{"id":2108,"date":"2018-02-07T16:20:27","date_gmt":"2018-02-07T13:20:27","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2108"},"modified":"2018-02-07T16:20:27","modified_gmt":"2018-02-07T13:20:27","slug":"2014-4-13","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2014-4-13\/","title":{"rendered":"2014 (4) 13"},"content":{"rendered":"<p><strong>Study the influence of model biological medium on structure and properties of epoxy-polyurethane composite materials, filled by ferrocene<\/strong><\/p>\n<p><strong><em>\u00a0<\/em><\/strong><\/p>\n<p><strong><em>T.V. Rudenchyk, R.A. Roznova, V.I. Shtompel, V.V. Davidenko, N.A. Galatenko<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n<p>48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2014, <strong>36<\/strong>, no. 4: 424-433.<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Medecine polymers.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p><em>The influence of model biological medium on the structure and properties of epoxy-polyurethane (EPU) composite materials with ferrocene is investigated. Established that the incubation EPU composite materials in model biological medium is accompanied by loss of the samples due to the biodegradation of the polyurethane component and release of ferrocene. According to the IR-spectroscopic studies biodegradation occurs by ester and to a greater extent eterna linkages with simultaneous redistribution of hydrogen bonds system, which is associated with structuring polymer compositions in model biological medium 199 (BM 199). Established that the increase T<\/em><em>g<\/em><em>\u00a0and decrease the heat capacity jump during the glass transition samples of EPU filled by ferrocene after their incubation in model medium testifies about release of ferrocene from the polymer matrix, as well as during the time of processes of segregation rigid and flexible blocks of polyurethane component compositions.<\/em><\/p>\n<p><em>\u00a0<\/em><\/p>\n<p><strong>Key words: <\/strong>epoxy-polyurethane, composite materials, ferrocene, biodegradation, biological medium 199.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1. \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410., \u041a\u0443\u043a\u0441i\u043d \u0410.\u041c., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410, \u0410\u0441\u0442\u0430\u043f\u0435\u043d\u043a\u043e \u041e.\u041e. \/\/ \u0414\u043e\u043f. \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 2007. \u2013 \u2116 3. \u2013 \u0421. 142-148.<br \/>\n2. \u0414\u0435\u043a\u043b. \u043f\u0430\u0442. 13318 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a8 \u042109\u041a 3\/32. \u041f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0439 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0439\u043d\u0438\u0439 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \u0434\u043b\u044f \u043f\u043b\u0430\u0441\u0442\u0438\u043a\u0438 \u043a\u0456\u0441\u0442\u043a\u043e\u0432\u0438\u0445 \u0442\u043a\u0430\u043d\u0438\u043d \/ \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410., \u041a\u0443\u043a\u0441i\u043d \u0410.\u041c., \u0410\u0441\u0442\u0430\u043f\u0435\u043d\u043a\u043e \u041e.\u041e., \u0420\u043e\u0436\u043d\u043e-\u0432\u0430 \u0420.\u0410. \u2013 \u041e\u043f\u0443\u0431\u043b. 15.03.2006. \u2013 \u0411\u044e\u043b. \u2116 3.<br \/>\n3. \u041f\u0430\u0442. 79557 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a8 \u04212, \u0421 08J 3\/20. \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e\u0433\u043e \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0439\u043d\u043e\u0433\u043e \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0443 \/ \u041a\u0443\u043a\u0441i\u043d \u0410.\u041c., \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0410\u0441\u0442\u0430\u043f\u0435\u043d- \u043a\u043e \u041e.