{"id":3906,"date":"2024-01-18T14:34:45","date_gmt":"2024-01-18T11:34:45","guid":{"rendered":"https:\/\/polymerjournal.kiev.ua\/?page_id=3906"},"modified":"2024-01-18T14:38:52","modified_gmt":"2024-01-18T11:38:52","slug":"2023-4-5","status":"publish","type":"page","link":"https:\/\/polymerjournal.kiev.ua\/en\/2023-4-5\/","title":{"rendered":"2023 (4) 5"},"content":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.45.04.299<\/p>\n

STUDY OF THE EFFECTIVENESS OF THE INFLUENCE OF PLASTICIZERS AND FUNCTIONAL ADDITIVES IN THE RECEIVING OF THERMOPLASTIC STARCH ON ITS FILM-FORMING AND DESTRUCTIVE PROPERTIES<\/strong><\/p>\n

T.V. Dmytrieva,<\/strong>
\nInstitute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine,
\nORCID: 0000-0002-3526-8395<\/p>\n

S.K. Krymovska,<\/strong>
\nInstitute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine,
\nORCID: 0000-0002-9723-4633<\/p>\n

G.E. Glieva,<\/strong>
\nInstitute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine,
\nORCID: 0000-0002-2916-0257<\/p>\n

V.I. Bortnytskyi,<\/strong>
\nInstitute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine,
\nORCID: 0000-0003-4954-6533<\/p>\n

S.V. Riabov,<\/strong>
\nInstitute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine,
\ne-mail: imcnasusr@ukr.net<\/a>
\nORCID: 0000-0003-2996-3794<\/p>\n

Polym. J., 2023, 45, no. 4: 299-305.<\/p>\n

Section: Structure and properties.<\/p>\n

Language: Ukrainian.<\/p>\n

Abstract:<\/strong><\/p>\n

A literature review on the production of thermoplastic starch (TPS) with various plasticizing additives as a component of biodegradable polymer compositions was conducted. Plasticizing additives with different functional groups, due to which starch modification occurs, were analyzed. In order to expand the spectrum of functional additives for the formation of TPS, the introduction of acids with different amounts of carboxyl groups: citric, oxalic, oleic, stearic was studied. The technological parameters of thermomechanical processing of starch compositions and the quantitative composition of the components are determined. Physical and mechanical tests of strength and elasticity of film samples of TPS compositions and compatible with synthetic polymer were carried out. In order to obtain the structural characteristics of TPS and TPS films with polyethylene, studies were carried out by IR-Fourier spectroscopy and mass spectrometry. Studies of the effect of UV irradiation on the degradability of TPS compositions after exposure in a climate chamber for 90 days were conducted. It was found that the loss of strength and elasticity of TPS and TPS+PE film samples is (82\u201390)%, elasticity (60\u201370)%, depending on plasticizing and structure-forming additives and their amounts.<\/em><\/p>\n

Keywords:<\/strong> thermoplastic starch, structure-forming additives, film formation.<\/p>\n

