№3 (2017) 5

https://doi.org/10.15407/polymerj.39.03.177

Viscosity of solution of polyamic acid based on card diamines filled by carbon nanotubes

T.A. Shantalii, I.L. Karpova, K.S. Dragan, V.V. Klepko

Institute of Macromolecular Chemistry NAS of Ukraine

48, Kharkivs’ke shose, Kyiv, 02160, Ukraine

Polym. J., 2017, 39, № 3: 177-182.

Section: Structure and properties.

Language: Ukrainian.

Abstract:

Reseach of rheological properties of solutions of polyamic acid (PAA) based on pyromellitic dianhydride and 9,9-bis (4-aminophenyl) -fluorene (anilinfluorene) containing card fragment filled with carbon nanotubes (CNT) was conducted. The presence of such a volumetric structural unit determines the non-Newtonian character of the flow of concentrated solutions PAA, as well as the presence of an anomaly of the viscosity of dispersions of PAA with CNT. Introduction of CNT into solution of PAA leads to a decrease of the viscosity of the system, regardless of the concentration. When a CNT of less to 0.5% is added to the solution, we observe gradual decrease of the viscosity of dispersions, while an increase in the CNT content up to 1,0 % leads to a gradual increase of viscosity. Character of flow of dispersions of PAA–CNT changes with increasing content of CNT and does not depend on concentration of solutions of PAA.

Key words: polyamic acid, carbon nanotubes, viscosity, flow character, rheological properties.

References

1. 1. Buller K.U. Teplo- I termostoikie polimery. Moskva: Himija, 1984: 1056.
   2. GomzaYu.P., Shantalii T.A., Nesin S.D., Dragan K.S., Klepko V.V. Vplyv Karbonanotrubok na ztrukturni osoblyvost ipoliimidu. Polym.J., 2011, 33, no. 3: 244-247.
   3.Grozdov A.G., Girkova A.Z., Hofbauer E.I., Leonova T.A. Issledovanie reologicheskih charakteristik umerennokoncentrirovannyh rastvorov poliamidokislot. Vysokomol. Soed. Ser.A, 1972, 14, no. 3: 512-517.
   4. Rheology. Theory and Applications. Ed.by F.R. Eirich. New York–London: Academic Press, Vol. 3, 1960: 352.
   5. Paiffer D.G., Lubdberg R.D., Duvdevani I. Synthesis and rheological properties of low chargedencitypolyampholytes in nonaqueous solvents. Polymer, 1986, 27, no. 9: 1453-1562. https://doi.org/10.1016/0032-3861(86)90051-0
   6. Privalko V.P., Mudrak C.V., Karpova I.L., Korskanov V.V., Shapoval R.L., Usenko A.A. Characterization of poly(amide imide)s in solution. New Polymeric Materials, 1998, 5, no. 9: 141-157.
   7. Kargin V.A., Sogolova T.P., Metelskaya T.K. Vliyanie napolnitelei s chastitsami anizodiametricheskoy formy na svoistva polimerov. Vysokomol. Soed., 1962, 4, no. 4: 601-604.
   8. Prokopenko V.V., Petkevich O.K., Malinskiy Yu.M., Bakeev N.F. Vliyanie malyh dobavok tverdyh napolnitelei na reologicheskie svoistva polimerov. Dokl. AN SSSR, 1974, 214, no. 2: 389-392.
   9. Prokopenko V.V., Titova O.K., Fesik N.S., Malinskiy Yu.M., Bakeev N.F. O prirode anomalii koncentrirovannogo hoda vyazkosti napolnennyh polimerov v oblasti malyh napolnenii. Vysokomol. Soed., Ser.A, 1977, 19, no. 1: 95-101.
   10. Malkin A.Ya., Isaev A.I. Reologiya: kontceptcii, metody, prilogeniya. S.-Peterburg: Professiya, 2010: 557. ISBN 978-5-93913-139-1.
   11. Du F., Scogna R.S., Zhou W., Brand S., Fischer J.E.,Winey K.I. Nanotube networks in polymer nanocomposites: rheology and electrical conductivity. Macromolecules, 2004, 37, no. 9 : 9048-9055. https://doi.org/10.1021/ma049164g
   12. Shumsky V.F., LipatovYu.S., Fabulyak F.G., Getmanchuk I.P. Vliyanie modifikatcii poverhnosti napolnitelya na vyazkost dispersnoi sistemy poliefir – aerosol. Vysokomol. Soed., Ser.A, 1976, 18, no. 10: 2248-2255.
   13. Illin S.O., Spiridonova V.M., Savelleva V.S., Ovchinnikov M.M., Hignyak S.D., Frenkin E.I., Pahomov P.M., MalkinA.Ya. Geleobrazovanie v razbavlennyh vodnyh rastvorah L-tcisteina I AgNO3. Kolloid. J., 2011, 73, no. 5: 641-646.
   14. Shumsky V.F., Getmanchuk I.P., Tereshyn A.K., Kulchihyn V.G. Reologicheskie svoistva smesei izotropnyh I anizotropnyh rastvorov gidroxypropylcellulozy. Vysokomol. Soed., Ser.A, 2004, 46, no. 12: 2059-2071.
   15. Shantalii T.A., Karpova I.L., Dragan E.S., Getmanchuk I.P., Shumsky V.F. Vyazkost dispersii karbonanotrubok v rastvore poliamidokisloty. Voprosy khim. i khim. tecnol., 2013, no. 1: 61-65.
   16. Shantalii T.A., Karpova I.L., Getmanchuk I.P., Shumsky V.F. Vyazkost rastvorov Poliamidokisloty na osnove piromellitovogo diangidrida, 4,4′-diaminodifenilovogo efira i 3,5-diaminobenzoinoi kisloty, napolnennyh karbonanotrubkami. Polym. J., 2015, 37, no. 3: 269-274. https://doi.org/10.15407/polymerj.37.03.269
   17. Sokolov L.V. Osnovy sinteza polimerov metodom polikondensatcii. Moskva: Himiya, 1979: 264.
   18. Mudrak C.V. Sintez I svoictva poliamidoimidov na osnove imidov tri- i tetrakarbonovyh kislot. Kiev: Dis. kand. him. nauk, 1996: 123.
   19. MalkinA.Ya.Reologiya napolnennyh polymerov. In book: Kompozicionnye polimernye materialy. (Ed.), Kiev: Nauk. dumka, 1975: 60-76.
   20. Vinogradov V.G., Plotnikova E.P., Zabugina M.P., Borisenkova E.K. Vliyanie molekulyarnyh harakteristik polimera na predel tekuchesti ego napolnennyh kompositcii. Vysokomol. Soed., Ser.B, 1987, 29, no. 21: 211-213.
   21. Malkin A.Ya. Rheology of Filled Polymers. In book: Advances in Polymer Sci. Springer (Ed.), Verlag Berlin: Heidelberg, 1990: 70-97. https://doi.org/10.1007/3-540-52791-5_2
   22. Casson N. Rheology of disperse systems. Oxford: Pergamon, 1959: 84.