\u041e. \u2013 \u041e\u043f\u0443\u0431\u043b. 25.06.2007. \u2013 \u0411\u044e\u043b. \u2116 9.<br \/>\n4. \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410., \u041a\u0443\u043a\u0441i\u043d \u0410.\u041c., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0410\u0441\u0442\u0430\u043f\u0435\u043d\u043a\u043e \u041e.\u041e. \/\/ \u041f\u043e\u043bi\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2008. \u2013 30, \u2116 2. \u2013 \u0421. 169\u2013173.<br \/>\n5. \u041f\u0430\u0442. 59922 \u0423\u043a\u0440\u0430\u0457\u043d\u0430, \u041c\u041f\u041a8 \u042108L 63\/02, C08L 75\/04, A61F 2\/18, A61K 31\/00. \u041f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0439 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u0439\u043d\u0438\u0439 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \u0434\u043b\u044f \u043e\u0441\u0442\u0435\u043e\u0441\u0438\u043d\u0442\u0435\u0437\u0443 \/ \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0413\u043e\u0440\u0431\u0443\u043d\u043e\u0432\u0430 \u041d.\u041e. \u2013 \u041e\u043f\u0443\u0431\u043b. 10.06.2011. \u2013 \u0411\u044e\u043b. \u2116 11.<br \/>\n6. \u0420\u0443\u0434\u0435\u043d\u0447\u0438\u043a \u0422.\u0412., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0414\u0430\u0432\u0438\u0434\u0435\u043d\u043a\u043e \u0412.\u0412., \u0414\u0435\u043c\u0447\u0435\u043d\u043a\u043e \u0406.\u0411. \/\/ \u041f\u043e\u043b\u0456\u043c\u0435\u0440. \u0436\u0443\u0440\u043d. \u2013 2012. \u2013 34, \u2116 5. \u2013 \u0421. 437-443.<br \/>\n7. \u0420\u0443\u0434\u0435\u043d\u0447\u0438\u043a \u0422.\u0412., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u041a\u0443\u043b\u0454\u0448 \u0414.\u0412., \u0414\u0435\u043c\u0447\u0435\u043d- \u043a\u043e \u0406.\u0411., \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410. \/\/ \u041f\u043b\u0430\u0441\u0442\u0438\u0447\u043d\u0430 \u0442\u0430 \u0440\u0435\u043a\u043e\u043d\u0441\u0442\u0440\u0443\u043a\u0442\u0438\u0432\u043d\u0430 \u0445\u0456\u0440\u0443\u0440\u0433\u0456\u044f. \u2013 2012. \u2013 19, \u2116 2. \u2013 \u0421. 53-59.<br \/>\n8. \u041f\u0445\u0430\u043a\u0430\u0434\u0437\u0435 \u0413.\u0410. \u0411\u0438\u043e\u0434\u0435\u0441\u0442\u0440\u0443\u043a\u0442\u0438\u0440\u0443\u0435\u043c\u044b\u0435 \u043f\u043e\u043b\u0438\u043c\u0435\u0440\u044b. \u2013 \u041a\u0438\u0435\u0432: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 1990. \u2013 160 \u0441.<br \/>\n9. \u0412\u0438\u043b\u043b\u0438 \u041a. \u0411\u0438\u043e\u043b\u043e\u0433\u0438\u044f. \u2013 \u041c\u043e\u0441\u043a\u0432\u0430: \u041c\u0438\u0440, 1962. \u2013 678 \u0441.<br \/>\n10. \u0411\u0435\u043b\u043b\u0430\u043c\u0438 \u041b. \u0418\u043d\u0444\u0440\u0430\u043a\u0440\u0430\u0441\u043d\u044b\u0435 \u0441\u043f\u0435\u043a\u0442\u0440\u044b \u0441\u043b\u043e\u0436\u043d\u044b\u0445 \u043c\u043e\u043b\u0435\u043a\u0443\u043b. \u2013 \u041c\u043e\u0441\u043a\u0432\u0430: \u0418\u0437\u0434-\u0432\u043e \u0438\u043d\u043e\u0441\u0442\u0440. \u043b-\u0440\u044b, 1957. \u2013 444 \u0441.<br \/>\n11. Kratky O., Pilz I., Schmitz P. J. \/\/ Colloid Interface Sci. \u2013 1966. \u2013 21, \u2116 1. \u2013 P. 24-34.<br \/>\n12. Flory P. Principles of Polymer Chemistry. \u2013 Ithaca. N.Y.: Cornell University Press, 1953.<br \/>\n13. \u041f\u0445\u0430\u043a\u0430\u0434\u0437\u0435 \u0413.\u041e., \u0421\u043d\u0454\u0433\u0456\u0440\u044c\u043e\u0432 \u041e.\u0412. \/\/ \u0412\u0456\u0441\u043d\u0438\u043a \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438. \u2013 1987. \u2013 \u21162. \u2013 \u0421. 17-22.<br \/>\n14. \u0411\u043e\u043d\u0434\u0430\u0440\u0435\u043d\u043a\u043e \u041f.\u0410., \u0420\u0443\u0434\u0435\u043d\u0447\u0438\u043a \u0422.