2015 (2) 9

https://doi.org/10.15407/polymerj.37.02.168

Synthesis of allyl-containing poly(arylene ether)s copolymers with mono- and biphenylene fragments in main chain

І.М. Tkachenko, A.V. Sidorenko, О.V. Shekera, V.V. Shevchenko

Institute of Macromolecular Chemistry NAS of Ukraine

48, Kharkivske shose, Kyiv, 02160, Ukraine

Polym. J., 2015, 37, no. 2: 168-173.

Section: Synthesis polymers.

Language: Russian.

Abstract:

Methods of synthesis of allyl-containing core-fluorinated poly(arylene ether)s copolymers with tetrafluorobenzene and octafluorobiphenylene units and 2-allylbenzene and nonfluorinated meta-phenylenoxide fragments were developed. The polyethers were prepared from ternary copolycondensation of three core-fluorinated components, namely by interaction of decafluorobiphenyl with 2-(prop-2-en-1-yl)-4-{2,3,5,6-tetraыuoro-4-[4-hydroxy-3-(prop-2-en-1-yl)phenoxy]phenoxy}-phenol and 3-[2,3,5,6-Tetraыuoro-4-(3-hydroxyphenoxy)phenoxy]phenol. Changing the ratio of initial bisphenols allows to adjust the content of allyl groups and unsubstituted aromatic moieties in the main chain of the synthesized polymers while preserving the constant concentration of fluorine atoms. The influence of base NaH and K2CO3 on the molecular weight and mechanical properties of the synthesized copolymers was study.

Key words: core-fluorinated aromatic polyethers, allyl-containing polyethers, copolymers, synthesis, properties.

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