{"id":4545,"date":"2026-04-02T16:40:34","date_gmt":"2026-04-02T13:40:34","guid":{"rendered":"https:\/\/polymerjournal.kiev.ua\/?page_id=4545"},"modified":"2026-04-02T16:41:55","modified_gmt":"2026-04-02T13:41:55","slug":"2026-1-3","status":"publish","type":"page","link":"https:\/\/polymerjournal.kiev.ua\/en\/2026-1-3\/","title":{"rendered":"2026 (1) 3"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.15407\/polymerj.48.01.022\">https:\/\/doi.org\/10.15407\/polymerj.48.01.022<\/a><\/p>\n<p><strong>BRANCHED POLYURETHANES BASED ON RENEWABLE RAW MATERIALS: STRUCTURE AND PROPERTIES<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>Liudmyla MARKOVSKA<\/strong><sup>*<\/sup> (ORCID: <a href=\"http:\/\/www.orcid.org\/0000-0003-3427-9786\">0000-0003-3427-9786<\/a>)<\/p>\n<p><strong>Nataliia PARKHOMENKO<\/strong> (ORCID: <a href=\"http:\/\/www.orcid.org\/0000-0001-7481-9113\">0000-0001-7481-9113<\/a>)<\/p>\n<p><strong>Olga SAVELYEVA<\/strong> (ORCID: <a href=\"http:\/\/www.orcid.org\/0000-0002-3167-8493\">0000-0002-3167-8493<\/a>)<\/p>\n<p><strong>Yuri SAVELYEV<\/strong> (ORCID: <a href=\"http:\/\/www.orcid.org\/0000-0003-3356-9087\">0000-0003-3356-9087<\/a>)<\/p>\n<p>Institute of Macromolecular Chemistry, NAS of Ukraine<\/p>\n<p>48, Kharkivske Highway, Kyiv, 02155, Ukraine<\/p>\n<p><sup>*<\/sup>Corresponding author.<\/p>\n<p>E-mail:\u00a0 <a href=\"mailto:yuri2savelyev@gmail.com\">yuri2savelyev@gmail.com<\/a><\/p>\n<p>Polimernyi Zhurnal, 2026,\u00a0<strong>48<\/strong>, no. 1: 22-29<\/p>\n<p>Section: Structure and properties<\/p>\n<p>Language: Ukrainian.<\/p>\n<p><strong>Abstract<\/strong><\/p>\n<p style=\"padding-left: 160px;\">Polymer compositions based on branched polyurethanes (BPU) have been developed using renewable natural raw materials, particularly castor oil (CO), while maintaining the performance characteristics inherent in polyurethanes. The developed method for obtaining these materials will improve the process&#8217;s cost-effectiveness and environmental friendliness. The introduction of CO, as a macrochain fragment, into the structure of the BPU at 25 to 64 wt.% increases the adhesive\/cohesion strength of the BPU\/CO; it also contributes to the preservation of the indicators of physical, mechanical and operational properties of BPU\/CO under conditions of complex cumulative atmospheric loading (UV and IR radiation, prolonged elevated temperature and humidity); changes the nature of thermal-oxidative destruction, contributes to the preservation of indicators of physical, mechanical, and operational properties of BPU\/CO under conditions of complex cumulative atmospheric loading (UV and IR radiation, prolonged elevated temperature and humidity); changes the nature of thermal-oxidative destruction, indicating the stabilizing effect of CO on resistance to this destructive action; gives BPU\/CO signs of resistance to fungus, water, oil, gasoline, diesel fuel, organic solvents, and diluted acids and alkalis. Targeted materials with improved properties can be obtained by varying the structure and composition of the BPU\/CO. The developed materials can be used as protective coatings for various objects, provided they are adapted to the available raw material base. The ability of the BPU\/CO to provide long-term, comprehensive protection for materials, structures, and infrastructure will ensure their reliable, prolonged operation.<\/p>\n<p><strong>Keywords<\/strong><em>: <\/em>branched polyurethanes, renewable raw materials, adhesion, a(biotic) destructors, barrier properties<em>.<\/em><\/p>\n<h4>REFERENCES<\/h4>\n<p>1. L\u0435bedev \u0415.V., S\u0430v\u0435ly\u0435v Yu.V. Polymers on guard of people health. Visn. Nac. Akad. Nauk Ukr., 2008, 10: 16\u201322. http:\/\/dspace.nbuv.gov.ua\/handle\/123456789\/3442.