\u0412., \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410. \/\/ \u041f\u043b\u0430\u0441\u0442. \u043c\u0430\u0441\u0441\u044b. \u2013 2012. \u2013 \u2116 12. \u2013 \u0421. 35-38.<br \/>\n15. \u0421\u043b\u0438\u0432\u043a\u0438\u043d \u0410.\u0418. \u0424\u0443\u043d\u043a\u0446\u0438\u043e\u043d\u0430\u043b\u044c\u043d\u044b\u0439 \u0430\u043d\u0430\u043b\u0438\u0437 \u043e\u0440\u0433\u0430\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043b\u0435\u043a\u0430\u0440\u0441\u0442\u0432\u0435\u043d\u043d\u044b\u0445 \u0432\u0435\u0449\u0435\u0441\u0442\u0432. \u2013 \u0412\u043e\u0440\u043e\u043d\u0435\u0436: \u0412\u043e\u0440\u043e\u043d\u0435\u0436\u0441\u043a\u0438\u0439 \u0433\u043e\u0441. \u0443\u043d-\u0442, 2007. \u2013 426 \u0441.<br \/>\n16. \u0424\u0440\u0438\u0437\u0435\u043d \u0410.\u041a., \u0425\u0443\u0440\u0441\u0430\u043d \u0421.\u041b. \/\/ \u0411\u0430\u0448\u043a\u0438\u0440\u0441\u043a\u0438\u0439 \u0445\u0438\u043c. \u0436\u0443\u0440\u043d. \u2013 2006. \u2013 13, \u2116 1. \u2013 \u0421. 111-112.<br \/>\n17. \u0424\u0440\u0438\u0437\u0435\u043d \u0410.\u041a., \u0425\u0443\u0440\u0441\u0430\u043d \u0421.\u041b. \/\/ \u0412\u0435\u0441\u0442\u043d\u0438\u043a \u0411\u0430\u0448\u043a\u0438\u0440\u0441\u043a\u043e\u0433\u043e \u0443\u043d-\u0442\u0430. \u2013 2008. \u2013 13, \u2116 4. \u2013 \u0421. 903-906.<br \/>\n18. \u0428\u0442\u043e\u043c\u043f\u0435\u043b\u044c \u0412.\u0418., \u041a\u0435\u0440\u0447\u0430 \u042e.\u042e. \u0421\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0430 \u043b\u0438\u043d\u0435\u0439\u043d\u044b\u0445 \u043f\u043e\u043b\u0438\u0443\u0440\u0435\u0442\u0430\u043d\u043e\u0432. \u2013 \u041a\u0438\u0435\u0432: \u041d\u0430\u0443\u043a. \u0434\u0443\u043c\u043a\u0430, 2008. \u2013 247 \u0441.<br \/>\n19. \u0420\u043e\u0436\u043d\u043e\u0432\u0430 \u0420.\u0410., \u0420\u0443\u0434\u0435\u043d\u0447\u0438\u043a \u0422.\u0412., \u0414\u0430\u0432\u0438\u0434\u0435\u043d\u043a\u043e \u0412.\u0412., \u0411\u043e\u043d\u0434\u0430\u0440\u0435\u043d\u043a\u043e \u041f.\u0410., \u0413\u0430\u043b\u0430\u0442\u0435\u043d\u043a\u043e \u041d.\u0410. \/\/ \u0412\u044b\u0441\u043e\u043a\u043e\u043c\u043e\u043b\u0435\u043a\u0443\u043b\u044f\u0440. \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u044f. \u0421\u0435\u0440. \u0410. \u2013 2014. \u2013 56, \u2116 3. \u2013 \u0421. 296-303.<br \/>\n20. Perret R., Ruland W. \/\/ Kolloid Z. \u2013 Z. Polymere. \u2013 1971. \u2013 247, \u2116 1-2. \u2013 P. 835-843.<br \/>\n21. Ruland W. \/\/ J. Appl. Cryst. \u2013 1971. \u2013 4, \u2116 1. \u2013 P. 70-73.<br \/>\n22. \u0413\u0438\u043d\u044c\u0435 \u0410. \u0420\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0433\u0440\u0430\u0444\u0438\u044f \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u043e\u0432. \u0422\u0435\u043e\u0440\u0438\u044f \u0438 \u043f\u0440\u0430\u043a\u0442\u0438\u043a\u0430. \u2013 \u041c\u043e\u0441\u043a\u0432\u0430: \u0424\u0438\u0437\u043c\u0430\u0442\u0433\u0438\u0437, 1961. \u2013 604 \u0441.<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Study the influence of model biological medium on structure and properties of epoxy-polyurethane composite materials, filled by ferrocene \u00a0 T.V. Rudenchyk, R.A. Roznova, V.I. Shtompel, V.V. Davidenko, N.A. Galatenko &nbsp; Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine &nbsp; Polym. J., 2014, 36, no. 4: 424-433. &nbsp; Section: Medecine polymers. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2108"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2108"}],"version-history":[{"count":1,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2108\/revisions"}],"predecessor-version":[{"id":2109,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2108\/revisions\/2109"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2108"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}