{"id":2446,"date":"2018-10-25T19:11:52","date_gmt":"2018-10-25T16:11:52","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2446"},"modified":"2019-01-22T13:32:39","modified_gmt":"2019-01-22T10:32:39","slug":"2018-3-1","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2018-3-1\/","title":{"rendered":"2018 (3) 1"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.40.03.141\">https:\/\/doi.org\/10.15407\/polymerj.40.03.141<\/a><\/p>\n<p><strong>Cyclodextrin-containing polymers: synthesis and use<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong><em>S.V. Riabov, V.V. Boyko, L.V. Kobrina<\/em><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>Institute of Macromolecular Chemistry, National Academy of Science of Ukraine<\/p>\n<p>48, Kharkivske schose, 02160 Kyiv, Ukraine<\/p>\n<p>&nbsp;<\/p>\n<p>Polym. J., 2018, <strong>40<\/strong>, no. 3: 141-154<\/p>\n<p>&nbsp;<\/p>\n<p>Section: Review.<\/p>\n<p>&nbsp;<\/p>\n<p>Language: Ukrainian.<\/p>\n<p>&nbsp;<\/p>\n<p>Abstract:<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p style=\"padding-left: 90px;\"><em>A review of the main methods for obtaining polymers and polymer systems of various structures based on or using cyclodextrins (CDs) has been given. Unique structural features of CDs, namely the separation of hydrophilic and hydrophobic groups, cause unusual physical and chemical properties of these molecules. The most important property of natural or chemically modified CDs is the ability to reversibly and selectively bind organic, inorganic, and biological molecules, forming inclusion complexes (ICs) of the \u201cguest\u2013host\u201d type. Such systems are interesting in that, on the one hand, a process of incorporation into the CDs cavity of the molecule &#8211; the \u201cguest\u201d, and on the other hand &#8211; the retention of the substrate by the proper polymer network formed by the macrocycles of the CD is possible. Due to such properties, cyclodextrin-containing polymers are of interest both from the scientific (the study of various model interactions) and from the practical points of view.The most interesting examples of the application of ICs with CDs in pharmaceutical, food, and chemical industry, spectrometric analysis, separation technologies, of the use of CDs as models for molecular recognition in biology are given in the review. The mechanism and methods of the formation of ICs, their properties and the methods of analysis have been described. Particular attention has been paid to cyclodextrin-containing polymers. The review gives examples of the use of CDs and their derivatives as prepolymers for the development of a wide range of polymer networks and complexes. One of the new promising directions of the application of CDs, namely, the preparation of nanosized materials, has been considered.<\/em><\/p>\n<p>&nbsp;<\/p>\n<p><strong>Key words:<\/strong> cyclodextrins (CD), complex, polymers, sorbents, catalysts.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>References<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>1. Lenn J.-M. Supramolecular chemistry: Concepts and perspectives. Novosibirsk: Science, 1998: 334. ISBN5-02-031603-2.<br \/>\n2. Atwood J.L., Gokel G.W., BarbourL.J., editors. Comprehensive Supramolecular chemistry.Vol.1. Amsterdam: Elsevier Ltd, 2017:495. ISBN978-0-12-803198-8.<br \/>\n3. Schneider H.J. Applications of supramolecular chemistry. Boca Raton: CRC Press, 2012: 454. ISBN 978-1-4398-4014-6. https:\/\/doi.org\/10.1201\/b11798<br \/>\n4. Kurkov S.V., Loftsson T. Cyclodextrins. 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Polymer-Plastics Technology and Engineering. 2018, 57, no. 9: 836\u2013849. https:\/\/doi.org\/10.1080\/03602559.2017.1354224<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.40.03.141 Cyclodextrin-containing polymers: synthesis and use &nbsp; S.V. Riabov, V.V. Boyko, L.V. Kobrina &nbsp; Institute of Macromolecular Chemistry, National Academy of Science of Ukraine 48, Kharkivske schose, 02160 Kyiv, Ukraine &nbsp; Polym. J., 2018, 40, no. 3: 141-154 &nbsp; Section: Review. &nbsp; Language: Ukrainian. &nbsp; Abstract: &nbsp; &nbsp; A review of the main methods for [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2446"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2446"}],"version-history":[{"count":3,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2446\/revisions"}],"predecessor-version":[{"id":2530,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2446\/revisions\/2530"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2446"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}