{"id":4097,"date":"2024-12-26T15:33:19","date_gmt":"2024-12-26T12:33:19","guid":{"rendered":"http:\/\/polymerjournal.kiev.ua\/?page_id=4097"},"modified":"2024-12-26T15:33:22","modified_gmt":"2024-12-26T12:33:22","slug":"2024-3-5","status":"publish","type":"page","link":"http:\/\/polymerjournal.kiev.ua\/en\/2024-3-5\/","title":{"rendered":"2024 (3) 5"},"content":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.46.03.203<\/p>\n<p><strong>PHYSICAL-MECHANICAL AND DEGRADATION PROPERTIES<\/strong><\/p>\n<p><strong>OF THERMOPLASTIC STARCH DEPENDING ON THE COMPOSITION OF THE STRUCTURE-FORMING MODIFYING ADDITIVE<\/strong><\/p>\n<p><strong>TETIANA DMYTRIEVA (ORCID: 0000-0002-3526-8395), GALYNA GLIEVA (ORCID: 0000-0002-2916-0257), VOLODYMYR BORTNYTSKYI (ORCID: 0000-0003-4954-6533), SERGII RIABOV* (ORCID: 0000-0003-2996-3794)<\/strong><br \/>\nInstitute of Macromolecular Chemistry of the NAS of Ukraine, 48 Kharkivske Highway, Kyiv 02155, Ukraine,<\/p>\n<p>*e-mail: <a href=\"mailto:Riabov.S@nas.gov.ua\">Riabov.S@nas.gov.ua<\/a><\/p>\n<p>Polym. J., 2024, <strong>46<\/strong>, no. 3: 203-208.<\/p>\n<p>Section: Structure and properties.<\/p>\n<p>Language: Ukrainian.<\/p>\n<h4>Abstract:<\/h4>\n<p style=\"padding-left: 120px;\"><em>The composition of thermoplastic starch (TPS) was prepared using glycerol as a plasticizer, lactic acid and its binary mixture with stearic acid. A number of component concentrations and thermo-mechanical technological parameters were varied during starch processing and formation of film-forming compositions. Physical-mechanical tests of TPS film samples were carried out, and the strength and elasticity properties were determined depending on the concentration of plasticizer and structure-forming additives. The effect of UV irradiation on the degradability of TPS compositions and TPS film samples with synthetic polymer &#8211; polyethylene was studied. The optimal composition, loss of strength and elasticity in the range of 80\u2013100% after 90 days of aging in a climate chamber were determined. Mass spectrometric study of TPS films before and after UV irradiation confirmed the influence of structure-forming additives of stearic and lactic acids on the degradability of TPS compositions. The obtained results indicate the possibility of forming plastic materials with the ability of rapid degradation under environmental conditions.<\/em><\/p>\n<p><strong><em>Key words: <\/em><\/strong><em>thermoplastic starch, structure-forming additives, film formation, lactic acid, stearic acid.<\/em><\/p>\n<p><strong>REFERENCES<\/strong><\/p>\n<p>1. Dmitrieva T.V., Krymovska S.K., Glieva G.E., Riabov S.V. Thermoplastic starch as a component of film- forming compositions with degradable properties. Polymernyi Zhurnal. 2021, 43, no 2: 73\u201377. https:\/\/doi.org\/10.15407\/polymerj.43.02.073.<br \/>\n2. Byshk\u043e M.V., S\u0435m\u0456nskyi \u041e.\u041e., Zubr\u0456y \u041e.G. Influence of plastificer selection on starch-based polymer properties. Bulletin of National Technical University of Ukraine \u201cIgor Sikorsky Kyiv Polytechnic Institute\u201d Series \u201cChemical Engineering Ecology and Resource Saving\u201d. 2022, 1: 9\u201319. https:\/\/doi.org\/10.20535\/2617-9741.1.2022.254154.<br \/>\n3. Kulish B. I., Levytskyi B. V., Masyuk A. S., Levytskyi V. Ye., Zemke V. M. Features of starch modification for the creation of polymer composites. Technology and Application of Substances. V. 6, no. 2, 2023. https:\/\/doi.org\/10.23939\/ctas2023.02.145.<br \/>\n4. Masyuk A. S., Kechur D. I., Kysil D. B., Kulish B. I., Levytskyi V. Ye. Physico-chemical interactions in plasticized starch materials. Chemistry, Technology and Application of Substances. 2023, 6, 1: 124\u2013130 https:\/\/doi.org\/10.23939\/ctas2023.01.124.<br \/>\n5. Bulakh V.Yu. Development of technology for thermoplastic starch and properties\u2013 Manuscript. PhD thesis &#8230; Candidate of Technical Sciences: specialty 05.17.06 \u00abTechnology of polymeric and composite materials\u00bb KNUTD, Kyiv, 2015. https:\/\/er.knutd.edu.ua\/handle\/123456789\/385.<br \/>\n6. Patent US 10.975.213 B2. Composition and method of making Biodegradable Pellets. Dong C., Tyagl K., Siddiqul N. Publ. 13.04.2021.