References<\/strong><\/p>\n

1. Estrada \u2013 Monje A., Alonso-Romero S., Zitzumbo-Guzman R., Estrada-Moreno I.A., Zaragoza-Contreras E.A. Thermoplastic Starch \u2013 Based Blends with Improved Thermal and Thermomechanical Properties. Polymers, 2021, no.13: 4263 \u2013 4276. https:\/\/doi.org\/10.3390\/polym13234263.
\n2. Zhai X., Wang W., Zhang H., Dai Y., Dong H., Hou H. Effects of high starch content on the physicochemical properties of starch\/PBAT nanocomposite films prepared by extrusion blowing. Carbohydrate Polymers, 2020: 239. https:\/\/doi.org\/10.1016\/j.carbpol.2020.116231.
\n3. Phothisarattana D., Wongphan P., Promsorn J., Harnkarnsujarit N.. Blown film extrusion of PBAT\/TPS\/ZnO nanocomposites for shelf-life extension of meat packaging. Colloids and Surfaces B: Biointerfaces, 2022: 214. https:\/\/doi.org\/10.1016\/j.colsurfb.2022.112472.
\n4. Wongphan P., Panrong T., Harnkarnsujarit N. Effect of different modified starches on physical, morphological, thermomechanical, barrier and biodegradation properties of cassava starch and polybutylene adipate terephthalate blend film. Food Packaging and Shelf Life. 2022, 32: 100844. https:\/\/doi.org\/10.1016\/j.fpsl.2022.100844.
\n5. Klinmalai P., Srisa A., Laorenza V., KatekhongW., Harnkarnsujarit N. Antifungal and plasticization effects of carvacrol in biodegradable polylactic acid and PBAT blend films for bakery packaging. LWT. 2021, 152: 112356 https:\/\/doi.org\/10.1016\/j.lwt.2021.112356.
\n6. Katekhong W., Wongphan P., Klinmalai P., Harnkarnsujarit N. Termoplasttic starch blown films functionalized by plasticized nitrit blended with PBAT for superior oxygen barrier and active biodegradable meat packaging. Food Chem. 2022; 374: 131709. https:\/\/doi.org\/10.1016\/j.foodchem.2021.131709.
\n7. Dahiru Adamu Ajiya, Suzi Salwah Jikan, Balkis Haji A.Talip, Nur Azam Badarulzaman, Matias \u2013 Peralta, Darfizzi Derawi, Shehu Yahaya. The Influence of Glycerol on Mechanical, Thermal and Morphological Properties of Thermoplastic Tapioca Starch Film. Journal of Science and Technology. 2017, 9, no. 4: 24\u201329. https:\/\/publisher.uthm.edu.my\/ojs\/index.php\/JST\/article\/view\/2054.
\n8. Lukin N.D., \u0410n\u0430n\u0435v V.V., K\u043elp\u0430k\u043ev\u0430 V.V., Us\u0430ch\u0435v I.S., S\u0430rdzhv\u0435l\u0430dz\u0435 \u0410.S., Sd\u043ebnik\u043ev\u0430 \u041e.\u0410., S\u043el\u043emin D.\u0410., Lukin D.N. Bi\u043el\u043egicheski r\u0430zrush\u0430\u0435m\u0430ya t\u0435rm\u043epl\u0430stichn\u0430ya k\u043emp\u043ezitsiia. P\u0430tent RF 2645677 \u04211. Opubl. 27.02.2018. Bul. no. 6.
\n9. V\u0430sil\u0435v I.Yu., \u0410n\u0430n\u0435v V.V., \u041a\u043elp\u0430k\u043ev\u0430 V.V., S\u0430rdzhv\u0435l\u0430dz\u0435 \u0410.S. R\u0430zr\u0430b\u043etk\u0430 t\u0435hn\u043el\u043egii p\u043eluch\u0435niia bi\u043er\u0430zl\u0430g\u0430y\u0435mykh k\u043emp\u043ezitsiy n\u0430 \u043esn\u043ev\u0435 p\u043elietil\u0435n\u0430, kr\u0430khm\u0430l\u0430 i m\u043en\u043eglic\u0435rid\u043ev. Fine Chemical Technologies. 2020, no 15: 44\u201355.
\n10. \u041a\u043elp\u0430k\u043ev\u0430 V.V., Us\u0430ch\u0435v I.S, S\u043el\u043emin D.\u0410. Bi\u043er\u0430zl\u0430g\u0430\u0435my\u0435 p\u043elim\u0435ry: s\u043est\u0430vny\u0435 bi\u043ek\u043emp\u043en\u0435nty i t\u0435khn\u043el\u043egich\u0435ski\u0435 r\u0435sh\u0435niya pr\u043eizv\u043eds\u0442tv\u0430. Pishch\u0435v\u0430ia pr\u043emyshl\u0435nn\u043est. 2019, no. 12: 51\u201357. https:\/\/doi.org\/10.1055\/a-0881-0918.
