{"id":2465,"date":"2018-10-25T19:56:08","date_gmt":"2018-10-25T16:56:08","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/en\/?page_id=2465"},"modified":"2019-01-22T13:53:13","modified_gmt":"2019-01-22T10:53:13","slug":"2018-3-7","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2018-3-7\/","title":{"rendered":"2018 (3) 7"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.40.03.190<\/a><\/p>\n

Synthesis of the power of (alkoxy) (acyloxy) titanates on the basis of the sum of monocarboxylic acids of sonyashnikovoy <\/strong>\u0430<\/strong>nd llyanoi olii<\/strong><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

N.Ya. Kuzmenko<\/em><\/strong>1<\/em><\/strong>, S.N. Kuzmenko<\/em><\/strong>1<\/em><\/strong>, N.N. Laskovenko<\/em><\/strong>1<\/em><\/strong>, T.Yu. Kolyada<\/em><\/strong>1<\/em><\/strong>, G.O. Pashkinkina<\/em><\/strong>1<\/em><\/strong>, A.O. Stogniy<\/em><\/strong>1<\/em><\/strong><\/p>\n

 <\/p>\n

1DVNZ \u201cUkrainian State Technological University\u201d<\/p>\n

8, Gagarin Avenue, Dnipro, 49005, Ukraine<\/p>\n

2Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine<\/p>\n

48, Kharkivske shose, Kyiv, 02160, Ukraine<\/p>\n

 <\/p>\n

Polym. J., 2018, 40<\/strong>, no. 3: 190-194<\/p>\n

 <\/p>\n

Section: Synthesis polymers.<\/p>\n

 <\/p>\n

Language: Ukrainian.<\/p>\n

 <\/p>\n

Abstract:<\/p>\n

 <\/p>\n

\u00a0<\/em><\/p>\n

The reaction of transesterification of tetrabutoxytitanate with a mixture of monocarboxylic acids of sunflower or linseed oil were synthesized by the corresponding (alkoxy)(acyloxy)titanates. They are, for the most part, solid at room temperature a light-yellow-brown color shade that is well soluble in aliphatic, aromatic, chloroaromatic, chlorinated hydrocarbons, and lower alcohols.<\/em><\/p>\n

Their structure is confirmed by elemental, functional analysis, molecular weights, infrared spectra.<\/em><\/p>\n

\u00a0These compounds, which contain reactive butoxy groups in the titanium atom and the monocarboxylic acid residues with unsaturated bonds in their structure, can be effectively used as hydrophobic agents of the organic and inorganic materials, tissue, paper, skin, and others. in various branches of the economic activity<\/em><\/p>\n

\u00a0<\/em><\/strong><\/p>\n

Key words<\/strong>: tetrabutoxytitanium, sunflower acid and linseed oil, transesterification, synthesis.<\/p>\n

 <\/p>\n

References<\/strong><\/p>\n

 <\/p>\n

1. V.A. Voytovich, I.N. Hryapchenkova, A.A. Yavorskiy., Gidrofobizatsiya kak sposob povyisheniya sroka sluzhbyi zdaniy , M.: Stroitelnyie materialyi. 2013, January: 15\u201317.
\n2. Katalog-spravochnik. Kremniy organicheskie produktyi, vyipuskaemyie v SSSR. O.A. Muzovskaya, T.M. Yakusheva, G.S. Popeleva, M.M. Zubova. M.:Himiya, 1975: 71.
\n3. N.Ya. Kuzmenko, S.N. Kuzmenko, O.V. Skrinnik, Sintez i svoystva [(butoksi)(stearatatsiloksi)]titanov-titanoksanatov. Voprosyi himii i himicheskoy tehnologii. g.Dnepropetrovsk GVUZ \u00abUGHTU\u00bb, 2015, V. 1: 19\u201326
\n4. L.P. Bezzubov. V kn. Himiya zhirov. M.: (Pischevaya promyishlennost, 1975: 156.
\n5. Kreshkov A.P., Prakticheskoe rukovodstvo po analizu monomernyih i polimernyih kremnoyorganicheskih soedineniy., Kolichestvennyiy elementnyiy analiz:, M.:Goshimizdat, 1962: 288\u2013289.
\n6. Prech E.Byulmann, Affolter K. Opredelenie stroeniya organicheskih soedineniy. Tablitsyi spektralnyih dannyih. Perevod s angl.-M.: Mir. BINOM. Laboratoriya znaniy, 2006: 438.
\n7. Anisimova N.A. Identifikatsiya organicheskih soedineniy. Gorno-Altaysk: RIO GAGU, 2009: 95.
\n8. Infrakrasnyie spektryi nekotoryih titanorganicheskih soedineniy , Semerneva G.A., Suvorov A.L., Samarina L.A., Alekseeva I.A., Spasskiy S.S., Zhurn. priklad. spektroskopii., 1965, V.3: 555\u2013559.
\n9. L.M. Sverdlov, M.A.Kovner, E.P. Kraynov v kn. Kolebatelnyie spektryi mnogoatomnyih molekul. M.: Nauka, 1970: 599(p. 246).<\/p>\n","protected":false},"excerpt":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.40.03.190 Synthesis of the power of (alkoxy) (acyloxy) titanates on the basis of the sum of monocarboxylic acids of sonyashnikovoy \u0430nd llyanoi olii \u00a0 N.Ya. Kuzmenko1, S.N. Kuzmenko1, N.N. Laskovenko1, T.Yu. Kolyada1, G.O. Pashkinkina1, A.O. Stogniy1   1DVNZ \u201cUkrainian State Technological University\u201d 8, Gagarin Avenue, Dnipro, 49005, Ukraine 2Institute of Macromolecular Chemistry of National Academy […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2465"}],"collection":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=2465"}],"version-history":[{"count":2,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2465\/revisions"}],"predecessor-version":[{"id":2537,"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/2465\/revisions\/2537"}],"wp:attachment":[{"href":"http:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=2465"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}