{"id":2375,"date":"2018-08-31T16:01:14","date_gmt":"2018-08-31T13:01:14","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2375"},"modified":"2018-08-31T16:02:09","modified_gmt":"2018-08-31T13:02:09","slug":"2018-2-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2018-2-5\/","title":{"rendered":"2018 (2) 5"},"content":{"rendered":"

The influence of quantity and nature of bortitan-containing modifier on the properties of the alkyd protective coatings<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

S.N. Kuzmenko, N.Ya. Kuzmenko, N.N. Laskovenko, V.A. Gumenyuk<\/em><\/strong><\/p>\n

 <\/p>\n

1DVNZ \u201cUkrainian State Technological University\u201d<\/p>\n

8, Gagarin Avenue, Dnipro, 49005, Ukraine<\/p>\n

2Institute of Macromolecular Chemistry NAS of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

 <\/p>\n

Polym. J., 2018, 40<\/strong>, no. 2: 106-112<\/p>\n

 <\/p>\n

Section: Structure and properties.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

 <\/p>\n

The results of studies of the effect of the amount and nature of tris [tri (butoxy) titanoxy] borane and the products of its transesterification degree with stearic acid on the properties of protective films based on PF-060 varnish are presented. It has been shown that the modification of alkyd lacquer by the products of esterification of tris [tri (butoxy) titanoxyl] boron stearic acid makes it possible to significantly increase the strength of films by breaking, practically twice their resistance at 500 \u00b0C to water; 20% H2SO4 solution; 4% NaCl solution. Such a positive effect is possible for a set of inactivation in the structure of a polymer film based on the alkyd oligomer of hydrophilic carboxyl and hydroxyl groups, which is also confirmed by an increase in the contact angle of the films.<\/em><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

Key words:<\/strong> alkyd resins, varnishes, sealants, enamels, protective coatings, modifier, tris [tri (butoxy) titanoxy] borane and its transesterification products with stearic acid.<\/p>\n

 <\/p>\n

References<\/strong><\/p>\n

 <\/p>\n

1. M.M. Goldberh v kn.: Materialyi dlya lakokrasochnyih pokryitiy. M.: Himiya, 1972, 344 p. (p.10).
\n2. M.Ya. Kuzmenko, M.V. Burmyistr, Yu.M. Kobelchuk v kn. Tekhnolohiia vyrobnytstva ta pereroblennia vysokomolekuliarnykh spoluk (kn. 2 Syntetychni smoly ta polimery, m. Dnipropetrovsk: DVNZ \u00abUDKhTU\u00bb, 2015, 489 p. (p. 221).
\n3. M.Ya. Kuzmenko, S.M. Kuzmenko, O.V. Skrinnik, D.M. Marchenko, O.O. Kolomiets, Sintez i fiziko, himicheskie svoystva [(butoksi)(stearatatsiloksi)titanoksi]boranov, M.: Izv. VUZov RF. Ser. \u00ab Himiya i himicheskaya tehnologiya:, 2015, v. 58, no.9: 10\u201314.
\n4. A. Adamson. Fizicheskaya himiya, A. Adamson: per. s angl. G. Abidora. M.: Mir, 1979, 568 p.
\n5. M.Ya. Kuzmenko, S.M. Kuzmenko, A.V. Hrybenko, Vplyv pryrody i kilkosti tytan, ta tytanborvmisnoho modyfikatoru na mitsnist karbamidoformaldehidnoho polimeru., m. Dnipro: DVNZ \u00abUDKhTU\u00bb. \u00abVoprosyi himii i himicheskoy tehnologii\u00bb, 2017, no.5 (114): 36-41.<\/p>\n","protected":false},"excerpt":{"rendered":"

The influence of quantity and nature of bortitan-containing modifier on the properties of the alkyd protective coatings \u00a0 S.N. Kuzmenko, N.Ya. Kuzmenko, N.N. Laskovenko, V.A. Gumenyuk   1DVNZ \u201cUkrainian State Technological University\u201d 8, Gagarin Avenue, Dnipro, 49005, Ukraine 2Institute of Macromolecular Chemistry NAS of Ukraine 48, Kharkivske shose, Kyiv, 02160, Ukraine   Polym. J., 2018, […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2375"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2375"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2375\/revisions"}],"predecessor-version":[{"id":2377,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2375\/revisions\/2377"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2375"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}