438\u0435.
\n13. \u0413\u041e\u0421\u0422 4650-80 \u041f\u043b\u0430\u0441\u0442\u043c\u0430\u0441\u0441\u044b. \u041c\u0435\u0442\u043e\u0434 \u043e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u0432\u043e\u0434\u043e\u043f\u043e\u0433\u043b\u043e\u0449\u0435\u043d\u0438\u044f.
\n14. \u0412\u0430\u0442\u0443\u043b\u0435\u0432 \u0412.\u041d., \u041b\u0430\u043f\u0442\u0438\u0439 \u0421.\u0412., \u041a\u0435\u0440\u0447\u0430 \u042e.\u042e. \u0418\u043d\u0444\u0440\u0430\u043a\u0440\u0430\u0441\u043d\u044b\u0435 \u0441\u043f\u0435\u043a\u0442\u0440\u044b \u0438 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0430 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432. \u2013 \u041a\u0438\u0435\u0432: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1987. \u2013 188\u0441.
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\n16. \u0415\u0440\u043c\u043e\u043b\u043e\u0432\u0438\u0447 \u041e.\u0410., \u041c\u0430\u043a\u0430\u0440\u0435\u0432\u0438\u0447 \u0410.\u0412., \u0413\u043e\u043d\u0447\u0430\u0440\u043e\u0432\u0430 \u0415.\u041f. \/\/ \u0411\u0438\u043e\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u044f. \u2013 2005. \u2013 \u2116 4. \u2013 \u0421. 47\u201354.
\n17. \u0411\u0430\u0431\u044c\u0435\u0432\u0430 \u0418.\u041f., \u0417\u0435\u043d\u043e\u0432\u0430 \u0413.\u041c. \u0411\u0438\u043e\u043b\u043e\u0433\u0438\u044f \u043f\u043e\u0447\u0432. \u2013 \u041c.: \u0418\u0437\u0434-\u0432\u043e \u041c\u043e\u0441\u043a. \u0443\u043d-\u0442\u0430, 1989. \u2013 \u0421. 320.
\n18. \u0417\u0430\u0438\u043a\u0438\u043d \u0412.\u0410. \u041c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u0441\u043a\u043e\u043f\u0438\u044f \u0441\u0438\u043d\u0442\u0435\u0442\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u043e\u0432. \u2013 \u041c.: \u0418\u0437\u0434-\u0432\u043e \u0412\u0441\u0435\u0440\u043e\u0441. \u043c\u0430\u0441\u0441-\u0441\u043f\u0435\u043a\u0442\u0440\u043e\u043c\u0435\u0442\u0440\u0438\u0447. \u043e\u0431\u0449-\u0432\u0430, 2009. \u2013 332 \u0441.
\n19. \u0411\u043e\u0439\u043a\u043e \u0412.\u0412, \u041a\u043e\u0431\u0440\u0438\u043d\u0430 \u041b.\u0412., \u0420\u044f\u0431\u043e\u0432 \u0421.\u0412., \u0413\u0430\u0439\u0434\u0443\u043a \u0420.\u041b.\/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2004. \u2013 26, \u2116 4. – \u0421. 235-238.<\/p>\n

 <\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

Preparation and properties of (bio) degradable ionomeric polyurethanes based on xanthan \u00a0 \u0422.V. Travinskaya, \u0410.N. Brykova, V.I. Bortnitsky, Yu.V. Savelyev   Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine, travinskaya-tamara@rambler.ru   Polym. J., 2014, 36, no. 4: 393-400.   Section: Structure and properties.   Language: Russian.   Abstract: New potentially […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2092"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2092"}],"version-history":[{"count":1,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2092\/revisions"}],"predecessor-version":[{"id":2093,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2092\/revisions\/2093"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2092"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}