\n11. P\u0430t. 11518860 \u04121 US. Biodegradable and waterproof shaped articles based on thermoplastic starch with lower retrogradation and improved mechanical properties. 2022.
\n12. P\u0430tent WO 2019\/138022 A1. Thermoplastic starch. Opubl. 18.07.2019.
\n13. Bishk\u043e M.V., S\u0435m\u0456nskij \u041e.\u041e., Zubr\u0456j \u041e.G. Influence of plastificer selection on starch based polymer properties Bulletin of National Technical University of Ukraine \u201dIgor Sikorsky Kyiv Polytechnic Institute\u201d Series \u201dChemical Engineering Ecology and Resource Saving\u201d. 2022, no 1: 9 -19. https:\/\/doi.org\/10.20535\/2617-9741.1.2022.254154.
\n14. Keydis Martinez Villadiego, Mary Judith Arias Tapia, J.Useche, Daniela Escobar Macias. Thermoplastic Starch (TPS)\/Polylactic Acid (PLA) Blending Methodologies: A Review. Journal of Polymers and the Environment. 2022, 30: 75-91 https:\/\/doi.org\/10.1007\/s10924-021-02207-1.
\n15. Palai B., Biswal M., Mohanty S., Nayak S. In situ reactive compatibilization of polylactic acid (PLA) and thermoplastic starch (TPS) blends: synthesis and evaluation of extrusion blown films thereof. Industrial Crops and Products. 2019, 1 December, 14: 111748. https:\/\/doi.org\/10.1016\/j.indcrop.2019.111748.
\n16. Aarsha Surendren, Amar K. Mohanty, Qiang Liu, Manjusri Misra. A review of biodegradable thermoplastic starches, their blends and composites: recent developments and opportunities for single-use plastic packaging alternatives. Green Chemistry. 2022, no 24: 8606 \u2013 8636. https:\/\/doi.org\/10.1039\/D2GC02169B.
\n17. R\u0435chun \u041e.Yu., \u0422k\u0430chuk V.V. Use of biodegradable polymers and antimicrobial packaging materials in food packaging. \u0422\u043ev\u0430r\u043ezn\u0430vchyi v\u0456snyk. 2022, 15: 274-285. https:\/\/doi.org\/10.36910\/6775-2310-5283-2022-15-24.
\n18. \u041a\u043elp\u0430k\u043ev\u0430 V.V., S\u0430rdzhv\u0435l\u0430dz\u0435 \u0410.S. P\u0430p\u0430hin \u0410.\u0410., B\u043er\u043edin\u0430 Z.\u041c., V\u0430sil\u0435v I.Yu., \u0410n\u0430n\u0435v V.V. Bi\u043el\u043egich\u0435ski r\u0430zrush\u0430\u0435m\u0430ia t\u0435rm\u043epl\u0430stichn\u0430ia k\u043emp\u043ezitsiia. P\u0430tent RF 2761830 \u0421 . Opubl. 22.04.2021. Bul. no.12.
\n19. S\u043ev\u0430 N.V., S\u0430vch\u0435nk\u043e B.\u041c., Pl\u0430v\u0430n V.P., B\u0456l\u043esh\u0435nk\u043e V.\u041e. Some ways to create environmentally safe polymer packaging in Ukraine. Upakovka. 2017, no 5: 31 \u2013 34.<\/p>\n","protected":false},"excerpt":{"rendered":"

https:\/\/doi.org\/10.15407\/polymerj.45.04.299 STUDY OF THE EFFECTIVENESS OF THE INFLUENCE OF PLASTICIZERS AND FUNCTIONAL ADDITIVES IN THE RECEIVING OF THERMOPLASTIC STARCH ON ITS FILM-FORMING AND DESTRUCTIVE PROPERTIES T.V. Dmytrieva, Institute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, 02155, Ukraine, ORCID: 0000-0002-3526-8395 S.K. Krymovska, Institute of Macromolecular Chemistry NAS of Ukraine, 48, Kharkivske Shose, Kyiv, […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/3906"}],"collection":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=3906"}],"version-history":[{"count":2,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/3906\/revisions"}],"predecessor-version":[{"id":3910,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/3906\/revisions\/3910"}],"wp:attachment":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=3906"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}