<br \/>\n7. Dang K.M., Yoksan R. Termoplastic starch blown films with improved mechamical and barrier properties. International Journal of Biological Macromolecules. 2021: 290\u2013299. https:\/\/doi.org\/10.1016\/j.ijbiomac.2021.08.027.<br \/>\n8. Zaman H.U., Beg M.D.H. Biodegradable Composites manufactured from Low \u2013 Density Polyethylene and Thermoplastic Sago Starch: Preparation and characterization. Progress in Applied Science and Technology. 2021, 11, 2: 42\u201349. https:\/\/doi.org\/10.14456\/past.2021.16.<br \/>\n9. Chorey O., Ischenko O. Research of properties of films on the modified starch with polysaccharides. KNUTD Bulletin. 2014, 6 (80): 50\u201357 https:\/\/www.knutd.edu.ua\/publications\/pdf\/Visnyk\/2014-6\/50-57.pdf.<br \/>\n10. Bulakh V.Yu., Sova N.V., Pakharenko O.V., Savchenko B.M., Matvienko V.S., Pakharenko V.O. Thermoplastic composite materials based on starch. Study of kinetics of retrogradation processes. Chemical industry of Ukraine. 2015, 1: 20\u201324.<br \/>\n11. Chen Y., Wang Z., Jia, L., Niu C., Hu, Z., Wu C., Yang J. Effect of functional groups of plasticizers on starch plasticization. Colloid and Polymer Science, 2024, 1\u201313. https:\/\/doi.org\/10.1007\/s00396-024-05272-9.<br \/>\n12. Abdollahi Moghaddam M. R., Hesarinejad M. A., Javidi F. Effect of the sorbitol to glycerol weight ratio and sugarcane bagasse concentration on the physicomechanical properties of wheat starch-based biocomposite. Chemical and Biological Technologies in Agriculture, 2023, 10(1), 131. https:\/\/doi.org\/10.1186\/s40538-023-00504-6.<br \/>\n13. Castro J. M., Montalb\u00e1n M. G., Mart\u00ednez-P\u00e9rez N., Domene-L\u00f3pez D., P\u00e9rez J. M., Arrabal-Campos F. M., Garc\u00eda-Quesada J. C. Thermoplastic starch\/polyvinyl alcohol blends modification by citric acid\u2013glycerol polyesters. International Journal of Biological Macromolecules, 2023, 244, 125478. https:\/\/doi.org\/10.1016\/j.ijbiomac.2023.125478.<br \/>\n14. Wang S., Hao Y., He Q., Gao Q. Biodegradable starch-polyvinyl alcohol composite films by the incorporation of lignin for packaging applications. Journal of Thermoplastic Composite Materials, 2024. https:\/\/journals.sagepub.com\/doi\/10.1177\/08927057241233566.<br \/>\n15. G\u00f3mez-Aldapa C. A., Velazquez G., Gutierrez M. C., Rangel-Vargas E., Castro-Rosas J., \uf026 Aguirre-Loredo R. Y. Effect of polyvinyl alcohol on the physicochemical properties of biodegradable starch films. Materials Chemistry and Physics, 2020, 239, 122027. https:\/\/doi.org\/10.1016\/j.matchemphys.2019.122027.<br \/>\n16. Sreekumar P. A., Al\u2010Harthi M. A., De S. K. Studies on compatibility of biodegradable starch\/polyvinyl alcohol blends. Polymer Engineering &amp; Science, 2012, 52(10): 2167\u20132172. https:\/\/doi.org\/10.1002\/pen.23178.<br \/>\n17. Patent WO 2019\/138022 A1. Thermoplastic Starch. Publ. 18.07.2019.<br \/>\n18. Patent WO 2023\/017085 A1. Thermoplastic Starch forming compositions and uses thereof. Publ. 16.02.2023.<br \/>\n19. Patent US 11.518.860 B1. Biodegradable and waterproof shaped articles based on thermoplastic starch with lower retrogradation and improved mechanical properties. Publ. 6.12.2022.<br \/>\n20. Dmitrieva T.V., Krymovska S.K., Glieva G.E., Bortnitskyi V.I., Riabov S.V. Study of the effectiveness of the influence plasticizers and functional additives in the receiving of thermoplastic starch on its film- forming and destructive properties. Polymernyi Zhurnal. 2023, 45, 4: 299-305. https:\/\/doi.org\/10.15407\/polymerj.45.04.299.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.46.03.203 PHYSICAL-MECHANICAL AND DEGRADATION PROPERTIES OF THERMOPLASTIC STARCH DEPENDING ON THE COMPOSITION OF THE STRUCTURE-FORMING MODIFYING ADDITIVE TETIANA DMYTRIEVA (ORCID: 0000-0002-3526-8395), GALYNA GLIEVA (ORCID: 0000-0002-2916-0257), VOLODYMYR BORTNYTSKYI (ORCID: 0000-0003-4954-6533), SERGII RIABOV* (ORCID: 0000-0003-2996-3794) Institute of Macromolecular Chemistry of the NAS of Ukraine, 48 Kharkivske Highway, Kyiv 02155, Ukraine, *e-mail: Riabov.S@nas.gov.ua Polym. J., 2024, 46, no. 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