<br \/>\n2. L\u0435bedev \u0415.V., S\u0430v\u0435ly\u0435v Yu.V., Kolyada V.M. Functional polymers and composite materials based on them for building construction Budivelni materialy, vyroby i sanitarna tehnika. 2011, 42: 76\u201380. nbuv.gov.ua\/UJRN\/bmvs_2012_42_76.<br \/>\n3. P\u0430t\u0435nt UA 85111. IPC \u042108L75\/04, \u042108L75\/06, \u042108L75\/08. Polyurethane composition. Yu.V. S\u0430v\u0435ly\u0435v, M\u0430r\u043a\u043evs\u043a\u0430 L.\u0410., P\u0430rkh\u043em\u0435n\u043a\u043e N.I., S\u0430v\u0435ly\u0435va \u041e.\u041e. Publ. 11.11.2013, Bul 21.<br \/>\n4. P\u0430t\u0435nt UA 105706. IPC \u042108L75\/00, \u042108 L75\/06, \u042108L75\/08 Process for the preparation of polyurethane composition. S\u0430v\u0435ly\u0435v Yu.V., M\u0430r\u043a\u043evs\u043a\u0430 L.\u0410., P\u0430rkh\u043em\u0435n\u043a\u043e N.I., S\u0430v\u0435ly\u0435va \u041e.\u041e. Publ. 10.06.2014, Bul. 11.<br \/>\n5. P\u0430t\u0435nt UA 90678. IPC C08J3\/00, C08J3\/20, \u042108\u041a5\/500, \u042108L75\/00, \u042108L75\/08. Process for the preparation of polyurethane composition for protective coating. S\u0430v\u0435ly\u0435v Yu.V., M\u0430r\u043a\u043evs\u043a\u0430 L.\u0410., P\u0430rkh\u043em\u0435n\u043a\u043e N.I., S\u0430v\u0435ly\u0435va \u041e.\u041e. Publ. 10.06.2014, Bul. 11.<br \/>\n6. Zhang Y., Dong H., Yang W., Lu H., Wei C., Yang W. Recent progress on bio-based polyurethanes: Synthesis, structure and cutting-edge applications. Mater. Today Commun., 2025, 45, 112279. https:\/\/doi.org\/10.1016\/j.mtcomm.2025.112279.<br \/>\n7. Piotrowska A., Paciorec-Sadowska J., \u0141azarska M., Borowicz M., Isbrandt M. Current progress in synthesis of polyurethane materials based on raw materials of non-petrochemical origin. Eur. Polym. J., 2025, 234, 114028 https:\/\/doi.org\/10.1016\/j.eurpolymj.2025.114028.<br \/>\n8. Sangeetha N. J., Retna A. M., Joy Y. J., Sophia A. A review on advanced methods of polyurethane synthesis based on natural resources. J. Chem. Pharm. Sci, 2014, 7, 242\u2013249.<br \/>\n9. Ma Y., Xiao Y., Zhao Y., Bei Y., Hu L., Zhou Y., Jia, P. Biomass based polyols and biomass based polyurethane materials as a route towards sustainability. React. and Funct. Polym., 2022, 175, 105285. https:\/\/doi.org\/10.1016\/j.reactfunctpolym.2022.105285.<br \/>\n10. Methods of experimental mycology. S\u0440r\u0430v\u043echnik. \u041a.: Nauk. dumka, 1989: 540.<br \/>\n11. Biron M. (2004). Chapter 3\u2014Basic criteria for the selection of thermosets. Thermosets and Composites; Biron, M., Ed.; Elsevier Science: Oxford, UK, 145\u2013181. https:\/\/doi.org\/10.1016\/B978-185617411-4\/50005-X.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>https:\/\/doi.org\/10.15407\/polymerj.48.01.022 BRANCHED POLYURETHANES BASED ON RENEWABLE RAW MATERIALS: STRUCTURE AND PROPERTIES \u00a0 Liudmyla MARKOVSKA* (ORCID: 0000-0003-3427-9786) Nataliia PARKHOMENKO (ORCID: 0000-0001-7481-9113) Olga SAVELYEVA (ORCID: 0000-0002-3167-8493) Yuri SAVELYEV (ORCID: 0000-0003-3356-9087) Institute of Macromolecular Chemistry, NAS of Ukraine 48, Kharkivske Highway, Kyiv, 02155, Ukraine *Corresponding author. E-mail:\u00a0 yuri2savelyev@gmail.com Polimernyi Zhurnal, 2026,\u00a048, no. 1: 22-29 Section: Structure and properties [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"acf":[],"_links":{"self":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/4545"}],"collection":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/comments?post=4545"}],"version-history":[{"count":2,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/4545\/revisions"}],"predecessor-version":[{"id":4547,"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/pages\/4545\/revisions\/4547"}],"wp:attachment":[{"href":"https:\/\/polymerjournal.kiev.ua\/en\/wp-json\/wp\/v2\/media?parent=4545"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}