{"id":2098,"date":"2018-02-07T16:06:57","date_gmt":"2018-02-07T13:06:57","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2098"},"modified":"2018-02-07T16:06:57","modified_gmt":"2018-02-07T13:06:57","slug":"2014-4-10","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2014-4-10\/","title":{"rendered":"2014 (4) 10"},"content":{"rendered":"

Sens<\/strong>\u043e<\/strong>r system based on molecular imprinted polymers with catalytic properties to determination o<\/em>-hydroxyphenol in the environment<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

T.<\/em><\/strong>\u0410<\/em><\/strong>. Sergeyeva<\/em><\/strong>1<\/em><\/strong>, L.A. Gorbach<\/em><\/strong>2<\/em><\/strong>, <\/em><\/strong>\u041e<\/em><\/strong>.D. Lutsyk<\/em><\/strong>2 <\/em><\/strong>, <\/em><\/strong>\u041e<\/em><\/strong>.O. Brovko<\/em><\/strong>2<\/em><\/strong>, L.M. Sergeeva<\/em><\/strong>2<\/em><\/strong>, G.V. Elska<\/em><\/strong>1<\/em><\/strong><\/p>\n

 <\/p>\n

1Institute of Molecular Biology and Genetics NAS of Ukraine<\/p>\n

150, Zabolotnogo str., Kyiv, 03680, Ukraine<\/p>\n

2Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

 <\/p>\n

Polym. J., 2014, 36<\/strong>, no. 4: 406-412.<\/p>\n

 <\/p>\n

Section: Synthesis polymers.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

Organic polymers-biomimicks, containing catalytic sites in their structure, which mimic mushroom tyrosinase active sites, that are capable of highly-selective recognition of o-hydroxyphenols were synthesized according to the technique of molecular imprinting. Biosensor devices for o-hydroxyphenols detection in environmental samples were developed on their basis. The methodology of calibration of the laboratory prototype of the biosensor based on tyrosinase mimicks for the detection of\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0o-hydroxyphenols in natural and waste waters was developed. Comparison of data of the biosensor analysis and traditional HPLC method was made. Real samples of river water were analyzed as for\u00a0\u00a0\u00a0\u00a0\u00a0 o-hydroxyphenol content using developed biosensor. The protocol for the determination of\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 o-hydroxyphenol concentration in real samples was worked out. As compared to traditional analytical methods of o-hydroxyphenol detection the proposed biosensor method is more effective from the point of view of simplicity of operation, as well as cost and size of equipment.<\/em><\/p>\n

\u00a0<\/strong><\/p>\n

Keywords: <\/strong>molecular imprinted polymers, binding sites, portable biosensors, <\/strong>o<\/em>-hydroxyphenols.<\/p>\n

 <\/p>\n

\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

 <\/p>\n

1. Dangerouns Properties of Industrial Materials \/ Ed. By N.J. Sax. \u2013 New York: VNR Company, 1984. – 3124 p.
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\n9. \u0421\u0435\u0440\u0433\u0435\u0454\u0432\u0430 \u0422.\u0410., \u0421\u043b\u0456\u043d\u0447\u0435\u043d\u043a\u043e \u041e.\u0410., \u0411\u0440\u043e\u0432\u043a\u043e \u041e.\u041e., \u041f\u0456\u043b\u0435\u0446\u044c\u043a\u0438\u0439 \u0421.\u0410., \u0404\u043b\u044c\u0441\u044c\u043a\u0430 \u0413.\u0412. \/\/ \u0423\u043a\u0440. \u0431\u0456\u043e\u0445\u0456\u043c. \u0436\u0443\u0440\u043d. \u2013 2009. \u2013 81, \u2116 1. \u2013 \u0421. 20\u201330.
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 <\/p>\n

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Sens\u043er system based on molecular imprinted polymers with catalytic properties to determination o-hydroxyphenol in the environment \u00a0 T.\u0410. Sergeyeva1, L.A. Gorbach2, \u041e.D. Lutsyk2 , \u041e.O. Brovko2, L.M. Sergeeva2, G.V. Elska1   1Institute of Molecular Biology and Genetics NAS of Ukraine 150, Zabolotnogo str., Kyiv, 03680, Ukraine 2Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2098"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2098"}],"version-history":[{"count":1,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2098\/revisions"}],"predecessor-version":[{"id":2099,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2098\/revisions\/2099"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2098"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}